Skip to main content
SpringerLink
Log in

Photoactivation of the oxidation process of para-chlorophenol in aqueous solutions

  • Various Physicochemical and Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Kinetics of the oxidative destruction of para-chlorophenol in a combined iron-persulfate system under the action of simulated sunlight was studied. It was shown that, under additional photoirradiation, a deep conversion of chlorophenol and main intermediate products of its destruction is provided, with iron compounds serving not only as catalysts, but also as photochemical oxidation sensitizers. The degree of mineralization of para-chlorophenol and products of its oxidation under a photoactivated treatment for two hours reached a value of 60%, whereas that in the “dark” reaction did not exceed 1%. In the combined oxidizing system S2O 2–8 /Fe2+/UV-Vis, a considerable synergic effect was observed due to the formation of reactive oxygen intermediate both via decomposition persulfate and through reduction of Fe3+ from inactive Fe3+ intermediates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kharlampovich, G.D. and Churkin, Yu.V., Fenoly (Phenols), Moscow: Khimiya, 1974.

    Google Scholar 

  2. Ahlborg, U.G. and Thunberg, T.M., Crit. Rev. Toxicol., 1980, vol. 7, pp. 1–35.

    Article  CAS  Google Scholar 

  3. Fokin, A.V. and Kolomiets, A.F., Priroda, 1985, no. 3, pp. 3–15.

    Google Scholar 

  4. Naturally Produced Organohalogens, Grimvall, A. and de Leer, Ed. W.B., Eds., Springer Science+Business, Media, B. V., 1995.

  5. Pera-Titus, M., García-Molina, V., Banos, M.A., et al., Appl. Catal., B, 2004, vol. 47, pp. 219–256.

    Article  CAS  Google Scholar 

  6. Andreozzi, R., Caprio, V., Insola, A., et al., Catal. Today, 1999, vol. 53, no. 7, pp. 51–59.

    Article  CAS  Google Scholar 

  7. Gogate, P.R. and Pandit, A.B., Adv. Environ. Res., 2004, vol. 8, nos. 3–4, pp. 553–597.

    Article  CAS  Google Scholar 

  8. Batoeva, A.A., Ryazantsev, A.A., Sizykh, M.R., and Khandarkhaeva, M.S., Khim. Interesakh Ustoich. Razvit., 2006, vol. 14, no. 4, pp. 343–348.

    CAS  Google Scholar 

  9. Aseev, D.G., Batoeva, A.A., and Sizykh, M.R., Khim. Interesakh Ustoich. Razvit., 2009, no. 2, pp. 203–207.

    Google Scholar 

  10. Carey, J.H., Water Pollut. Res. J. Can., 1992, vol. 27, pp. 1–21.

    Google Scholar 

  11. Liu, X., Fang, L., Zhou, Y., et al., J. Environ. Sci., 2013, vol. 25, no. 8, pp. 1519–1528.

    Article  CAS  Google Scholar 

  12. Ahmed, M.M. and Chiron, S., Water Res., 2014, vol. 48, pp. 229–236.

    Article  CAS  Google Scholar 

  13. Chen-Ju, L. and Shun-Chin, H., Sustain. Environ. Res., 2012, vol. 22, no. 4, pp. 199–208.

    Google Scholar 

  14. Criquent, J. and Leithner, N.K.V., Chemosphere, 2009, vol. 77, pp. 194–200.

    Article  Google Scholar 

  15. Liu, C.S., Shih, K., Sun, C.X., et al., Sci. Total Environ., 2012, vol. 416, pp. 507–512.

    Article  CAS  Google Scholar 

  16. Hussain, I., Zhang, Y., Huang, S., et al., Chem. Eng. J., 2012, vol. 203, pp. 269–276.

    Article  CAS  Google Scholar 

  17. Pinevich, A.V., Mikrobiologiya zheleza i margantsa (Microbiology of Iron and Manganese), St. Petersburg: S. Peterburg. Univ., 2005.

    Google Scholar 

  18. Rao, Y.F., Qu, L., Yang, H., et al., J. Hazard. Mater., 2014, vol. 268, pp. 23–32.

    Article  CAS  Google Scholar 

  19. Fang, S.C. and Lo, S.L., Appl. Mech. Mater., 2011, vols. 121–126, pp. 2546–2556.

    Article  Google Scholar 

  20. Weiner, E.R., Applications of Environmental Chemistry, Lewis Publishers, CRC Press LLC, Boca Raton, FL, 2000.

    Google Scholar 

  21. Legrini, O., Oliveros, E., and Braun, A.M., Chem. Rev., 1993, vol. 93, pp. 671–698.

    Article  CAS  Google Scholar 

  22. Vorob’eva, N.I., Matafonova, G.G., and Batoev, V.B., Voda: Khim. Ekologiya, 2012, no. 9, pp. 32–36.

    Google Scholar 

  23. Batoev, V.B., Matafonova, G.G., and Filippova, N.I., Russ. J. Appl. Chem., 2011, vol. 84, no. 3, pp. 407–411).

    Article  CAS  Google Scholar 

  24. Vichutinskaya, E.V., Pervunina, R.I., Semenova, I.V., et al., Khim. Fiz., 1997, vol. 16, no. 4, pp. 25–34.

    CAS  Google Scholar 

  25. Zhao, J., Zhang, Y., Quan, X., et al., Sep. Purif. Technol., 2010, vol. 71, pp. 302–307.

    Article  CAS  Google Scholar 

  26. Rod’ko, I.Ya., Kozlov, Yu.N., and Purmal’, A.P., Zh. Fiz. Khim., 1999, vol. 73, no. 6, pp. 1125–1126.

    Google Scholar 

  27. Lou, X., Wu, L., Guo, Y., et al., Chemosphere, 2014, vol. 117, pp. 582–585.

    Article  CAS  Google Scholar 

  28. Li, B., Li, L., Lin, K., et al., Ultrason. Sonochem., 2013, vol. 20, pp. 855–863.

    Article  CAS  Google Scholar 

  29. Huang, Y.-F. and Huang, Y.-H., J. Hazard. Mater., 2009, vol. 162, pp. 1211–1216.

    Article  CAS  Google Scholar 

  30. Kusic, H., Peternel, I., Ukic, S., et al., Chem. Eng. J., 2011, vol. 172, pp. 109–121.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, ul. Sakh’yanova 8, Ulan-Ude, Republic of Buryatia, 670047, Russia

    M. S. Khandarkhaeva, A. A. Batoeva, D. G. Aseev & M. R. Sizykh

Authors
  1. M. S. Khandarkhaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Batoeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. G. Aseev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. R. Sizykh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Batoeva.

Additional information

Original Russian Text © M.S. Khandarkhaeva, A.A. Batoeva, D.G. Aseev, M.R. Sizykh, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 10, pp. 1420-1426.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Khandarkhaeva, M.S., Batoeva, A.A., Aseev, D.G. et al. Photoactivation of the oxidation process of para-chlorophenol in aqueous solutions. Russ J Appl Chem 88, 1605–1611 (2015). https://doi.org/10.1134/S1070427215100080

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427215100080

Keywords

Search

Navigation