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Catalytic activity of the VIII Group metals in the hydrogenation and isomerization of α- and β-pinenes

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Abstract

The kinetic regularities of the liquid-phase hydrogenation and isomerization of α- and β-pinenes over the Pd/C, Ru/C, Rh/C, Pt/C, and Ir/C catalysts were studied at temperatures ranging from 20 to 100 °C and at hydrogen pressures of 1–11 bar using n-octane as the solvent. The hydrogenation and isomerization of α- and β-pinenes occur simultaneously on the Ru/C, Rh/C, Pt/C, and Ir/C catalysts, and the reaction mixture contains the products of double bond hydrogenation, viz., cis- and trans-pinanes. The Ru, Rh, and Pd metals have a higher catalytic activity in β-pinene isomerization than Ir and Pt. Among the VIII Group metals studied, the Pd-based catalyst has the highest catalytic activity in double bond isomerization of α- and β-pinenes. The general scheme of the mechanism of hydrogenation and isomerization of α- and β-pinenes on the Pd/C catalyst was proposed.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent eva, 630090, Novosibirsk, Russian Federation

    I. V. Deliy & I. L. Simakova

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  1. I. V. Deliy
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  2. I. L. Simakova
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Correspondence to I. V. Deliy.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2020–2027, October, 2008.

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Deliy, I.V., Simakova, I.L. Catalytic activity of the VIII Group metals in the hydrogenation and isomerization of α- and β-pinenes. Russ Chem Bull 57, 2056–2064 (2008). https://doi.org/10.1007/s11172-008-0279-1

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  • DOI: https://doi.org/10.1007/s11172-008-0279-1

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