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Thermodynamic properties of graphite-like nanostructures prepared by thermobaric treatment of fullerite C60

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Abstract

Temperature dependences of the heat capacities of disordered graphite-like nanostructures prepared by the thermobaric treatment of fullerite C60 (p = 2 and 8 GPa, T = 1373 K) were measured in the temperature ranges from 7 to 360 K in an adiabatic vacuum calorimeter and from 330 to 650 K in a differential scanning calorimeter. At T < 50 K, the dependences obtained were analyzed using the Debye theory of the heat capacity of solids and its multifractal version. The fractal dimensions D were determined and some conclusions on the heterodynamic character of the structures studied were made. The thermodynamic functions C p o T), H o(T) − H o(0), S o(T) − S o(0), and G o(T) − H o(0) were calculated in the temperature range from T → 0 to 610 (650) K. The thermodynamic properties of the graphite-like nanostructures studied and some carbon allotropes were compared. The standard entropies of formation Δf S o of the graphite nanostructures studied and diamond were calculated along with the standard entropies of the reactions of their synthesis from the face-centered cubic phase of fullerite C60 and their interconversions at T = 298.15 K.

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Authors and Affiliations

  1. Chemistry Research Institute, N. I. Lobachevsky Nizhnii Novgorod State University, Building 5, 23 prosp. Gagarina, 603950, Nizhnii Novgorod, Russian Federation

    A. V. Markin, N. N. Smirnova, I. E. Boronina & V. A. Ruchenin

  2. L. F. Vereshchagin Institute of High-Pressure Physics, Russian Academy of Sciences, 142190, Troitsk, Moscow Region, Russian Federation

    A. G. Lyapin

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  1. A. V. Markin
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  2. N. N. Smirnova
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  3. I. E. Boronina
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  4. V. A. Ruchenin
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Correspondence to A. V. Markin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1940–1945, September, 2008.

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Markin, A.V., Smirnova, N.N., Boronina, I.E. et al. Thermodynamic properties of graphite-like nanostructures prepared by thermobaric treatment of fullerite C60 . Russ Chem Bull 57, 1975–1980 (2008). https://doi.org/10.1007/s11172-008-0265-7

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  • DOI: https://doi.org/10.1007/s11172-008-0265-7

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