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Reactivity of triangular oxalate cluster complexes [M3Q7(C2O4)3]2− (M = Mo or W; Q = S or Se)

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Abstract

The reactions of the oxalate complexes [M3Q7(C2O4)3]2− (M = Mo or W; Q = S or Se) with MnII, CoII, NiII, and CuII aqua and ethylenediamine complexes in aqueous and aqueous ethanolic solutions were studied. The previously unknown heterometallic complexes [Mo3Se7(C2O4)3Ni(H2O)5]·3.5H2O (1) and K3{[Cu(en)2H2O]([Mo3S7(ox)3]2Br)}·5.5H2O (2) were synthesized. In these complexes, the oxalate clusters serve as monodentate ligands. The K(H2en)2[W3S7(C2O4)3]2Br·4H2O salt (3) was isolated from solutions containing CoII, NiII, or CuII aqua complexes and ethylenediamine. The reaction of [Mo3Se7(C2O4)3]2− with HBr produced the bromide complex [Mo3Se7Br6]2−, which was isolated as (Bu4N)2[Mo3Se7Br6] (4). Complexes 1–3 were characterized by X-ray diffraction, IR spectra, and elemental analysis. The formation of 4 was detected by electrospray mass spectrometry.

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References

  1. Y. Q. Sun, J. Zhang, and G. Y. Yang, J. Chem. Soc., Dalton Trans., 2006, 1685.

  2. E. Coronado and J. R. Galan-Mascaros, J. Mater. Chem., 2005, 15, 66.

    Article  CAS  Google Scholar 

  3. J. C. Trombe and A. Mohanu, Solid State Sciences, 2004, 6, 1403.

    Article  CAS  Google Scholar 

  4. E. Coronado and P. Day, Chem. Rev., 2004, 104, 5419.

    Article  CAS  Google Scholar 

  5. Y. Q. Sun, J. Zhang, and G. Y. Yang, J. Chem. Soc., Dalton Trans., 2004, 971.

  6. O. Kahn, Molecular Magnetism; VCH: Weinheim, Germany, 1993.

    Google Scholar 

  7. J. M. Garriga, R. Llusar, S. Uriel, C. Vicent, A. J. Usher, N. T. Lucas, M. G. Humphrey, and M. Samoc, J. Chem. Soc., Dalton Trans, 2003, 4546.

  8. M. N. Sokolov, A. L. Gushchin, D. Yu. Naumov, O. A. Gerasko, and V. P. Fedin, Inorg. Chem., 2005, 44, 2431.

    Article  CAS  Google Scholar 

  9. M. N. Sokolov, A. L. Gushchin, D. Y. Naumov, O. A. Gerasko, and V. P. Fedin, J. Cluster Science, 2005, 16, 309.

    Article  CAS  Google Scholar 

  10. V. P. Fedin, M. N. Sokolov, O. A. Gerasko, A. V. Virovets, N. V. Podberezskaya, and V. Ye. Fedorov, Inorg. Chim. Acta, 1991, 187, 81.

    Article  CAS  Google Scholar 

  11. M. J. Laws, C. H. Schiesser, J. M. White, and Shi-Long Zheng, Aust. J. Chem., 2000, 53, 277.

    Article  CAS  Google Scholar 

  12. M. Piatek, B. Oleksyn, and J. Sliwinski, Acta Cryst., Sect. C: Cryst. Struct. Commun., 1995, 51, 298.

    Article  Google Scholar 

  13. L. Dupont, O. Dideberg, and P. Jacquemin, Acta Cryst., Sect. C: Cryst. Struct. Commun., 1990, 46, 484.

    Article  Google Scholar 

  14. F. H. Allen, Acta Cryst. A58, 2002, 380.

  15. A. Kobayashi, H. Kondo, Y. Sasaki, H. Kobayashi, A. E. Underhill, and D. M. Watkins, Bull. Chem. Soc. Jpn., 1982, 55, 2074.

    Article  CAS  Google Scholar 

  16. A. V. Virovets, A. L. Gushchin, P. A. Abramov, N. I. Alferova, M. N. Sokolov, and V. P. Fedin, Zh. Strukt. Khim., 2006, 47, 340 [J. Struct. Chem., 2006, 47 (Engl. Transl.)].

    Google Scholar 

  17. A. Gordon and R. Ford, Chemist’s companion, A Wiley-Interscience Publication, New York-London-Sydney-Toronto, 1972.

    Google Scholar 

  18. Masslynx 3.2, Micromass, Manchester, UK, 1998.

  19. APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11), Bruker Advanced X-ray Solutions, Bruker AXS Inc., Madison, Wisconsin, USA, 2004.

  20. G. M. Sheldrick, SHELXS-97 and SHELXL-97, Programs for the Refinement of Crystal Structures, Göttingen University, Göttingen, Germany, 1997.

    Google Scholar 

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. L. Gushchin, K. A. Kovalenko, M. N. Sokolov, D. Yu. Naumov, E. V. Peresypkina, A. V. Virovets & V. P. Fedin

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  1. A. L. Gushchin
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  2. K. A. Kovalenko
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  3. M. N. Sokolov
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  4. D. Yu. Naumov
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  5. E. V. Peresypkina
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  6. A. V. Virovets
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  7. V. P. Fedin
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Correspondence to V. P. Fedin.

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Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1645–1649, September, 2007.

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Gushchin, A.L., Kovalenko, K.A., Sokolov, M.N. et al. Reactivity of triangular oxalate cluster complexes [M3Q7(C2O4)3]2− (M = Mo or W; Q = S or Se). Russ Chem Bull 56, 1707–1711 (2007). https://doi.org/10.1007/s11172-007-0265-z

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  • DOI: https://doi.org/10.1007/s11172-007-0265-z

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