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New inorganic ligand μ3-[SbO(H2O)2]3− in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se)

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Abstract

The mixed-ligand cluster complexes of the composition K5[{Re4S3[SbO(H2O)2]}-(CN)12]·8H2O (1) and K5[{Re4Se3[SbO(H2O)2]}(CN)12] · 3H2O (2) bearing the new inorganic ligand μ3-[SbO(H2O)2]3− were synthesized by the high-temperature reactions of ReI3 with Sb, S, or Se and KCN followed by the recrystallization of the soluble products from water. The structures of the new compounds were studied by X-ray diffraction analysis. Using mass spectrometry data, it was found that the μ3-[SbO(H2O)2]3− ligand is deprotonated stibine oxide, which is additionally coordinated by two water molecules.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 18-13-00058) and the Ministry of Science and Higher Education of the Russian Federation (Project No. 121031700321-3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. S. Pronin & Y. V. Mironov

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  1. A. S. Pronin
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  2. Y. V. Mironov
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Correspondence to Y. V. Mironov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2179–2186, October, 2022.

We are grateful to A. I. Smolentsev for performing X-ray diffraction analysis.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Pronin, A.S., Mironov, Y.V. New inorganic ligand μ3-[SbO(H2O)2]3− in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se). Russ Chem Bull 71, 2179–2186 (2022). https://doi.org/10.1007/s11172-022-3644-6

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  • DOI: https://doi.org/10.1007/s11172-022-3644-6

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