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First chiral phosphite with a quaternary ammonium fragment: Synthesis and use in Rh-catalyzed asymmetric hydrogenation

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Abstract

The first representative of chiral P-monodentate phosphite ligands containing quaternary ammonium substituents and its rhodium complex [Rh(COD)(L)2]BF4 (COD is 1,5-cycloctadiene) were obtained. The use of this ligand in Rh-catalyzed asymmetric hydrogenation of prochiral methyl esters of unsaturated acids allowed one to achieve optical yields up to 99%.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, V. A. Davankov, P. M. Valetskii & P. V. Petrovskii

  2. S. A. Esenin Ryazan State University, 46 ul. Svobody, 390000, Ryazan, Russian Federation

    M. G. Maksimova & K. N. Gavrilov

Authors
  1. S. E. Lyubimov
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  2. V. A. Davankov
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  3. P. M. Valetskii
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  4. P. V. Petrovskii
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  5. M. G. Maksimova
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  6. K. N. Gavrilov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1395–1398, August, 2006.

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Lyubimov, S.E., Davankov, V.A., Valetskii, P.M. et al. First chiral phosphite with a quaternary ammonium fragment: Synthesis and use in Rh-catalyzed asymmetric hydrogenation. Russ Chem Bull 55, 1448–1451 (2006). https://doi.org/10.1007/s11172-006-0438-1

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  • DOI: https://doi.org/10.1007/s11172-006-0438-1

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