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Facile formation of exo-nido→closo-rearrangement products upon the replacement of PPh3 ligands with bis(diphenylphosphino)alkanes in “three-bridge” ruthenacarborane 5,6,10-[RuCl(PPh3)2]-5,6,10-(µ-H)3-10-H-exo-nido-7,8-C2B9H8

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Abstract

The replacement of the PPh3 ligands in “three-bridge” exo-nido-ruthenacarborane 5,6,10-[RuCl(PPh3)2]-5,6,10-(µ-H)3-10-H-exo-nido-7,8-C2B9H8 with diphosphines, viz., 1,3-bis(diphenylphosphino)propane (dppp) or 1,4-bis(diphenylphosphino)butane (dppb) dramatically decreases the barrier to the thermal exo-nido→closo rearrangement affording the chelate closo-complexes 3,3-[Ph2P(CH2)nPPh2]-3-H-3-Cl-closo-3,1,2-RuC2B9H11 (n = 3 or 4) under mild conditions. In the reaction with dppp, the rearrangement is accompanied by the formation of 17-electron paramagnetic closo-ruthenacarborane 3,3-[Ph2P(CH2)3PPh2]-3-Cl-closo-3,1,2-RuC2B9H11, which could be isolated as the main product when the reaction was carried out at 80 °C.

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References

  1. I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, P. V. Petrovskii, A. V. Polyakov, A. I. Yanovsky, and Yu. T. Struchkov, Metalloorg. Khim., 1991, 4, 957 [Organomet. Chem. USSR, 1991, 4, 469 (Engl. Transl.)].

    Google Scholar 

  2. G. D. Kolomnikova, P. V. Sorokin, I. T. Chizhevsky, P. V. Petrovskii, V. I. Bregadze, F. M. Dolgushin, and A. I. Yanovsky, Izv. Akad. Nauk, Ser. Khim., 1997, 2076 [Russ. Chem. Bull., 1997, 46, 1971 (Engl. Transl.)].

  3. I. A. Lobanova, I. T. Chizhevsky, P. V. Petrovskii, and V. I. Bregadze, Izv. Akad. Nauk, Ser. Khim., 1996, 250 [Russ. Chem. Bull., 1996, 45, 241 (Engl. Transl.)].

    Google Scholar 

  4. D. D. Ellis, S. M. Couchman, J. C. Jeffery, J. M. Malget, and F. G. A. Stone, Inorg. Chem., 1999, 38, 2981.

    Article  CAS  Google Scholar 

  5. I. T. Chizhevsky, I. A. Lobanova, P. V. Petrovskii, V. I. Bregadze, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, A. L. Chistyakov, I. V. Stankevich, C. B. Knobler, and M. F. Hawthorne, Organometallics, 1999, 18, 726.

    Article  CAS  Google Scholar 

  6. J. A. Long, T. B. Marder, P. E. Behnken, and M. F. Hawthorne, J. Am. Chem. Soc., 1984, 106, 2979.

    CAS  Google Scholar 

  7. I. T. Chizhevsky, I. A. Lobanova, V. I. Bregadze, P. V. Petrovskii, V. A. Antonovich, A. V. Polyakov, A. I. Yanovsky, and Yu. T. Struchkov, Mendeleev Commun., 1991, 47.

  8. I. V. Pisareva, F. M. Dolgushin, O. L. Tok, V. E. Konoplev, K. Yu. Suponitsky, A. I. Yanovsky, and I. T. Chizhevsky, Organometallics, 2001, 20, 4216.

    Article  CAS  Google Scholar 

  9. G. D. Kolomnikova, P. V. Petrovskii, P. V. Sorokin, F. M. Dolgushin, A. I. Yanovsky, and I. T. Chizhevsky, Izv. Akad. Nauk, Ser. Khim., 2001, 677 [Russ. Chem. Bull., Int. Ed., 2001, 50, 706].

    Google Scholar 

  10. D. N. Cheredilin, F. M. Dolgushin, E. V. Balagurova, I. A. Godovikov, and I. T. Chizhevsky, Izv. Akad. Nauk, Ser. Khim., 2004, 2000 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2086].

    Google Scholar 

  11. D. N. Cheredilin, R. Kadyrov, F. M. Dolgushin, E. V. Balagurova, I. A. Godovikov, S. P. Solodovnikov, and I. T. Chizhevsky, Inorg. Chem. Commun., 2005, 8, 614.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. N. Cheredilin, E. V. Balagurova, I. A. Godovikov, S. P. Solodovnikov & I. T. Chizhevsky

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  1. D. N. Cheredilin
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  2. E. V. Balagurova
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  3. I. A. Godovikov
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  4. S. P. Solodovnikov
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  5. I. T. Chizhevsky
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2455–2459, November, 2005.

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Cheredilin, D.N., Balagurova, E.V., Godovikov, I.A. et al. Facile formation of exo-nido→closo-rearrangement products upon the replacement of PPh3 ligands with bis(diphenylphosphino)alkanes in “three-bridge” ruthenacarborane 5,6,10-[RuCl(PPh3)2]-5,6,10-(µ-H)3-10-H-exo-nido-7,8-C2B9H8 . Russ Chem Bull 54, 2535–2539 (2005). https://doi.org/10.1007/s11172-006-0151-0

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  • DOI: https://doi.org/10.1007/s11172-006-0151-0

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