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Molecular Characteristics of Star-Like Polyvinylpyrrolidone with Fullerene C60 as the Branching Site in Dilute Solutions

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

Star-like water-soluble macromolecules with fullerene as the branching site were synthesized by the reaction of fullerene C60 with polyvinylpyrrolidone whose molecules contain one terminal primary amino group. The initial and C60-containing polymers were studied by UV spectroscopy, thin-layer chromatography, centrifugal sedimentation, translation diffusion, and viscometry in aqueous buffer solutions. Diffusion-sedimentation and sedimentation two-detector analyses of the initial and fullerene-containing samples were performed. The molecular weights of the polymers were estimated by the Svedberg equation. The proportion of the fullerene-containing segment in the samples synthesized was determined, and the number of the branches in the fullerene-containing macromolecules was estimated.

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Authors and Affiliations

  1. Fock Research Institute of Physics, St. Petersburg State University, St. Petersburg, Russia

    G. M. Pavlov, O. V. Nazarova, C. Ebel, N. A. Mikhailova, I. I. Zaitseva, S. N. Bokov, L. S. Litvinova, E. V. Afanas’eva, E. V. Korneeva & E. F. Panarin

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    G. M. Pavlov, O. V. Nazarova, C. Ebel, N. A. Mikhailova, I. I. Zaitseva, S. N. Bokov, L. S. Litvinova, E. V. Afanas’eva, E. V. Korneeva & E. F. Panarin

  3. Laboratoire de Biophysique Moleculaire, Institut de Biologie Structurale, Grenoble, France

    G. M. Pavlov, O. V. Nazarova, C. Ebel, N. A. Mikhailova, I. I. Zaitseva, S. N. Bokov, L. S. Litvinova, E. V. Afanas’eva, E. V. Korneeva & E. F. Panarin

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  1. G. M. Pavlov
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  2. O. V. Nazarova
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  3. C. Ebel
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  4. N. A. Mikhailova
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  6. S. N. Bokov
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  7. L. S. Litvinova
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  8. E. V. Afanas’eva
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  9. E. V. Korneeva
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  10. E. F. Panarin
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__________

Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 1, 2005, pp. 132–138.

Original Russian Text Copyright © 2005 by Pavlov, Nazarova, Ebel, Mikhailova, Zaitseva, Bokov, Litvinova, Afanas’eva, Korneeva, Panarin.

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Pavlov, G.M., Nazarova, O.V., Ebel, C. et al. Molecular Characteristics of Star-Like Polyvinylpyrrolidone with Fullerene C60 as the Branching Site in Dilute Solutions. Russ J Appl Chem 78, 130–136 (2005). https://doi.org/10.1007/s11167-005-0244-9

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  • DOI: https://doi.org/10.1007/s11167-005-0244-9

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