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Preparation and application of ZnFe2O4@SiO2–SO3H, as a novel heterogeneous acidic magnetic nanocatalyst for the synthesis of tetrahydrobenzo[b]pyran and 2,3-dihydroquinazolin-4(1H)-one derivative

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Abstract

In this work, we report the synthesis and identification of ZnFe2O4@SiO2–SO3H as a novel and green nanomagnetic solid acid catalyst, which is containing the sulfuric acid catalytic sites on the surface of ZnFe2O4 magnetic nanoparticles as the catalytic support. The as-synthesized ZnFe2O4@SiO2–SO3H MNPs were characterized with accuracy by different physicochemical methods; including, X-ray powder diffraction, energy-dispersive spectroscopy, Scanning electron microscopy, Fourier transform infrared, X-ray elemental mapping, Thermogravimetric analysis, and Vibrating Sample Magnetometer analyses. The catalytic activity of this nanomagnetic material is considered for the synthesis of the diversely substituted tetrahydrobenzo[b]pyran and DHQZ (2,3-dihydroquinazolin-4(1H)-ones) in ethanol solvent, which affording excellent yields (86–97%). The heterogeneous nature of the catalyst was confirmed via the hot filtration experiment. Furthermore, the activity of the recycled nanocatalyst was examined for at least five cycles with a negligible loss of its activity (97–92%). Also, the amount of sulfamic acid function in the ZnFe2O4@SiO2–SO3H was calculated from back titration.

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Acknowledgements

The authors thank the research facilities of Bu-Ali Sina University, Hamedan, Iran, for financial support of this research project.

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  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

    Hamid Aghavandi & Arash Ghorbani-Choghamarani

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  1. Hamid Aghavandi
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AG-C: Supervision, Conceptualization, Resources, Writing—review and editing. HA: Methodology, Conceptualization, Writing—original draft.

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Correspondence to Arash Ghorbani-Choghamarani.

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Aghavandi, H., Ghorbani-Choghamarani, A. Preparation and application of ZnFe2O4@SiO2–SO3H, as a novel heterogeneous acidic magnetic nanocatalyst for the synthesis of tetrahydrobenzo[b]pyran and 2,3-dihydroquinazolin-4(1H)-one derivative. Res Chem Intermed 49, 441–467 (2023). https://doi.org/10.1007/s11164-022-04890-8

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