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Pd(OAc)2 immobilized on imine-functionalized microporous covalent triazine polymer as efficient heterogeneous catalyst for Mizoroki–Heck cross-coupling reaction

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Abstract

A template consisting of Pd(OAc)2 immobilized on imine-functionalized microporous covalent triazine polymer network (Pd/TATAE) was synthesized and found to be an efficient and recyclable heterogeneous solid catalyst for Mizoroki–Heck C–C coupling of styrene with substituted aryl halides under mild reaction conditions and without addition of any ligand or additives. Furthermore, Pd/TATAE could be recycled for nine consecutive cycles with minor loss of catalytic activity. Finally, the Pd/TATAE catalyst showed good catalytic activity with excellent yield of 96 % and high turnover number of 3349.

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Acknowledgments

A.S. and V.S. acknowledge financial support from the Department of Science and Technology, SERB, Extramural Major Research Project (grant no. EMR/2015/000969), Council of Scientific and Industrial Research (CSIR), HRDG (no. 01(2901)/17/EMR-II), New Delhi, and the Department of Science and Technology DST/TM/CERI/C130(G), New Delhi, India.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, School of Chemistry, Supramolecular and Organometallic Chemistry Lab, Madurai Kamaraj University, Madurai, Tamil Nadu, 625021, India

    Velu Sadhasivam, Mariyappan Mathappan, Muniyasamy Harikrishnan, Chinnadurai Chithiraikumar, Sepperumal Murugesan & Ayyanar Siva

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  1. Velu Sadhasivam
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  2. Mariyappan Mathappan
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  3. Muniyasamy Harikrishnan
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  6. Ayyanar Siva
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Correspondence to Ayyanar Siva.

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Sadhasivam, V., Mathappan, M., Harikrishnan, M. et al. Pd(OAc)2 immobilized on imine-functionalized microporous covalent triazine polymer as efficient heterogeneous catalyst for Mizoroki–Heck cross-coupling reaction. Res Chem Intermed 44, 2853–2866 (2018). https://doi.org/10.1007/s11164-018-3265-8

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