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Aminoclay decorated with nano-Pd(0) picolinic acid complex as a novel efficient, heterogeneous, and phosphine ligand-free catalyst in Heck reaction under solvent-free conditions

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Abstract

A new heterogeneous phosphine ligand-free nano-Pd(0) picolinic acid complex was synthesized under mild and ecofriendly conditions with a short and simple process in green solvent. In this work, as a novel functionalization method, the surface of aminoclay was decorated via ionic bond formation between the picolinic acid complex of nano-Pd(0) and the amino group on its surface. Then, the prepared heterogeneous catalyst was characterized by TEM, FE-SEM, ICP, IR, XRD, TGA, EDX, XPS and UV–visible techniques and was subsequently employed as an efficient and reusable heterogeneous catalyst for selective Heck coupling of aryl halide and n-butyl acrylate under solvent-free conditions. The catalyst was recoverable simply by centrifuging and was reusable for at least seven runs with a minimum amount of palladium leaching. Also, the mercury poisoning test confirmed the heterogenous nature of the catalyst.

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Acknowledgement

We gratefully acknowledge the support of this work by Shiraz University Research Council.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71946- 84795, Iran

    Nafiseh Fahimi & Ali Reza Sardarian

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  1. Nafiseh Fahimi
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  2. Ali Reza Sardarian
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Correspondence to Ali Reza Sardarian.

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Fahimi, N., Sardarian, A.R. Aminoclay decorated with nano-Pd(0) picolinic acid complex as a novel efficient, heterogeneous, and phosphine ligand-free catalyst in Heck reaction under solvent-free conditions. Res Chem Intermed 43, 4923–4941 (2017). https://doi.org/10.1007/s11164-017-2921-8

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