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Nano-manganese hydrogen sulfate as a novel catalyst for the anti-diastereoselective Mannich reaction in water

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Abstract

β-Amino carbonyl compounds are attractive targets for chemical synthesis, because they are widely used as biologically active compounds and are important synthons for a variety of pharmaceuticals. Nano-manganese hydrogen sulfate was prepared and used as a novel nano-catalyst for the named organic transformation, i.e. Mannich-type reaction of benzaldehyde, aniline, and cyclohexanone in water. Mannich products were obtained in high yields, with excellent diastereoselectivity, and short reaction time in the presence of a catalytic system comprising nano-Mn(HSO4)2 and a surfactant, for example sodium dodecyl sulfate. Use of mild, environmentally benign reaction conditions, low loading, and ready accessibility are the main features of this new catalyst.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, 91775-1436, Mashhad, Iran

    H. Eshghi, M. Rahimizadeh, A. Javadian-Saraf & M. Hosseini

Authors
  1. H. Eshghi
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  2. M. Rahimizadeh
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  3. A. Javadian-Saraf
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  4. M. Hosseini
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Correspondence to H. Eshghi.

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Eshghi, H., Rahimizadeh, M., Javadian-Saraf, A. et al. Nano-manganese hydrogen sulfate as a novel catalyst for the anti-diastereoselective Mannich reaction in water. Res Chem Intermed 41, 5049–5058 (2015). https://doi.org/10.1007/s11164-014-1587-8

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