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Novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex: synthesis, spectral, thermal, and crystal structure studies

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Abstract

A novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex has been prepared by reacting CdCl2·2.5H2O with 4,7-dimethyl-1,10-phenanthroline (dmphen) ligand. The complex was characterized on the basis of elemental analysis, FAB-MS, IR, UV–visible, 1H, and 13C NMR spectroscopy, TG/DTA, and X-ray single-crystal diffraction studies. The Cd(II) ions in [CdCl2(C14H12N2)]2 are coordinated to three Cl atoms with the centrosymmetric dimer bridged through the Cl atoms and two N atoms in a slightly distorted square-pyramidal disposition. Several hydrogen bonds formed between the terminal Cl atoms and H-Me/H-Ph groups may stabilize the structure in the dimer form.

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Acknowledgments

The project was supported by King Saud University, Deanship of Scientific Research, College of Science Research Center.

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Authors and Affiliations

  1. Department of Chemistry, Science College, King Saud University, P. O. Box 2455, Riyadh, 11451, Saudi Arabia

    Ismail Warad

  2. Department of Chemistry, College of Science, University of Hail, P. O. Box 2440, Hail, Saudi Arabia

    Maha Al-Ali

  3. LCAE-URAC18, Faculté des Sciences, Université Mohammed Ier, 60000, Oujda, Morocco

    Belkheir Hammouti

  4. Laboratoire Chimie Matériaux, FSO, Université Mohammed Ier, 60000, Oujda, Morocco

    Taibi Ben Hadda

  5. Department of Basic Science, Allied Medical Science College, Applied Science Private University, P. O. Box 166, Amman, 11931, Jordan

    Rami Shareiah

  6. Laboratoire de Chimie des Matériaux, Facultédes Sciences de Bizerte, 7021, Zarzouna Bizerte, Tunisia

    Mohamed Rzaigui

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  1. Ismail Warad
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  2. Maha Al-Ali
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  3. Belkheir Hammouti
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  4. Taibi Ben Hadda
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  5. Rami Shareiah
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  6. Mohamed Rzaigui
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Correspondence to Ismail Warad.

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Warad, I., Al-Ali, M., Hammouti, B. et al. Novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex: synthesis, spectral, thermal, and crystal structure studies. Res Chem Intermed 39, 2451–2461 (2013). https://doi.org/10.1007/s11164-012-0771-y

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