Abstract
In this study, zinc oxide (ZnO) crystals were obtained by a simple wet chemical method using zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and hexamethylenetetramine as the starting materials in the presence of the water-soluble biopolymer carboxymethyl inulin (CMI). We investigated the effect of reaction temperature and CMI concentration on the morphology, surface area, particle size, and size distribution of zinc oxide. X-ray diffraction analysis showed the XRD patterns for all the samples were similar to that of ZnO with the wurtzite structure, irrespective of the geometric shape of the particle. The ZnO rod grows preferentially along the [001] direction in the absence of the CMI. The biopolymer affects the ZnO crystals in a concentration-dependent manner by altering the growth rate of the particles along the c-axis and a-axis. The vast majority of the crystals have a central grain boundary in the presence of CMI. The precipitate consisted of micrometer-sized hexagonally shaped bipyramidal ZnO crystals and nanocrystals.
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P. Samarasekara, N. Yapa, N. Kumara, M. Perera, Bull. Mater. Sci. 30, 113 (2007)
M. Ghosh, R. Bhattacharyya, A. Raychaudhuri, Bull. Mater. Sci. 31, 283 (2008)
S. Fujihara, H. Naito, T. Kimura, Thin Solid Films 389, 227 (2001)
A. Degen, M. Kosec, J. Eur. Ceram. Soc. 20, 667 (2000)
J. Wrzesinski, D. Fröhlich, Solid State Commun. 105, 301 (1998)
S. Kashyap, K. Chopra, B. Bhushan, Bull. Mater. Sci. 9, 169 (1987)
K. Byrappa, A. Subramani, S. Ananda, K. Rai, R. Dinesh, M. Yoshimura, Bull. Mater. Sci. 29, 433 (2006)
W.F. Elseviers, H. Verelst, Fuel 78, 601 (1999)
F.A. Sigoli, M.R. Davolos, M. Jafelicci Jr., J. Alloy Compd. 262–263, 292 (1997)
O. Yamamoto, Int. J. Inorg. Mater. 3, 643 (2001)
H. Akiyama, O. Yamasaki, H. Kanzaki, J. Tada, J. Arata, J. Dermatol. Sci. 17, 67 (1998)
M.J. Zheng, L.D. Zhang, G.H. Li, W.Z. Shen, Chem. Phys. Lett. 363, 123 (2002)
S. Ohara, T. Mousavand, M. Umetsu, S. Takami, T. Adschiri, Y. Kuroki, M. Takata, Solid State Ionics 172, 261 (2004)
W.-T. Chiou, W.-Y. Wu, J.-M. Ting, Diam. Relat. Mater. 12, 1841 (2003)
M. Izaki, T. Omi, Appl. Phys. Lett. 68, 2439 (1996)
J.E. Rodriguez-Paez, A.C. Caballero, M. Villegas, C. Moure, P. Duran, J.F. Fernandez, J. Eur. Ceram. Soc. 21, 925 (2001)
S. Komarneni, M. Bruno, E. Mariani, Mater. Res. Bull. 35, 1843 (2000)
C.-H. Lu, C.-H. Yeh, Ceram. Int. 26, 351 (2000)
D. Chen, X. Jiao, G. Cheng, Solid State Commun. 113, 363 (1999)
E. Reverchon, G. Della Porta, D. Sannino, P. Ciambelli, Powder Technol. 102, 127 (1999)
C.-H. Lu, C.-H. Yeh, Mater. Lett. 33, 129 (1997)
B.P. Lim, J. Wang, S.C. Ng, C.H. Chew, L.M. Gan, Ceram. Int. 24, 205 (1998)
Q. Zhong, E. Matijevic, J. Mater. Chem. 6, 443 (1996)
M. Öner, J. Norwig, W.H. Meyer, G. Wegner, Chem. Mater. 10, 460 (1998)
A. Taubert, G. Glasser, D. Palms, Langmuir 18, 4488 (2002)
A. Taubert, D. Palms, Ö. Weiss, M.-T. Piccini, D.N. Batchelder, Chem. Mater. 14, 2594 (2002)
X. Liu, Z. Jin, S. Bu, J. Zhao, Z. Liu, J. Am. Ceram. Soc. 89, 1226 (2006)
P. Yang, H. Yan, S. Mao, R. Russo, J. Johnson, R. Saykally, N. Morris, J. Pham, R. He, H.J. Choi, Adv. Funct. Mater. 12, 323 (2002)
Z.L. Wang, J. Phys. Condens. Matter 16, R829 (2004)
J.M. Marentette, J. Norwig, E. Stöckelmann, W.H. Meyer, Adv. Mater. 9, 647 (1997)
L. Qi, H. Cölfen, M. Antonietti, Chem. Mater. 12, 2392 (2000)
P.G. Klepetsanis, P.G. Koutsoukos, J. Cryst. Growth 193, 156 (1998)
E. Akyol, M. Öner, E. Barouda, K.D. Demadis, Cryst. Growth Des. 9, 5145 (2009)
Ö. Dogan, M. Öner, Langmuir 22, 9671 (2006)
S. Kırboga, M. Öner, Cryst. Growth Des. 9, 2159 (2009)
G. Wegner, P. Baum, M. Müller, J. Norwig, K. Landfester, Macromol. Symp. 175, 349 (2001)
A. Taubert, C. Kübel, D.C. Martin, J. Phys. Chem. B. 107, 2660 (2003)
H. Cölfen, M. Antonietti, Langmuir 14, 582 (1998)
H. Cölfen, Macromol. Rapid Commun. 22, 219 (2001)
L. Qi, H. Cölfen, M. Antonietti, M. Li, J.D. Hopwood, A.J. Ashley, S. Mann, Chem. Eur. J. 7, 3526 (2001)
A. Bigi, E. Boanini, G. Cojazzi, G. Falini, S. Panzavolta, Cryst. Growth Des. 1, 239 (2001)
S. Kırboga, M. Öner, Colloid Surf B. 78, 357 (2010)
R. Munoz-Espí, Y. Qi, I. Lieberwirth, C.M. Gomez, G. Wegner, Chem. Eur. J. 12, 118 (2006)
F.R. Johannsen, Food Chem. Toxicol. 41, 49 (2003)
D. Verraest, J. Peters, H. van Bekkum, G. van Rosmalen, J. Am. Oil Chem. Soc. 73, 55 (1996)
B. Akin, M. Öner, Y. Bayram, K.D. Demadis, Cryst. Growth Des. 8, 1997 (2008)
Ö. Dogan, M. Öner, Ö. Cinel, J. Ceram. Soc. Jpn. 118, 579 (2010)
K.D. Demadis, E. Mavredaki, A. Stathoulopoulou, E. Neofotistou, C. Mantzaridis, Desalination 213, 38 (2007)
P.T. Anastas, J.C. Warner, Green chemistry: theory and practice (Oxford University Press, New York, 1998)
K. Lu, J. Zhao, Chem. Eng. J. 160, 788 (2010)
P.-Y. Wu, J. Pike, F. Zhang, S.-W. Chan, Int. J. Appl. Ceram. Tec. 3, 272 (2006)
M. Wang, S.H. Hahn, J.S. Kim, J.S. Chung, E.J. Kim, K.-K. Koo, J. Cryst. Growth 310, 1213 (2008)
S. Cho, J.-W. Jang, J.S. Lee, K.-H. Lee, Langmuir 26, 14255 (2010)
M.-K. Liang, O. Deschaume, S.V. Patwardhan, C.C. Perry, J. Mater. Chem. 21, 80 (2011)
S. Music, D. Dragcevic, M. Maljkovic, S. Popovic, Mater. Chem. Phys. 77, 521 (2003)
D. Li, H. Haneda, Chemosphere 51, 129 (2003)
H.P. Klug, L.E. Alexander, X-ray diffraction procedures for polycrystalline and amorphous materials (John Wiley, New York, 1974)
J.-M. Oh, S.-H. Hwang, J.-H. Choy, Solid State Ionics 151, 285 (2002)
L. Addadi, S. Weiner, PNAS 82, 4110 (1985)
L. Addadi, Z. Berkovitch-Yellin, I. Weissbuch, J. Van Mil, L.J.W. Shimon, M. Lahav, Angew. Chem. Int. Edit. 24, 466 (1985)
S. Golovko, R. Munoz-Espí, G. Wegner, Langmuir 23, 3566 (2007)
Acknowledgments
We thank YTUAF (project no: 29-07-01-ODAP01) for their support of this work. The authors thank Dr. Andrew Cutler for valuable discussions.
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Akin, B., Oner, M. Aqueous pathways for formation of zinc oxide particles in the presence of carboxymethyl inulin. Res Chem Intermed 38, 1511–1525 (2012). https://doi.org/10.1007/s11164-011-0481-x
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DOI: https://doi.org/10.1007/s11164-011-0481-x