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Hydrogenolysis of glycerol to 1,3-propanediol over Li2B4O7-modified tungsten–zirconium composite oxides supported platinum catalyst

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Abstract

A series of Pt–yLi2B4O7/WOx/ZrO2 (y = 0, 0.5, 1, 2 wt%) catalysts were prepared by varying the content of Li2B4O7 through the method of coimpregnation-calcination. The obtained catalysts were used for the selective hydrogenolysis of glycerol to 1,3-propanediol. Meanwhile, these catalysts were characterized by N2 adsorption and desorption (BET), CO chemisorption, X-ray diffraction (XRD), NH3-temperature programmed desorption (NH3-TPD), H2-temperature programmed reduction (H2-TPR), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). The results showed that Pt–1Li2B4O7/WOx/ZrO2 achieved the highest activity with glycerol conversion of 90.7% at 150 °C and 4 MPa and exhibited excellent stability over 200 h. Pt/WOx/ZrO2 catalyst modified with Li2B4O7 was able to enhance catalytic activity and stability, since Li2B4O7 promoted the dispersion of Pt, increased the acid amount of the catalyst and strengthened the interaction between active components and support.

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References

  1. Wang YL, Zhou JX, Guo XW (2015) RSC Adv 5:74611–74628

    Article  CAS  Google Scholar 

  2. Zhu SH, Zhu YL, Hao SL, Zheng HY, Mo T, Li YW (2012) Green Chem 14:2607–2616

    Article  CAS  Google Scholar 

  3. Ruppert AM, Weinberg K, Palkovits R (2012) Angew Chem 51:2564–2601

    Article  CAS  Google Scholar 

  4. Boffito DC, Neagoe C, Edake M, Pastor-Ramirez B, Patience GS (2014) Catal Today 237:13–17

    Article  CAS  Google Scholar 

  5. Nakagawa Y, Tomishige K (2011) Catal Sci Technol 1:179–190

    Article  CAS  Google Scholar 

  6. Liu LJ, Zhang YH, Wang AQ, Zhang T (2012) Chin J Catal 33:1257–1261

    Article  CAS  Google Scholar 

  7. Nakagawa Y, Shinmi Y, Koso S, Tomishige K (2010) J Catal 272:191–194

    Article  CAS  Google Scholar 

  8. Lee CS, Aroua MK, Daud WMAW, Cognet P, Pérès-Lucchese Y, Fabre PL, Reynes O, Latapie L (2015) Renew Sust Energy Rev 42:963–972

    Article  CAS  Google Scholar 

  9. Zhang YH, Zhao X-C, Wang Y, Zhou LK, Zhang JY, Wang J, Wang AQ, Zhang T (2013) J Mater Chem A 1:3724–3732

    Article  CAS  Google Scholar 

  10. Zheng SN, Zhu KN, Li W, Ji Y (2017) New J Chem 41:5752–5763

    Article  CAS  Google Scholar 

  11. Kurian JV (2005) J Polym Environ 13:159–167

    Article  CAS  Google Scholar 

  12. Mizugaki T, Yamakawa T, Arundhathi R, Mitsudome T, Jitsukawa K, Kaneda K (2012) Chem Lett 41:1720–1722

    Article  Google Scholar 

  13. Priya SS, Bhanuchander P, Kumar VP, Bhargava SK, Chary KVR (2016) Ind Eng Chem Res 55:4461–4472

    Article  CAS  Google Scholar 

  14. Ding TM, Tian HS, Zhao BQ (2016) React Kinet Mech Cat 118:497–508

    Article  CAS  Google Scholar 

  15. García-Fernández S, Gandarias I, Requies J, Soulimani F, Arias PL, Weckhuysen BM (2017) Appl Catal B Environ 204:260–272

    Article  CAS  Google Scholar 

  16. Kurosaka T, Maruyama H, Naribayashi I, Sasaki Y (2008) Catal Commun 9:1360–1363

    Article  CAS  Google Scholar 

  17. Fan YQ, Cheng SJ, Wang H, Ye DH, Xie SH, Pei Y, Hu HR, Hua WM, Li ZH, Qiao MH, Zong BN (2017) Green Chem 19:2174–2183

    Article  CAS  Google Scholar 

  18. Wang J, Lei N, Yang CJ, Su Y, Zhao XC, Wang AQ (2016) Chin J Catal 37:1513–1519

    Article  CAS  Google Scholar 

  19. Priya SS, Kumar VP, Kantam ML, Bhargava SK, Chary KVR (2014) Catal Lett 144:2129–2143

    Article  CAS  Google Scholar 

  20. Zhu SH, Zhu YL, Hao SL, Chen LG, Zhang B, Li YW (2012) Catal Lett 142:267–274

    Article  CAS  Google Scholar 

  21. Qin L-Z, Song M-J, Chen C-L (2010) Green Chem 12:1466–1472

    Article  CAS  Google Scholar 

  22. Edake M, Dalil M, Darabi Mahboub MJ, Dubois J-L, Patience GS (2017) RSC Adv 7:3853–3860

    Article  CAS  Google Scholar 

  23. García-Fernández S, Gandarias I, Tejido-Núñez Y, Requies J, Arias PL (2017) ChemCatChem 24:4508–4519

    Article  CAS  Google Scholar 

  24. Zhu SH, Gao XQ, Zhu YL, Li YW (2015) J Mol Catal A Chem 398:391–398

    Article  CAS  Google Scholar 

  25. Oh J, Dash S, Lee H (2011) Green Chem 13:2004–2007

    Article  CAS  Google Scholar 

  26. Pamphile-Adrián AJ, Florez-Rodriguez PP, Pires MHM, Perez G, Passos FB (2017) Catal Today 289:302–308

    Article  CAS  Google Scholar 

  27. Deng CH, Duan XZ, Zhou JH, Zhou XG, Yuan WK, Scott SL (2015) Catal Sci Technol 5:1540–1547

    Article  CAS  Google Scholar 

  28. Nakagawa Y, Ning X, Amada Y, Tomishige K (2012) Appl Catal A Gen 433–434:128–134

    Article  CAS  Google Scholar 

  29. Luo WT, Lyu Y, Gong LF, Du H, Wang T, Ding YJ (2016) RSC Adv 6:13600–13608

    Article  CAS  Google Scholar 

  30. Huang L, Zhu YL, Zheng HY, Ding GQ, Li YW (2009) Catal Lett 131:312–320

    Article  CAS  Google Scholar 

  31. Feng YH, Yin HB, Wang AL, Shen LQ, Yu LB, Jiang TS (2011) Chem Eng J 168:403–412

    Article  CAS  Google Scholar 

  32. Geng GL, Wei RP, Liang T, Zhou MH, Xiao GM (2015) React Kinet Mech Cat 117:239–251

    Article  CAS  Google Scholar 

  33. Niu L, Wei RP, Li C, Gao LJ, Zhou MH, Jiang F, Xiao GM (2015) React Kinet Mech Cat 115:377–388

    Article  CAS  Google Scholar 

  34. Zhou JX, Guo LY, Guo XW, Mao JB, Zhang SG (2010) Green Chem 12:1835–1843

    Article  CAS  Google Scholar 

  35. Zhu SH, Qiu YA, Zhu YL, Hao SL, Zheng HY, Li YW (2013) Catal Today 212:120–126

    Article  CAS  Google Scholar 

  36. García-Fernández S, Gandarias I, Requies J, Güemez MB, Bennici S, Auroux A, Arias PL (2015) J Catal 323:65–75

    Article  CAS  Google Scholar 

  37. Fan YQ, Cheng SJ, Wang H, Tian J, Xie SH, Pei Y, Qiao MH, Zong BN (2017) Appl Catal B Environ 217:331–341

    Article  CAS  Google Scholar 

  38. Luo WT, Lyu Y, Gong LF, Du H, Jiang M, Ding YJ (2016) React Kinet Mech Cat 118:481–496

    Article  CAS  Google Scholar 

  39. Arundhathi R, Mizugaki T, Mitsudome T, Jitsukawa K, Kaneda K (2013) ChemSusChem 6:1345–1347

    Article  CAS  PubMed  Google Scholar 

  40. Zhu SH, Gao XQ, Zhu YL, Zhu YF, Xiang XM, Hu CX, Li YW (2013) Appl Catal B Environ 140–141:60–67

    Article  CAS  Google Scholar 

  41. Zhu SH, Gao XQ, Zhu YL, Cui JL, Zheng HY, Li YW (2014) Appl Catal B Environ 158–159:391–399

    Article  CAS  Google Scholar 

  42. Zhu SH, Gao XQ, Zhu YL, Zhu YF, Zheng HY, Li YW (2013) J Catal 303:70–79

    Article  CAS  Google Scholar 

  43. Checa M, Marinas A, Marinas JM, Urbano FJ (2015) Appl Catal A Gen 507:34–43

    Article  CAS  Google Scholar 

  44. Xiong HF, Schwartz TJ, Andersen NI, Dumesic JA, Datye AK (2015) Angew Chem 54:7939–7943

    Article  CAS  Google Scholar 

  45. Pham HN, Anderson AE, Johnson RL, Schwartz TJ, O’Neill BJ, Duan P, Schmidt-Rohr K, Dumesic JA, Datye AK (2015) ACS Catal 5:4546–4555

    Article  CAS  Google Scholar 

  46. Robertson DS, Young IM (1982) J Mater Sci 17:1729–1738

    Article  CAS  Google Scholar 

  47. Mohandoss R, Dhanuskodi S, Renganathan B, Sastikumar D (2013) Curr Appl Phys 13:957–963

    Article  Google Scholar 

  48. Ozdemir A, Altunal V, Kurt K, Depci T, Yu Y, Lawrence Y, Nur N, Guckan V, Yegingil Z (2017) Radiat Phys Chem 141:352–362

    Article  CAS  Google Scholar 

  49. Celik MG, Yilmaz A, Yazici AN (2017) Radiat Meas 102:16–26

    Article  CAS  Google Scholar 

  50. Barton DG, Soled SL, Iglesia E (1998) Top Catal 6:87–99

    Article  CAS  Google Scholar 

  51. Hadjiivanov K, Lukinskas P, Knözinger H (2002) Catal Lett 82:73–77

    Article  CAS  Google Scholar 

  52. Xi YJ, Zhang QF, Cheng HS (2013) J Phys Chem C 118:494–501

    Article  CAS  Google Scholar 

  53. Ebitani K, Hattori H (1991) B Chem Soc Jpn 64:2422–2427

    Article  CAS  Google Scholar 

  54. Zhigadlo ND, Zhang M, Salje EKH (2001) J Phys Condens Mat 13:6551–6561

    Article  CAS  Google Scholar 

  55. Priya SS, Bhanuchander P, Kumar VP, Dumbre DK, Periasamy SR, Bhargava SK, Lakshmi Kantam M, Chary KVR (2016) ACS Sustain Chem Eng 4:1212–1222

    Article  CAS  Google Scholar 

  56. Gong LF, Lu Y, Ding YJ, Lin RH, Li JW, Dong WD, Wang T, Chen WM (2010) Appl Catal A Gen 390:119–126

    Article  CAS  Google Scholar 

  57. Nimlos MR, Blanksby SJ, Qian XH, Himmel ME, Johnson DK (2006) J Phys Chem A 110:6145–6156

    Article  CAS  PubMed  Google Scholar 

  58. Triwahyono S, Yamada T, Hattori H (2003) Appl Catal A Gen 242:101–109

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Financial support by the Research and Development of Prospective Research Project of Jiangsu Province, China (BY2015005-08) is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 210009, Jiangsu, China

    Min Zhu & Changlin Chen

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  1. Min Zhu
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  2. Changlin Chen
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Correspondence to Changlin Chen.

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Zhu, M., Chen, C. Hydrogenolysis of glycerol to 1,3-propanediol over Li2B4O7-modified tungsten–zirconium composite oxides supported platinum catalyst. Reac Kinet Mech Cat 124, 683–699 (2018). https://doi.org/10.1007/s11144-018-1379-z

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  • DOI: https://doi.org/10.1007/s11144-018-1379-z

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