Skip to main content
SpringerLink
Log in

Kinetic studies and optimization of abies wood fractionation by hydrogen peroxide under mild conditions with TiO2 catalyst

  • Published:
Reaction Kinetics, Mechanisms and Catalysis Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The kinetic study of abies wood delignification by H2O2 in the medium acetic acid–water was first carried out in the presence of TiO2 catalyst under mild conditions: temperatures 70–100 °C, atmospheric pressure. The oxidative delignification process is described satisfactory by the first order equation in all temperature range. The rate constants varied between 0.80 and 12.3 × 10−3 min−1 and the activation energy was near 81 ± 0.21 kJ mol−1. The optimal parameters of the delignification process, providing the effective fractionation of abies wood on microcrystalline cellulose and soluble lignin, were established by experimental and numerical methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Johan G, Fogelbolm CJ (2000) Chemical pulping, papermaking science and technology book 6A. Tappi Press, Finland

    Google Scholar 

  2. Sixta H (2006) Hand book of pulp. Wiley, Weinheim

    Book  Google Scholar 

  3. JiménezL Pérez A, Rodríguez A, de la Torre MJ (2006) New raw materials and pulping processes for production of pulp and paper. Afinidad 63(525):362–369

    Google Scholar 

  4. Rodríguez A, Jiménez L (2008) Pulping with organic solvents other than alcohols. Afinidad 65(535):188–196

    Google Scholar 

  5. Sixta H, Harms H, Dapia S, Parajo JC, Puls J, Saake B, Fink HP, Röder T (2004) Evaluation of new organosolv dissolving pulps. Part I: preparation, analytical characterization and viscose processability. Cellulose 11:73–83

    Article  CAS  Google Scholar 

  6. Zhao X, Heide E, Zhang T, Liu D (2010) Delignification of sugarcane bagasse with alkali and peracetic acid and characterization of the pulp. Bioresources 5:1565–1580

    CAS  Google Scholar 

  7. López F, Alfaro A, Jiménez L, Rodríguez A (2006) Alcohols as organic solvents for obtainment of cellulose pulp. Afinidad 523:174–182

    Google Scholar 

  8. Villaverde JJ, Ligero P, Vega A (2015) Fractionation of Miscanthus x Giganteus via modification of the Formacell process. Ind Crops Prod 77:275–281

    Article  CAS  Google Scholar 

  9. Ligero P, Vega A, Villaverde JJ (2010) Delignification of Miscanthus x Giganteus by the Milox process. Bioresour Technol 101:3188–3193

    Article  CAS  Google Scholar 

  10. Suchy M, Argyropoulos D (2001) Catalysis and activation of oxygen and peroxi dedelignification of chemical pulps: a review. ACS Symp Ser 785:2–43

    Article  CAS  Google Scholar 

  11. SongYo Wi SG, Kim HM, Bae HJ (2016) Cellulosic bioethanol production from Jerusalem artichoke (Helianthus tuberosus L.) using hydrogen peroxide-acetic acid (HPAC) pretreatment. Bioresour Technol 214:30–36

    Article  Google Scholar 

  12. Dussan K, Girisuta B, Haverty D, Leahy JJ, Hayes MH (2014) The effect of hydrogen peroxide concentration and solid loading on the fractionation of biomass in formic acid. Carbohydr Polym 111:374–384

    Article  CAS  Google Scholar 

  13. Das S, Lachenal D, Marlin N (2013) Production of pure cellulose from Kraft pulp by a totally chlorine-free process using catalyzed hydrogen peroxide. Ind Crops Prod 49:844–850

    Article  CAS  Google Scholar 

  14. Ramadoss G, Muthukumar K (2015) Influence of dual salt on the pretreatment of sugarcane bagasse with hydrogen peroxide for bioethanol production. Chem Eng J 260:178–187

    Article  CAS  Google Scholar 

  15. Gaspar AR, Gamelas JAF, EvtuguinD NetoCP (2007) Alternatives for lignocellulosic pulp delignification using polyoxometalates and oxygen: a review. Green Chem 9:717–730

    Article  CAS  Google Scholar 

  16. Popova NR, Tortseva TV, Bogolitsyn KG (2013) Catalytic delignification of cellulose fibers by hydrogen peroxide in presence of polyoxometalates. Russ J Appl Chem 86:1275–1279

    Article  CAS  Google Scholar 

  17. Kuznetsov BN, Kuznetsova SA, Danilov VG, Yatsenkova OV, Petrov AV (2011) A green one-step process of obtaining microcrystalline cellulose by catalytic oxidation of wood. Reac Kinet Mech Cat 104:337–343

    Article  CAS  Google Scholar 

  18. Kuznetsov BN, Kuznetsova SA, Danilov VG, Yatsenkova OV (2008) Catalytic properties of TiO2 in wood delignification by acetic acid–hydrogen peroxide mixture. React Kinet Catal Lett 94:311–317

    Article  CAS  Google Scholar 

  19. Kuznetsov BN, Kuznetsova SA, Danilov VG, Yatsenkova OV (2009) Influence of UV pretreatment on the abies wood catalytic delignification in the medium “acetic acid–hydrogen peroxide–TiO2”. React Kinet Catal Lett 97:295–300

    Article  CAS  Google Scholar 

  20. Fernández-Rodrígueza C, Dona-Rodrígueza JM, González-Díaza O, Secka I, Zerbani D, Portillob D, Perez-Pena J (2012) Synthesis of highly photoactive TiO2 and Pt/TiO2 nanocatalysts for substrate-specific photocatalytic applications. Appl Catal B 125:383–389

    Article  Google Scholar 

  21. Hu F, Jung S, Radauskas A (2012) Pseudo-lignin formation and its impact on enzymatic hydrolysis. Bioresour Technol 117:7–12

    Article  CAS  Google Scholar 

  22. Kuznetsov BN, Sudakova IG, Garyntseva NV, Djakovitch L, Pinel C (2013) Kinetic study of aspen-wood sawdust delignification by H2O2 with sulfuric acid catalyst under mild conditions. Reac Kinet Mech Cat 110:271–280

    Article  CAS  Google Scholar 

  23. Sjoöstroöm E, Aleŕn R (1999) Analytical methods in wood chemistry pulping and papermaking, Springer, Berlin

    Book  Google Scholar 

  24. Park S, Baker JO, Himmel ME, Parilla PA, Jonson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulose performance. Biotechnol Biofuels 3:10

    Article  Google Scholar 

  25. Lente G (2015) Deterministic kinetics in chemistry and systems biology. Springer, New York. ISBN 978-3-319-15481-7

    Book  Google Scholar 

  26. Sudakova IG, Garyntseva NV, Yatsenkova OV, Kuznetsov BN (2013) Optimization of aspen wood delignification by H2O2 with sulfuric acid catalyst. J Sib Fed Univ Chem 6:76–84

    CAS  Google Scholar 

  27. Adel AM, El-Wahab ZH, Ibrahim AA, Al-Shemy MT (2011) Characterization of microcrystalline cellulose prepared from lignocellulosic materials part II: physicochemical properties. Carbohydr Polym 83:676–687

    Article  CAS  Google Scholar 

  28. Fan M, Dai D, Huang B (2012) Fourier transform infrared spectroscopy for natural fibres. In: SalihSalih (ed) Fourier transform—materials analysis. In Tech, Rijeka. doi:10.5772/35482

    Google Scholar 

  29. Xiang LY, Mohammed MAP, Baharuddin AS (2016) Characterisation of microcrystalline cellulose from oil palm fibers for food applications. Carbohydr Polym 148:11–20

    Article  CAS  Google Scholar 

  30. Shankar S, Rhim JW (2016) Preparation of nanocellulose from microcrystalline cellulose: the effect on the performance and properties of agar based composite films. Carbohydr Polym 135:18–26

    Article  CAS  Google Scholar 

  31. Yuvraj P, Chauhan RS, Sapkal VS, Zamre GS (2009) Microcrystalline cellulose from cotton rags (Waste from garment and hosiery industries. Int J Chem Sci 7:681–688

    Google Scholar 

  32. Moran JI, Alvarez VA, Cyras VP, Vazquez A (2008) Extraction of cellulose and preparation of nanocellulose from sisal fibers. Cellulose 15:149–159

    Article  CAS  Google Scholar 

  33. Wikberg H, Maunu SL (2004) Characterization of thermally modified hard- and softwoods by 13C CPMAS NMR. Carbohydr Polym 58:461–466

    Article  CAS  Google Scholar 

  34. Zuckerstätter G, Schild G, Wollboldt P, Röder T, Weber HK, Sixta H (2009) The elucidation of cellulose supramolecular structure by 13C CP-MAS NMR. Lenzing Ber 87:38–46

    Google Scholar 

  35. Garyntseva NV, Sudakova IG, Kuznetsov BN (2015) Study of birch wood catalytic delignification by hydrogen peroxide at atmospheric pressure. J Sib Fed Univ. Chem 8:422–429

    Article  Google Scholar 

  36. Ma R, XuYa Zhang X (2015) Catalytic oxidation of biorefinery lignin to value-added chemicals to support sustainable biofuel production. ChemSusChem 8:24–51

    Article  CAS  Google Scholar 

  37. Kuznetsov BN, Tarabanko VE, Kuznetsova SA (2008) New catalytic methods for obtaining cellulose and other chemical products from vegetable biomass. Kinet Catal 49:517–526

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The reported study was supported by the Russian Science Foundation (Grant No. 16-13-10326).NMR experiments were conducted on BrukerAvance III spectrometer at Krasnoyarsk Regional Centre of Research Equipment SB RAS. The authors wish to thank Alexander Kondrasenko for the help with NMR experiments.

Author information

Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC SB RAS, Akademgorodok, 50-24, Krasnoyarsk, Russia, 660036

    B. N. Kuznetsov, I. G. Sudakova & N. V. Garyntseva

  2. Siberian Federal University, Svobodny prospect 79, Krasnoyarsk, Russia, 660041

    B. N. Kuznetsov

  3. IRCELYON, 2 avenues Albert Einstein, 69626, Villeurbanne Cedex, Lyon, France

    L. Djakovitch & C. Pinel

Authors
  1. B. N. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. G. Sudakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Garyntseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Djakovitch
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. C. Pinel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. N. Kuznetsov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kuznetsov, B.N., Sudakova, I.G., Garyntseva, N.V. et al. Kinetic studies and optimization of abies wood fractionation by hydrogen peroxide under mild conditions with TiO2 catalyst. Reac Kinet Mech Cat 120, 81–94 (2017). https://doi.org/10.1007/s11144-016-1100-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11144-016-1100-z

Keywords

Search

Navigation