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Mesoporous manganese oxide nanoparticles for the catalytic total oxidation of toluene

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Abstract

Mesoporous manganese oxide nanoparticles with the phases of tetragonal hausmannite, mixture of hausmannite Mn3O4 and monoclinic Mn5O8, and bixbyite Mn2O3 have been prepared by calcination of manganese acetate hydrate precursor at 200, 300, 400 and 700 °C, all of which were found to be active for the catalytic total oxidation of toluene. Their catalytic behavior depended on the oxidation state of manganese, the oxygen mobility and the amount of surface adsorbed oxygen species. The mesoporous nanoparticles calcined at 400 °C exhibited the highest catalytic performance with the complete toluene conversion temperature of 275 °C, suggesting that incorporating Mn5O8 into Mn3O4 could promote oxygen mobility, increase the amount of surface adsorbed oxygen and facilitate the activation of surface oxygen for the oxidation of toluene.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (20973096 and 21076056), the National Basic Research Program of China (2009CB623502), the Key Project of Chinese Ministry of Education (2100016), the Specialized Research Fund for the Doctoral Program of Higher Education (20091317120005, 20110031110016), and the 111 Project (B12015).

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Authors and Affiliations

  1. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China

    Qing-Fang Deng & Zhong-Yong Yuan

  2. Hebei Provincial Key Laboratory of Green Chemical Technology & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China

    Tie-Zhen Ren

Authors
  1. Qing-Fang Deng
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  2. Tie-Zhen Ren
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Correspondence to Zhong-Yong Yuan.

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Deng, QF., Ren, TZ. & Yuan, ZY. Mesoporous manganese oxide nanoparticles for the catalytic total oxidation of toluene. Reac Kinet Mech Cat 108, 507–518 (2013). https://doi.org/10.1007/s11144-012-0528-z

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  • DOI: https://doi.org/10.1007/s11144-012-0528-z

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