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Catalytic oxidation of CO and toluene over nanostructured mesoporous NiO/Ce0.8Zr0.2O2 catalysts

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Abstract

Mesoporous Ce0.8Zr0.2O2 oxides were prepared by a surfactant-assisted method of nanocrystalline particle assembly, and used as a support of nickel oxide nanocatalysts. The obtained mesoporous NiO/Ce0.8Zr0.2O2 nanocatalysts were characterized by XRD, N2 adsorption, TEM, H2-TPR and X-ray photoelectron spectroscopy techniques. The catalytic properties of the NiO/Ce0.8Zr0.2O2 nanocatalysts were evaluated by CO oxidation and toluene combustion. The results showed that the catalyst with 10 wt% NiO loading exhibited the highest catalytic activity for CO oxidation and toluene combustion.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (20973096), the National Basic Research Program of China (2009CB623502), the Specialized Research Fund for the Doctoral Program of Higher Education (20070055014), the Natural Science Foundation of Tianjin (08JCZDJC21500), and the Program for Changjiang Scholars and Innovative Research Team in University (IRT0927).

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Authors and Affiliations

  1. Institute of New Catalytic Materials Science, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China

    Bao Agula, Qing-Fang Deng, Yuping Liu & Zhong-Yong Yuan

  2. College of Chemistry and Environmental Science, Inner Mongolia Normal University, Huhhot, 010022, China

    Bao Agula, Mei-Lin Jia & Bao Zhaorigetu

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  1. Bao Agula
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  2. Qing-Fang Deng
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  3. Mei-Lin Jia
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  4. Yuping Liu
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  5. Bao Zhaorigetu
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  6. Zhong-Yong Yuan
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Correspondence to Zhong-Yong Yuan.

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Agula, B., Deng, QF., Jia, ML. et al. Catalytic oxidation of CO and toluene over nanostructured mesoporous NiO/Ce0.8Zr0.2O2 catalysts. Reac Kinet Mech Cat 103, 101–112 (2011). https://doi.org/10.1007/s11144-011-0296-1

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