Abstract
Manganese and mixed vanadium oxides were prepared by the hydrolysis of acetylacetonates. They were characterized by different techniques, such as X-ray diffraction, XPS, temperature-programmed surface reaction (TPSR), and conversion and selectivity measurements. TPSR studies showed that H2O, CO2, and O2 are present in manganese oxide samples and that the ones containing vanadium desorb CO2, H2O, methanol, formaldehyde, O2. The vanadium-free catalysts and the ones with a lower vanadium content also exhibit high methanol conversion and selectivity to CO2 at higher temperatures. The selectivity to dimethyl ether is important in the catalyst without V at lower temperature. The greatest conversion at lower temperatures and the highest selectivities to CO2 are achieved with the catalysts having the highest vanadium content.
Similar content being viewed by others
References
Romanyshyn Y, Guimond S, Kuhlenbeck H, Kaya S, Blum R, Niehus H, Shaikhutdinov S, Simic-Milosevic V, Nilius V, Freund H, Ganduglia-Pirovano M, Fortrie R, Dobler J, Sauer J (2008) Top Catal 50:106–115
Liu J, Fu Y, Sun Q, Shen J (2008) Micropor Mesopor Mater 116:614–621
Gimeno M, Gascón J, Téllez C, Herguido J, Menéndez M (2008) Chem Eng Process 47:1844–1852
Hetrick C, Patcas F, Amiridis M (2011) Appl Catal B 101:622–628
Gambaro L (2004) J Mol Catal A 214:287–294
Barrio L, Legorburu I, Montes M, Domínguez M, Centeno M, Odriozola J (2005) Catal Lett 101:151–158
Santos V, Pereira M, Órfão M, Figueiredo J (2010) Appl Catal B 99:353–363
Peluso M, Gambaro L, Pronsato E, Gazzoli D, Thomas H, Sambeth J (2008) Catal Today 133–135:487–492
Lamaita L, Peluso M, Sambeth J, Thomas H (2005) Appl Catal B 61:114–119
Aguero F, Barbero B, Costa AL, Montes M, Cadús L (2011) Chem Eng J 166:218–223
Nagirnyi V, Apostolova R, Baskevich A, Litvin P, Shembel E (2002) Russ J Appl Chem 75:552–557
Dobley A, Ngala K, Yang S, Zavalij P, Whittingham M (2001) Chem Mater 11:382–4386
Liu P, Zhang J, Turner J (2001) J Power Sources 92:204–211
Hara D, Shirakawa J, Ikuta H, Uchimoto Y, Wakihara M, Miyanaga T, Watanabe I (2002) J Mater Chem 12:3717–3722
Briand L, Jehng J, Cornaglia L, Hirt A, Wachs I (2003) Catal Today 78:257–268
Hasan M, Zaki M, Pasupukty L, Kumari K (1999) Appl Catal 181:171–179
Deraz N-A (2004) Thermochim Acta 421:171–177
Donia A, Radwan N, Atia A (2000) J Therm Anal Calorim 61:249–261
Polverejan M, Villegas J, Suib S (2004) J Am Chem Soc 126:7774–7775
Gac W (2007) Appl Catal B 75:107–117
Iablokov V, Frey K, Geszti O, Kruse N (2010) Catal Lett 134:210–216
Peluso M, Sambeth J, Thomas H (2003) React Kinet Catal Lett 80:241–247
Lahousse C, Bernier A, Gaigneaux E, Ruiz P, Grange P, Delmon B (1997) Catal 110:777–785
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Curia, V., Sambeth, J. & Gambaro, L. Catalytic and physicochemical characterization of the MnVOx system. Influence of vanadium on methanol oxidation. Reac Kinet Mech Cat 106, 165–176 (2012). https://doi.org/10.1007/s11144-012-0422-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11144-012-0422-8