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Correlation between reduction potential of vanadium-containing heteropolyacid (HPA) catalysts and their oxidation activity for cyclohexanol dehydrogenation

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Abstract

Vanadium-containing H6+xP2Mo18−xVxO62 (x = 0, 1, 2 and 3) Wells-Dawson heteropolyacid (HPA) and H3+xPMo12−xVxO40 (x = 0, 1, 2 and 3) Keggin HPA catalysts were applied to the vapor-phase dehydrogenation of cyclohexanol. The catalytic oxidation activity showed a volcano-shaped curve with respect to vanadium substitution for both families of HPA catalysts. The Wells-Dawson HPA showed a better catalytic oxidation performance than the Keggin HPA at the same level of vanadium substitution.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Seoul National University, Shinlim-dong Kwanak-ku, Seoul, 151-744, South Korea

    Dong Ryul Park, Heesoo Kim, Ji Chul Jung, Sang Hee Lee, Joohyung Lee & In Kyu Song

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  1. Dong Ryul Park
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  2. Heesoo Kim
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  3. Ji Chul Jung
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  4. Sang Hee Lee
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  5. Joohyung Lee
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  6. In Kyu Song
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Correspondence to In Kyu Song.

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Park, D.R., Kim, H., Jung, J.C. et al. Correlation between reduction potential of vanadium-containing heteropolyacid (HPA) catalysts and their oxidation activity for cyclohexanol dehydrogenation. React Kinet Catal Lett 93, 43–49 (2008). https://doi.org/10.1007/s11144-008-5202-0

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  • DOI: https://doi.org/10.1007/s11144-008-5202-0

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