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Activation energy for the ignition of the catalytic oxidation of methanol in oscillatory regime

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Abstract

The overall activation energy for the ignition of thermokinetic oscillations observed (in a dynamic calorimeter) during the heterogeneous catalytic oxidation of methanol on Pd/LiAl5O8 were obtained and discussed by a PdOx redox cycle.

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Authors and Affiliations

  1. “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, 202 Splaiul Independentei, 060021, Bucharest, Romania

    Niculae I. Ionescu, Monica Caldararu, Cristian Hornoiu & Cornel Munteanu

Authors
  1. Niculae I. Ionescu
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  2. Monica Caldararu
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  3. Cristian Hornoiu
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  4. Cornel Munteanu
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Correspondence to Niculae I. Ionescu.

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Ionescu, N.I., Caldararu, M., Hornoiu, C. et al. Activation energy for the ignition of the catalytic oxidation of methanol in oscillatory regime. React Kinet Catal Lett 91, 257–262 (2007). https://doi.org/10.1007/s11144-007-5137-x

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  • DOI: https://doi.org/10.1007/s11144-007-5137-x

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