Abstract
When ethene alone was contacted with silica supported cobalt catalyst (Co/SiO2), ethene homologation took place with considerable activity. Moreover, the propene metathesis reaction was suppressed ca. 1/6 fold as much as in the case using MoOX/SiO2 catalyst. The possibility of selective homologation with a lower activity for metathesis was suggested for the cobalt-based catalyst system.
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Suzuki, T. Selective ethene homologation reaction on silica supported cobalt catalyst. React Kinet Catal Lett 90, 61–68 (2007). https://doi.org/10.1007/s11144-007-4980-0
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DOI: https://doi.org/10.1007/s11144-007-4980-0