The formation of self-reinforced composites in the ZrO2–Y2O3–CeO2–Al2O3 system is investigated. Depending on different sintering conditions, plates of CeAlO3, T-ZrO2, and α-Al2O3 are formed in the matrix based on a solid solution of ZrO2. The self-reinforced composite with fracture toughness 17–20 MPa ⋅ m0.5 is obtained in optimum sintering conditions. In this composite, α-Al2O3 plates as well as individual Ce2O3 ⋅ 11Al2O3 plates are arranged in the matrix based on T-ZrO2. Selfreinforced composites in the ZrO2–Y2O3–CeO2–Al2O3 system have a considerable potential for various engineering ceramic materials with tailored combinations of properties, e.g., for medical applications (surgical tools and bioinert implants).
Similar content being viewed by others
References
A. V. Shevchenko, A. K. Ruban, and E. V. Dudnik, “Advanced zirconia ceramics,” Ogneupory Tekh. Keram., No. 9, 2–8 (2000).
J.-D. Lin and J. Duh, “Fracture toughness and hardness of ceria- and yttria-doped tetragonal zirconia ceramics,” Mater. Chem. Phys., 78, 253–261 (2002).
B. Bastid, P. Canale, and P. Odier, “Characterization of a new ternary Ce-tetragonal zirconia,” J. Eur. Ceram. Soc., 5, 289–293 (1989).
F. F. Lange, “Transformation toughening. Part 4. Fabrication, fracture toughness and strength of Al2O3–ZrO2 composites,” J. Mater. Sci., 17, 247–254 (1982).
A. V. Shevchenko, A. K. Ruban, E. V. Dudnik, et al., “Formation of self-reinforced gradient ceramic composites,” Functional Mat., No. 1, 67–70 (2001).
A. V. Shevchenko, E. V. Dudnik, V. A. Dubok, et al., “Biocompatible implants based on nanocrystalline ZrO2 powders,” Tekh. Mashinostr., No. 2 (58), 32–35 (2006).
G. S. Oleinik, Self-Reinforced Ceramic Materials [in Ukrainian], IPMA NASU, Kiev (1993), p. 46.
A. V. Shevchenko, E. V. Dudnik, A. K. Ruban, et al., “Hydrothermal synthesis of nanocrystalline powders in the ZrO2–Y2O3–CeO2 system,” Powder Metall. Met. Ceram., 46, No. 1–2, 18 –25 (2007).
E. V. Dudnik, A. V. Shevchenko, A. K. Ruban, et al., “Synthesis and properties of nanocrystalline 90 wt.% ZrO2(Y2O3, CeO2)–10 wt.% A12O3 powder,” Inorg. Mat., 44, No. 4, 409–413 (2008).
V. V. Scorokhod and S. M. Solonin, Physical-Metallurgical Bases of Powder Sintering [in Russian], Metallurgy, Moscow (1984), p. 159.
Yu. D. Tret’yakov, Solid-State Reactions [in Russian], Chemistry, Moscow (1978), p. 360.
V. Longo and D. Minichelli, “X-ray characterization of Ce2Zr3O10,” J. Am. Ceram. Soc., 56, No. 11, 600 (1973).
W. Pyda, K. Haberko, and Z. Zurek, “Zirconia stabilized with a mixture of the rare earth oxides,” J. Eur. Ceram. Soc., 10, 453–459 (1992).
E. Lucchini, S. Maschio, and E. Saldor, “Influenza delle condizioni di sinterizazione sulle proprieta meccamiche di una ”lega” ZrO2–CeO2 10.3 mol.%,” Ceram. Acta., 3, No. 2, 33–39 (1991).
A. I. Leonov, High-Temperature Chemistry of the Cerium Oxygen Compounds [in Russian], Leningrad (1969).
D. Fan and L.-Q. Chen, “Computer simulation of grain growth and Ostwald ripening in alumina-zirconia two-phase composites,” J. Am. Ceram. Soc., 80, No. 7, 1773–1780 (1997).
S.-J. Cho, K.-H. Kim, D.-J. Kim, and K.-J. Yoon, “Abnormal grain growth at the interface of centrifugally cast alumina bilayer during sintering,” J. Am. Ceram. Soc., 83, No. 7, 1773–1776 (2000).
A. G. Evans and E. A. Charles, “Fracture toughness determinations by indentation,” J. Am. Ceram. Soc., 59, No. 7, 371–372 (1976).
K. Niihara, R. Morena, and D. P. H. Hasselman, “Evaluation of K 1c of brittle solids by the indentation method with low crack-to indent rates,” J. Mat. Sci. Let., 1, No. 1, 13–16 (1982).
D. K. Shetty, A. R. Rosenfield, and W. H. Duckworth, “Indenter flow geometry and fracture toughness estimate for a glass-ceramic,” J. Am. Ceram. Soc., 68, No. 10, C282–C284 (1983).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Poroshkovaya Metallurgiya, Vol. 49, No. 1–2 (471), pp. 56–65, 2010.
Rights and permissions
About this article
Cite this article
Shevchenko, A.V., Dudnik, E.V., Ruban, A.K. et al. Sintering of self-reinforced ceramics in the ZrO2–Y2O3–CeO2–Al2O3 system. Powder Metall Met Ceram 49, 42–49 (2010). https://doi.org/10.1007/s11106-010-9199-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11106-010-9199-3