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Photocatalytic activity of anatase titanium dioxide nanostructures prepared by reactive magnetron sputtering technique

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Abstract

In this work, nanostructured titanium dioxide (TiO2) photocatalysts with high optical and structural homogeneity were successfully synthesized by dc reactive magnetron sputtering technique. The TiO2 thin films were produced with high structural homogeneity without any heat treatment. Analysis of the X-ray diffraction patterns and UV–visible spectroscopy gave an indication that the structure of prepared films is anatase with energy band gap of 3.23 eV. The Fourier-transform infrared spectroscopy has confirmed the formation of Ti–O bond. The average size of TiO2 particles in the deposited films was ranging in 5–7 nm. These nanostructures are very applicable as photocatalysts as their photocatalytic activity was determined from the degradation rate with UV irradiation time as the first order reaction rate constant was determined to be 2.4 × 10−3 min−1.

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References

  • Alhadrami, H.A., Baqasi, A., Iqbal, J., Shoudri, R.A.M., Ashshi, A.M., Azhar, E.I., Al-Hazmi, F., Al-Ghamdi, A., Wageh, S.: Antibacterial applications of anatase TiO2 nanoparticle. Am. J. Nanomater. 5(1), 31–42 (2017)

    Article  Google Scholar 

  • Al-Maliki, F.J., Al-Lamey, N.H.: Synthesis of Tb-doped titanium dioxide nanostructures by sol-gel method for environmental photocatalysis applications. J. Sol Gel. Sci. Technol. 81(1), 276–283 (2017)

    Article  Google Scholar 

  • Amano, F., Yasumoto, T., Prieto-Mahaney, O.-O., Uchida, S., Shibayama, T., Ohtani, B.: Photocatalytic activity of octahedral single-crystalline mesoparticles of anatase titanium(IV) oxide. Chem. Commun. 17, 2311–2313 (2009)

    Article  Google Scholar 

  • Biancardo, M., Argazzi, R., Bignozzi, C.: Solid-state photochromic device based on nanocrystalline TiO2 functionalized with electron donor−acceptor species. Inorg. Chem. 44(26), 9619–9621 (2005)

    Article  Google Scholar 

  • Biener, J., Wittstock, A., Baumann, T.F., Weissmüller, J., Bäumer, M., Hamza, A.V.: Surface chemistry in nanoscale materials. Materials 2, 2404–2428 (2009)

    Article  ADS  Google Scholar 

  • Bouachiba, Y., Bouabellou, A., Hanini, F., Kermiche, F., Taabouche, A., Boukheddaden, K.: Structural and optical properties of TiO2 thin films grown by sol-gel dip coating process. Mater. Sci. Pol. 32(1), 1–6 (2014)

    Article  ADS  Google Scholar 

  • Carneiro, J.O., Teixeira, V., Carvalho, P., Azevedo S., Manninen, N.: Self-cleaning smart nanocoatings. In: Nanocoatings and Ultra-Thin Films: Technologies and Applications, Woodhead Publishing Series in Metals and Surface Engineering, pp. 397–413 (2011). https://doi.org/10.1533/9780857094902.2.397

  • Castrejón-Sánchez, V.H., Camps, E., Camacho-López, M.: Quantification of phase content in TiO2 thin films by Raman spectroscopy. Superficies y Vacío 27(3), 88–92 (2014)

    Google Scholar 

  • Chaiyakun, S., Pokaipisit, A., Limsuwan, P., Ngotawornchai, B.: Growth and characterization of nanostructured anatase phase TiO2 thin films prepared by DC reactive unbalanced magnetron sputtering. Appl. Phys. A 95(2), 579–587 (2009)

    Article  ADS  Google Scholar 

  • Chen, X., Mao, S.S.: Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107(7), 2891–2959 (2007)

    Article  Google Scholar 

  • Ciancio, R., Vittadini, A., Selloni, A., Arpaia, R., Aruta, C., Granozio, F.M., di Uccio, U.S., Rossi, G., Carlino, E.: Evolution of nanostructures of anatase TiO2 thin films grown on (001) LaAlO3. J. Nanopart. Res. 15, 1735 (2013). https://doi.org/10.1007/s11051-013-1735-x

    Article  ADS  Google Scholar 

  • Essalhi, Z., Hartiti, B., Lfakir, A., Siadat, M., Thevenin, P.: Optical properties of TiO2 thin films prepared by sol gel method. J. Mater. Environ. Sci. 7(4), 1328–1333 (2016)

    Google Scholar 

  • Evans, P., Sheel, D.W.: Photoactive and antibacterial TiO2 thin films on stainless steel. Surf. Coat. Technol. 201(22–23), 9319–9324 (2007)

    Article  Google Scholar 

  • Hadjoub, I., Touam, T., Chelouche, A., Atoui, M., Solard, J., Chakaroun, M., Fischer, A., Boudrioua, A., Peng, L.H.: Post-deposition annealing effect on RF-sputtered TiO2 thin-film properties for photonic applications. Appl. Phys. A 122, 78 (2016). https://doi.org/10.1007/s00339-015-9570-9

    Article  ADS  Google Scholar 

  • Hamadi, O.A.: Characteristics of CdO-Si heterostructure produced by plasma-induced bonding technique. Proc. IMechE L J. Mater. Design Appl. 222(5), 65–71 (2008a)

    Google Scholar 

  • Hamadi, O.A.: Effect of annealing on the electrical characteristics of CdO-Si heterostructure produced by plasma-induced bonding technique. Iraqi J. Appl. Phys. 4(3), 34–37 (2008b)

    Google Scholar 

  • Hameed, M.A., Jabbar, Z.M.: Optimization of preparation conditions to control structural characteristics of silicon dioxide nanostructures prepared by magnetron plasma sputtering. Silicon 10(4), 1411–1418 (2018)

    Article  Google Scholar 

  • Hammadi, O.A., Naji, N.E.: Electrical and spectral characterization of CdS/Si heterojunction prepared by plasma-induced bonding. Opt. Quant. Electron. 48(8), 375 (2016). https://doi.org/10.1007/s11082-016-0647-2

    Article  Google Scholar 

  • Hammadi, O.A., Naji, N.E.: Characterization of polycrystalline nickel cobaltite nanostructures prepared by DC plasma magnetron Co-sputtering for gas sensing applications. Photon. Sens. 8(1), 43–47 (2018)

    Article  ADS  Google Scholar 

  • Hammadi, O.A., Khalaf, M.K., Kadhim, F.J., Chiad, B.T.: Operation characteristics of a closed-field unbalanced dual-magnetrons plasma sputtering system. Bulg. J. Phys. 41(1), 24–33 (2014)

    Google Scholar 

  • Hammadi, O.A., Khalaf, M.K., Kadhim, F.J.: Fabrication of UV photodetector from nickel oxide nanoparticles deposited on silicon substrate by closed-field unbalanced dual magnetron sputtering techniques. Opt. Quantum Electron. 47(12), 3805–3813 (2015)

    Article  Google Scholar 

  • Hammadi, O.A., Khalaf, M.K., Kadhim, F.J.: Fabrication and characterization of UV photodetectors based on silicon nitride nanostructures prepared by magnetron sputtering. Proc. IMechE N J. Nanoeng. Nanosys. 230(1), 32–36 (2016)

    Google Scholar 

  • Hammadi, O.A., Khalaf, M.K., Kadhim, F.J.: Silicon nitride nanostructures prepared by reactive sputtering using closed-field unbalanced dual magnetrons. Proc. IMechE L J. Mater. Design Appl 231(5), 479–487 (2017)

    Google Scholar 

  • Jin, Y., Li, G., Zhang, Y., Zhang, Y., Zhang, L.: Photoluminescence of anatase TiO2 thin films achieved by the addition of ZnFe2O4. ‎J. Phys. Condens. Matter. 13, L913–L918 (2001)

    Article  ADS  Google Scholar 

  • Kadhim, F.J., Anber, A.A.: Microhardness of nanostructured SixN1-x thin films prepared by reactive magnetron sputtering. Iraqi J. Appl. Phys. 12(2), 15–19 (2016)

    Google Scholar 

  • Karabay, I., Aydın Yüksel, S., Ongül, F., Öztürk, S., Asli, M.: Structural and optical characterization of TiO2 thin films prepared by sol–gel process. Acta Phys. Pol. A 121(1), 265–267 (2012)

    Article  Google Scholar 

  • Khairy, M., Zakaria, W.: Effect of metal-doping of TiO2 nanoparticles on their photocatalytic activities toward removal of organic dyes. Egyp. J. Petrol. 23(4), 419–426 (2014)

    Article  Google Scholar 

  • Lam, S.W., Soetanto, A., Amal, R.: Self-cleaning performance of polycarbonate surfaces coated with titania nanoparticles. J. Nanopart. Res. 11, 1971–1979 (2009)

    Article  ADS  Google Scholar 

  • Quesada-González, M., Baba, K., Sotelo-Vázquez, C., Choquet, P., Carmalt, C.J., Parkin, I.P., Boscher, N.D.: Interstitial boron-doped anatase TiO2 thin-films on optical fibres: atmospheric pressure-plasma enhanced chemical vapour deposition as the key for functional oxide coatings on temperaturesensitive substrates. J. Mater. Chem. A 5, 10836–10842 (2017)

    Article  Google Scholar 

  • Salman, O.N., Agool, I.R., Ismail, M.I.: Preparation of the scattering layer based on TiO2 nanotube and their dye sensitized solar cell applications. Appl. Phys. A 123, 402 (2017). https://doi.org/10.1007/s00339-017-1012-4

    Article  ADS  Google Scholar 

  • Stamate, M., Lazar, G., Lazar, I.: Anatase-rutile TiO2 thin films deposited in a d.c. magnetron sputtering system. Rom. J. Phys. 53(1–2), 217–221 (2008)

    Google Scholar 

  • Stefanov, B., Österlund, L.: Tuning the photocatalytic activity of anatase TiO2 thin films by modifying the preferred <001> grain orientation with reactive DC magnetron sputtering. Coatings 4, 587–601 (2014)

    Article  Google Scholar 

  • Yang, X.H., Yang, H.G., Li, C.Z.: Controllable nanocarving of anatase TiO2 single crystals with reactive 001 facets. Chem. Euro. J. 17(24), 6615–6619 (2011)

    Article  Google Scholar 

  • Zachariah, A., Baiju, K.V., Shukla, S., Deepa, K.S., James, J., Warrier, K.G.K.: Synergistic effect in photocatalysis as observed for mixed-phase nanocrystalline titania processed via sol-gel solvent mixing and calcination. J. Phys. Chem. C 112(30), 11345–11356 (2008)

    Article  Google Scholar 

  • Zakrzewska, K., Radecka, M.: TiO2-based nanomaterials for gas sensing—influence of anatase and rutile contributions. Nanoscale Res. Lett. 12, 89–96 (2017)

    Article  Google Scholar 

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Al-Oubidy, E.A., Kadhim, F.J. Photocatalytic activity of anatase titanium dioxide nanostructures prepared by reactive magnetron sputtering technique. Opt Quant Electron 51, 23 (2019). https://doi.org/10.1007/s11082-018-1738-z

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