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Efficient sensitization of Ln3+-doped NaYF4 nanocrystals with organic ligands

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Abstract

Ligand-capped lanthanide-doped fluoride nanocrystals have been prepared and fully characterized. Organic ligands can be used to promote efficient sensitization of lanthanide luminescence in the fluoride matrix up to a 330-fold enhancement in intensity, and to provide sizeable quantum yields of luminescence. The variation of luminescence efficiency in the capped nanocrystal series can be straightforwardly correlated to the energy of the measured ligand triplet states. The intense luminescence emission of most of the systems renders them very attractive for optical applications.

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Acknowledgments

N.G. would like to thank the Nanoscience foundation and Chimtronic research program (6.3.8 ConvSpec) and the authors thank the “French Agence National de la Recherche”, grants ANR-10-P2N-001 for financial support. The authors thank Amélie Revaux, Jacques Pécaut and François Saint-Antonin (CEA Grenoble) for the DLS, X-ray and TEM measurements mentioned in this article, and for fruitful discussions.

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Authors and Affiliations

  1. Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique (UMR E-3 CEA/UJF), INAC, CEA, 17 rue des Martyrs, 38054, Grenoble Cedex 9, France

    N. Gauthier, D. Imbert & M. Mazzanti

  2. Laboratoire de Chimie et de Sécurité des NanoMatériaux (DTNM/LITEN/DRT), CEA, Grenoble, France

    O. Raccurt

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  1. N. Gauthier
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Correspondence to D. Imbert.

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Gauthier, N., Raccurt, O., Imbert, D. et al. Efficient sensitization of Ln3+-doped NaYF4 nanocrystals with organic ligands. J Nanopart Res 15, 1723 (2013). https://doi.org/10.1007/s11051-013-1723-1

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