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RETRACTED ARTICLE: Green luminescent ZnO:Cu2+ nanoparticles for their applications in white-light generation from UV LEDs

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This article was retracted on 11 January 2023

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Abstract

Copper doped ZnO nanoparticles were synthesized by a chemical technique based on a hydrothermal method. The crystallite sizes, estimated by XRD and TEM/SEM for different doping percentage of Cu2+ (1–10%), were found to be in the range of ~10–15 nm. TEM/SEM images showed formation of uniform nanorods, the aspect ratio of which varied with doping percentage. Photoluminescence (PL) measurement showed strong green visible emission and PL intensity was found enhanced with increase in doping percentage. The increase in the PL intensity was mainly due to Cu incorporation in ZnO lattice. Currently, light-emitting diodes (LEDs) giving ultraviolet emission have been combined with broad-band visible green phosphors to make white-light LEDs. Thus, green luminescent ZnO:Cu2+ nanoparticles are seen as necessary and condemnatory constituent for white-light generation from UV LEDs, underlying the importance of the current work.

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References

  • Bannemainn DW, Kormann C, Hoffmann MR (1987) Preparation and characterization of quantum size zinc oxide: a detailed spectroscopic study. J Phys Chem 91:3789–3798

    Article  Google Scholar 

  • Cetin A, Kibar R, Ayvacikli M, Can N, Buchal Ch, Townsend PD, Stepanov AL, Karali T, Selvi S (2006) Optical properties of Cu implanted ZnO. Nucl Instrum Methods Phys Res B 249:474–477

    Article  CAS  Google Scholar 

  • Damen TC, Porto SPS, Tell B (1996) Raman effect in zinc oxide. Phys Rev 142:570–574

    Article  Google Scholar 

  • Fan Z, Lu JG (2005) Zinc oxide nanostructures: synthesis and properties. J Nanosci Nanotechnol 5:1561–1573

    Article  CAS  Google Scholar 

  • Gavces NY, Wang L, Bai L, Giles NC, Halliburtan LE, Cantwell G (2004) Role of copper in the green luminescence from ZnO crystals. Appl Phys Lett 81(4):622–624

    Google Scholar 

  • Hans J, Song JW, Yang C-H, Park SH, Park J-H, Jeong YH, Rhie KW (2002) A key to room-temperature ferromagnetism in Fe-doped ZnO: Cu. Appl Phys Lett 81:4212–4214

    Article  Google Scholar 

  • Honma I, Hirakowa S, Yamada K, Bae JM (1999) Synthesis of organic/inorganic nanocomposites protonic conducting membrane through sol–gel processes. Solid State Ionics 118:29–36

    Article  CAS  Google Scholar 

  • Hoyer P, Wellar H (1994) Size-dependent redox potentials of quantized zinc oxide measured with an optically transparent thin layer electrode. Chem Phys Lett 221:379–384

    Article  CAS  Google Scholar 

  • Hu J, Odom TW, Lieber CM (1999) Chemistry and physics in one dimension: synthesis and properties of nanowires and nanotubes. Acc Chem Res 32:435–445

    Article  CAS  Google Scholar 

  • Hu JQ, Bandu Y, Zhan HJ, Li BY, Sekiguchi T (2003) Two-dimensional micrometer-sized single-crystalline ZnO thin nanosheets. Appl Phys Lett 83:4414–4416

    Article  CAS  Google Scholar 

  • Huang MH, Wu YY, Feich HN, Tran N, Weber E, Yang PD (2001) Catalytic growth of zinc oxide nanowires by vapor transport. Adv Mater 13:113–116

    Article  CAS  Google Scholar 

  • Hui KN, Fu WY, Ng WN, Leung CH, Lai PT, Wong KKY, Choi HW (2008) Polychromatic light-emitting diodes with a fluorescent nanosphere opal coating. Nanotechnology 19:355203–355208

    Article  CAS  Google Scholar 

  • Karpina VA, Lazorenko VI, Lashkarev CV, Dobrowolski VD, Kopylova LI, Baturin VA, Lytuyn SA, Ovsyannikov VP, Mauvenko EA (2004) Zdinc oxide—analogue of GaN with new perspective possibilities. Cryst Res Technol 39:980–992

    Article  CAS  Google Scholar 

  • Koyano M, Quoc Bao P, Thanh Binh LT, Hong Ha L, Ngoc Long N, Katayama SI (2002) Photoluminescence and Raman spectra of ZnO thin films by charged liquid cluster beam technique. Phys Status Solid A 193:125–131

    Article  CAS  Google Scholar 

  • Kryshtab TG, Khomchenko VS, Papsha VP, Mazin MO, Tzykunov YA (2002) Thin ZnS:Cu, Ga and ZnO:Cu, Ga film phosphors. Thin Solid Films 403–404:76–80

    Article  Google Scholar 

  • Liu M, Kitai AH, Mascher P (1992) Point defects and luminescence centres in zinc oxide and zinc oxide doped with manganese. J Lumin 54:35–42

    Article  CAS  Google Scholar 

  • Mendoza-Galvain A, Trejo-Cruz C, Lee J, Bhattacharya D, Metson J, Evans PJ, Pala U (2006) Effect of metal-ion doping on the optical properties of nanocrystalline ZnO thin films. J Appl Phys 99:14306–14311

    Article  Google Scholar 

  • Mirkin CA (1999) Tweezers for the nanotool kit. Science 286:2095–2096

    Article  CAS  Google Scholar 

  • Nakamura S (1998) The roles of structural imperfections in InGaN-based blue light-emitting diodes and laser diodes. Science 281:956–961

    Article  CAS  Google Scholar 

  • Phely-Bobin TS, Muisener RJ, Koberstein JT, Papadinmitrakopoulos F (2001) Site-specific self-assembly of Si/SiOx nanoparticles on micropatterned poly(dimethylsiloxane) thin films. Synth Met 116:439–443

    Article  CAS  Google Scholar 

  • Prokes SM, Wang KL (1999) Novel methods of nanoscale wire formation. Mater Res Sci Bull 24:13–19

    Article  CAS  Google Scholar 

  • Sharma PK, Dutta RK, Pandey AC (2009) Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO: Cu2+ nanorods. J Magn Magn Mater 321:4001–4005

    Article  CAS  Google Scholar 

  • Spanhel L, Anderson MA (1991) Semiconductor clusters in the sol–gel process: quantized aggregation, gelation, and crystal growth in concentrated zinc oxide colloids. J Am Chem Soc 113:2826–2833

    Article  CAS  Google Scholar 

  • Studenikin SA, Golego Kiclolcy, Cocivera Michael (1998) Fabrication of green and orange photoluminescent, undoped ZnO films using spray pyrolysis. J Appl Phys 84:2287–2294

    Article  CAS  Google Scholar 

  • Vanheusden K, Warren WL, Seager CH, Tallanl DR, Voigt JA, Gandu BE (1996) Mechanisms behind green photoluminescence in ZnO phosphor powders. J Appl Phys 79:7983–7990

    Article  CAS  Google Scholar 

  • Wang Z, Zhang H, Zhang L, Yang J, Yan S, Wang C (2003) Low-temperature synthesis of ZnO nanoparticles by solid-state pyrolytic reaction. Nanotechnology 14:11–15

    Article  CAS  Google Scholar 

  • Wu XL, Siu GG, Fu CL, Ong HC (2001) Photoluminescence and cathodoluminescence studies of stoichiometric and oxygen-deficient ZnO films. Appl Phys Lett 78:2285–2287

    Article  CAS  Google Scholar 

  • Zhang Z, Huang B, Yu Y, Guo D (2001) Synthesis of Mg2Si1–xGex thermoelectric compound by solid phase reaction. Mater Sci Eng B 86:195–199

    Article  Google Scholar 

  • Zhang J, Sun L, Yin J, Su H, Liao C, Yon C (2002) Control of ZnO morphology via a simple solution route. Chem Mater 14:4172–4177

    Article  CAS  Google Scholar 

  • Zhao X, Komuro S, Isshiki H, Aoyagi Y, Sugamo T (2000) Fabrication and optical transition dynamics of Er-doped ZnO thin films formed on Si substrates. J Lumin 87–89:1254–1256

    Article  Google Scholar 

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Acknowledgments

Authors are thankful to DST and CSIR, India for supporting “Nanotechnology Application Centre” under ‘IRHPA’, ‘Nano-Mission’, and ‘NMITLI’.

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Correspondence to Prashant K. Sharma.

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Sharma, P.K., Kumar, M. & Pandey, A.C. RETRACTED ARTICLE: Green luminescent ZnO:Cu2+ nanoparticles for their applications in white-light generation from UV LEDs. J Nanopart Res 13, 1629–1637 (2011). https://doi.org/10.1007/s11051-010-9916-3

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  • DOI: https://doi.org/10.1007/s11051-010-9916-3

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