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Oxygen storage capacity of substituted YBaCo4O7+δ oxygen carriers

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Abstract

Investigations on Ti, Pr, and Dy substitution and Ti co-substitution with La, Ce, Pr, Nd, and Dy in Y site were carried out. The XRD patterns indicate that the solubility limit for Ti is 5%. The solubility limit for Dy is 100%. Impurities will form if the substituting proportion surpasses the solubility limit for the substituting ion. For the phase composition of all co-substitution samples, only Ti and Dy substituted one is essentially single phase. The largest oxygen content δ reached 1.054, 1.188 and 1.070 for Y0.95Ti0.05BaCo4O7+δ, DyBaCo4O7+δ, Y0.2Ti0.05Dy0.75BaCo4O7+δ, respectively. The largest oxygen content δ reached was 0.900 for Y0.25Pr0.75BaCo2O5+δ.

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (Grant Nos. 51576035, 51604078), the Fundamental Research Funds for the Central Universities (Grant No. N162504012) and the Post-Doctoral Science Foundation (Grant Nos. 2017M610185, 20170101).

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Authors and Affiliations

  1. School of Metallurgy, Northeastern University, P.O. Box 345, No. 11, Lane 3, Wenhua Road, Heping District, Shenyang, 110819, Liaoning, People’s Republic of China

    Limin Hou, Qingbo Yu, Kun Wang, Tuo Wang, Fan Yang & Shuo Zhang

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  1. Limin Hou
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  2. Qingbo Yu
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  3. Kun Wang
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  4. Tuo Wang
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  5. Fan Yang
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Correspondence to Qingbo Yu.

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Hou, L., Yu, Q., Wang, K. et al. Oxygen storage capacity of substituted YBaCo4O7+δ oxygen carriers. J Therm Anal Calorim 137, 317–325 (2019). https://doi.org/10.1007/s10973-018-7903-6

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  • DOI: https://doi.org/10.1007/s10973-018-7903-6

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