Skip to main content
SpringerLink
Log in

Modifying the oxygen adsorption properties of YBaCo4O7 by Ca, Al, and Fe doping

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The doping effect of Ca, Al, and Fe on the oxygen adsorption properties of YBaCo4O7 was investigated by thermogravimetry (TG) method. It was found that the original YBaCo4O7 oxygen adsorption properties can be modified greatly by Ca, Al, and Fe doping. Ca doping in Y sites eliminates the oxygen adsorption at low temperature (~300 °C) but the oxygen adsorption properties at high temperature is almost unchanged. Minor Al doping in Co sites eliminates the oxygen adsorption hump at high temperature, but the hump at low temperature is preserved. Fe appearance in YBaCo3Al1−xFexO7 seems to weaken the effect of Al doping, so the oxygen hump at high temperature emerges again. The doping effect was discussed based on elements valence, binding energy between cations and oxygen ions, and distortion of crystal structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Valldor M, Andersson M (2002) Solid State Sci 4:923. doi:https://doi.org/10.1016/S1293-2558(02)01342-0

    Article  CAS  Google Scholar 

  2. Valldor M (2004) Solid State Sci 6:251. doi:https://doi.org/10.1016/j.solidstatesciences.2004.01.004

    Article  CAS  Google Scholar 

  3. Huq A, Mitchell JF, Zheng H, Chapon LC, Radaelli PG, Knight KS et al (2006) J Solid State Chem 179:1136. doi:https://doi.org/10.1016/j.jssc.2006.01.010

    Article  CAS  Google Scholar 

  4. Maignan A, Caignaert V, Pelloquin D, Hébert S, Pralong V, Hejtmanek J et al (2006) Phys Rev B 74:165110. doi:https://doi.org/10.1103/PhysRevB.74.165110

    Article  Google Scholar 

  5. Chapon LC, Radaelli PG, Zheng H, Mitchell JF (2006) Phys Rev B 74:172401. doi:https://doi.org/10.1103/PhysRevB.74.172401

    Article  Google Scholar 

  6. Hao H, Chen C, Pan L, Gao J, Hu X (2007) Phys B 387:98. doi:https://doi.org/10.1016/j.physb.2006.03.089

    Article  CAS  Google Scholar 

  7. Hao H, Zhang X, He Q, Chen C, Hu X (2007) Solid State Commun 141:591. doi:https://doi.org/10.1016/j.ssc.2007.01.005

    Article  CAS  Google Scholar 

  8. Tsipis EV, Khalyavin DD, Shiryaev SV, Redkina KS, Nunez P (2005) Mater Chem Phys 92:33. doi:https://doi.org/10.1016/j.matchemphys.2004.12.027

    Article  CAS  Google Scholar 

  9. Nakayama N, Mizota T, Ueda Y, Sokolov AN, Vasiliev AN (2006) J Magn Magn Mater 300:98. doi:https://doi.org/10.1016/j.jmmm.2005.10.041

    Article  CAS  Google Scholar 

  10. Caignaert V, Maignan A, Pralong V, Hebert S, Pelloquin D (2006) Solid State Sci 8:1160

    Article  CAS  Google Scholar 

  11. Karppinen M, Yamauchi H, Otani S, Fujita T, Motohashi T, Huang Y-H et al (2006) Chem Mater 18:490. doi:https://doi.org/10.1021/cm0523081

    Article  CAS  Google Scholar 

  12. Hao H, Cui J, Chen C, Pan L, Hu J, Hu X (2006) Solid State Ionics 177:631. doi:https://doi.org/10.1016/j.ssi.2006.01.030

    Article  CAS  Google Scholar 

  13. Chmaissem O, Zheng H, Huq A, Stephens PW, Mitchell JF (2008) J Solid State Chem 181:664. doi:https://doi.org/10.1016/j.jssc.2007.12.016

    Article  CAS  Google Scholar 

  14. Tsipis EV, Kharton VV, Frade JR (2006) Solid State Ionics 177:1823. doi:https://doi.org/10.1016/j.ssi.2006.03.037

    Article  CAS  Google Scholar 

  15. Shannon RD (1976) Acta Crystallogr A 32:751. doi:https://doi.org/10.1107/S0567739476001551

    Article  Google Scholar 

  16. Valldor M (2006) Solid State Sci 8:1272. doi:https://doi.org/10.1016/j.solidstatesciences.2006.05.014

    Article  CAS  Google Scholar 

  17. Schweika W, Valldor M, Lemmens P (2007) Phys Rev Lett 98:067201. doi:https://doi.org/10.1103/PhysRevLett.98.067201

    Article  CAS  Google Scholar 

  18. Shao ZP, Xiong GX, Yang WS (2001) J Inorg Mater 16:23

    CAS  Google Scholar 

  19. Yaremchenko AA, Patrakeev MV, Kharton VV, Marques FMB, Leonidov IA, Kozhevnikov VL (2004) Solid State Sci 6:357. doi:https://doi.org/10.1016/j.solidstatesciences.2004.01.005

    Article  CAS  Google Scholar 

  20. Katsuki M, Wang S, Dokiya M, Hashimoto T (2003) Solid State Ionics 156:453. doi:https://doi.org/10.1016/S0167-2738(02)00733-6

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Physical Engineering and Material Physics Laboratory, Zhengzhou University, Zhengzhou, 450052, China

    Song Wang, Haoshan Hao, Baofeng Zhu, Jianfeng Jia & Xing Hu

  2. Department of Mathematical and Physical Sciences, Henan Institute of Engineering, Zhengzhou, 451191, China

    Haoshan Hao

Authors
  1. Song Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Haoshan Hao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Baofeng Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jianfeng Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xing Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xing Hu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, S., Hao, H., Zhu, B. et al. Modifying the oxygen adsorption properties of YBaCo4O7 by Ca, Al, and Fe doping. J Mater Sci 43, 5385–5389 (2008). https://doi.org/10.1007/s10853-008-2806-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-008-2806-8

Keywords

Search

Navigation