Abstract
The knowledge of the phase diagram of the Al–Ge–Zn ternary system is of importance in the development of high temperature soldering materials. In this study, the phase diagram of the Al–Ge–Zn ternary system was calculated by the calculation of phase diagrams method using binary thermodynamic parameters included in the COST MP0602 thermodynamic database. Chosen alloys with compositions along two vertical sections with molar ratio Al/Ge = 3/1 and 1/3 were measured using DTA (differential thermal analysis). The experimentally determined phase transition temperatures from this work and phase equilibria data from literature were compared with calculation results and good mutual agreement was noticed.
Similar content being viewed by others
References
Saunders N, Miodownik AP. CALPHAD (calculation of phase diagrams)—a comprehensive guide. Oxford: Elsevier Science; 1998.
Lukas HL, Fries SG, Sundman B. Computational thermodynamics: the Calphad method. Cambridge: Cambridge University Press; 2007.
Dinsdale AT. SGTE unary database, version. 4.4. www.crct.polymtl.ca/sgte/Unary.TDB. Accessed 15 June 2011.
Ansara I, Bros JP, Gambino M. Thermodynamic analysis of the germanium-based ternary systems (Al–Ga–Ge, Al–Ge–Sn, Ga–Ge–Sn). CALPHAD. 1979;3:225–33.
an Mey S. Reevaluation of the Al–Zn system.Z. Metallknde. 1993;84:451–5.
Chevalier PY. A thermodynamic evaluation of the Ge–In, Ge–Pb, Ge–Sb, Ge–Tl and Ge–Zn systems. Thermochim Acta. 1989;155:227–40.
Dinsdale A, Watson A, Kroupa A, Vřešt’ál J, Zemanová A, Vízdal J. Atlas of phase diagrams for lead-free soldering, vol. 1. Brno: COST office; 2008, pp.11–16. ISBN 978-80-86292-28-1
Tyapkin D, Burykin AA, Malienko El. Isomorphic precipitation of Al–Zn alloys with a positif parameter of elastic constant anisotropy. Metallofizika. 1987;9:32–9.
Tadjbakhche E. Ph.D. Thesis, University of Lyon: 1977.
Storonkin AV, Vasil’kova AW, Krivousov VY. Thermo- graphic Study of the A1–Zn–Ge system and calculation of the fusibility diagrams of some ternary metallic system. Russ J Phys Chem. 1981;55:354–8.
Chattopadhyay S, Srikanth S, Ranganathan S. Aluminium–Germanium–Zinc. Ternary Alloys. 1993;6:93–108.
Jacob KT, Fitzner K. The estimation of the thermodynamic properties of ternary alloys from binary data using the shortest distance composition path. Thermochim Acta. 1977;18:197–206.
Srikanth S, Chattopadhyay S. Thermodynamic calculation of phase-equilibria in the Al–Ge–Zn system. Thermochim Acta. 1992;207:29–44.
COST MP0602—HISOLD Advanced Solder Materials for High Temperature Application. http://cost602.ipm.cz Accessed 15 June 2011.
Ipser H. Basic research on lead-free soldering. J Min Metall B Metall. 2007;43B:109–12.
Acknowledgements
This study was supported by Ministry of Science of the Republic of Serbia (Project OI 172037) and performed, also, in the frame of the European action COST MP0602—HISOLD. The authors wish to express their acknowledgement to Dr Diana Ćubela, University of Zenica, Faculty of Metallurgy and Materials.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Balanović, L., Manasijević, D., Živković, D. et al. Experimental investigation and thermodynamic prediction of the Al–Ge–Zn phase diagram. J Therm Anal Calorim 110, 221–226 (2012). https://doi.org/10.1007/s10973-012-2312-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10973-012-2312-8