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A study of thermal and dielectric behavior of manganese malonate dihydrate single crystals

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Abstract

Thermal decomposition of manganese malonate dihydrate single crystals grown by gel method has been studied using the TG-DTA and DSC techniques. The presence of water molecules and the dehydration stages are discussed. Dielectric constant, dielectric loss, and AC conductivity have been estimated as a function of temperature in the range of 40–120 °C for four different frequencies. Thermal studies reveal that the material is thermally stable up to123 °C. The dielectric measurements indicate that the dielectric parameters increase with the increase in temperature. Also, the dielectric constant and dielectric loss factor values decrease whereas the electrical conductivities increase with the increase in frequency of the AC applied.

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References

  1. Zhang Q-Z, Yang W-B, Chen S-M, Lu C-Z. Synthesis and crystal structures of two metal complexes incorporating malonate and organodiamine ligands. Bull Korean Chem Soc. 2005;26:1631–4.

    Article  CAS  Google Scholar 

  2. Delgado FS, Kerbellec N, Ruiz-Perez C, Cano J, Lloret F, Julve M. Malonate–containing manganese (III) complexes; synthesis, crystal structure and magnetic properties of As Ph4 [Mn (mal)2 (H2O)2]. Inorg Chem. 2006;45:1012–20.

    Article  CAS  Google Scholar 

  3. Bhagavannarayana G, Kushwaha SK, Parthiban S, Meenakshisundaram S. The influence of Mn-doping on the non-linear optical properties and crystalline perfection of tris (thiourea) zinc (II) sulphate crystals. J Cryst Growth. 2009;311:960–5.

    Article  CAS  Google Scholar 

  4. Marczynski S, Guskos N, Typek J, Grech E, Kolodziej B. Magnetic ordering process in manganese (II) di (hydrogen malonate) monohydrate complex studied by ESR spectroscopy. Mater Sci Poland. 2006;24:1139–44.

    CAS  Google Scholar 

  5. Gupta MP, Chand P. The crystal structure of manganese malonate dihydrate. Curr Sci. 1977;46:557.

    CAS  Google Scholar 

  6. Lis T, Matuszewski J. Manganese (II) malonate dihydrate: a re-investigation. Acta Cryst. 1979;B35:2212–4.

    CAS  Google Scholar 

  7. Blank Z. The growth of cadmium mercury thiocyanate and zinc mercury thiocyanate crystals in gels. J Cryst Growth. 1973;18:281–8.

    Article  CAS  Google Scholar 

  8. Mathew V, Joseph J, Jacob S, Abraham KE. Crystallization and spectroscopic studies of manganese malonate. Bull Mat Sci. 2010;33:433–7.

    Article  CAS  Google Scholar 

  9. Perumal S, Mahadevan CK. Growth and characterization of multiphased mixed crystals of KCl, KBr and KI–part 2: Electrical measurements. Physica B. 2005;367:172–81.

    Article  CAS  Google Scholar 

  10. Neelakanda Pillai N, Mahadevan CK. Preparation and electrical properties of (NaCl)x (NaBr)y-x (NaI) 1-y crystals. Mater Manuf Proc. 2007;22:393–9.

    Article  Google Scholar 

  11. Gabbott Paul. Principles and applications of thermal analysis. Oxford: U. K. Blackwell; 2008.

    Book  Google Scholar 

  12. Brown ME. Handbook of thermal analysis and calorimetry, vol. 1. Amsterdam: Elsevier; 2003.

    Google Scholar 

  13. Nabar MA, Jukar BN. Studies on double malonates-II. Potassium rare earth malonates, K5Ln (C3H2O4)4 (Ln = Gd–Ho or Y). Bull Chem Soc Jpn. 1985;58:3582–6.

    Article  CAS  Google Scholar 

  14. Muraishi K. Thermal decomposition of alkali metal malonate anhydrides in various atmospheres. Thermochimica Acta. 1990;164:401–9.

    Article  CAS  Google Scholar 

  15. Muraishi K, Suzuki Y, Takahashi Y. Thermal behavior of alkaline earth metal malonate hydrates and their anhydrides. Thermochimica Acta. 1996;286:187–98.

    Article  CAS  Google Scholar 

  16. Varughese PA, Saban KV, George J, Paul I, Varghese G. Crystallization and structural properties of calcium malonate hydrate. J Mat Sci. 2004;39:6325–31.

    Article  CAS  Google Scholar 

  17. Doreswamy BH, Mahendra M, Sridhar MA, Shashidhara Prasad J, Varughese PA, Saban KV, Varghese G. Structural studies on praseodymium malonate hydrate. J Mol Struct. 2003;659:81–8.

    Article  CAS  Google Scholar 

  18. Mathew V, Joseph J, Jacob S, Abraham KE. Spectroscopic characterization of gel grown strontium malonate crystals. Indian J Pure Appl Phys. 2011;49:21–4.

    CAS  Google Scholar 

  19. Caires FJ, Lima LS, Carvalho CT, Giagio RJ, Ionashiro M. Thermal behavior of malonic acid, sodium malonate and its compounds with some bivalent transition metal ions. Thermochimica Acta. 2010;497:35–40.

    Article  CAS  Google Scholar 

  20. Rzaczynska Z, Danczowska-Burdon A, Sienkiewicz-Gromiuk J. Thermal and spectroscopic properties of light lanthanides (III) and sodium complexes of 2,5-pyridinedicarboxylic acid. J Therm Anal Calorim. 2010;101:671–7.

    Article  CAS  Google Scholar 

  21. Wyrzykowski D, Chumurzynski L. Thermodynamics of citrate complexation with Mn2+, Co2+, Ni2+ and Zn2+ ions. J Therm Anal Calorim. 2010;102:61–4.

    Article  CAS  Google Scholar 

  22. Meena M, Mahadevan CK. Growth and dielectric properties of l-arginine acetate and l-arginine oxalate single crystals. Mater Lett. 2008;62:3742–4.

    Article  CAS  Google Scholar 

  23. Goma S, Padma CM, Mahadevan CK. Dielectric parameters of KDP single crystals added with urea. Mater Lett. 2006;60:3701–5.

    Article  CAS  Google Scholar 

  24. Meena M, Mahadevan CK. Growth and electrical characterization of l-arginine added KDP and ADP single crystals. Cryst Res Technol. 2008;43:166–72.

    Article  CAS  Google Scholar 

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Correspondence to K. E. Abraham.

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Mathew, V., Xavier, L., Mahadevan, C.K. et al. A study of thermal and dielectric behavior of manganese malonate dihydrate single crystals. J Therm Anal Calorim 105, 123–127 (2011). https://doi.org/10.1007/s10973-011-1412-1

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  • DOI: https://doi.org/10.1007/s10973-011-1412-1

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