Skip to main content
Log in

Thermo-oxidative reactions of crude oils

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

In this research, thermo-oxidative reactions of crude oils of different origin are determined in limestone matrix using simultaneous thermogravimetry and differential thermal analysis (TG–DTA) systems. Two different reaction regions were identified known as low temperature (LTO) and high temperature oxidation (HTO). Kinetic parameters of the samples were determined by four different methods and the results are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Bae JH. Characterization of crude oil for fire-flooding using thermal analysis methods. Soc Pet Eng AIME. 1977;17–3:211–8.

    Google Scholar 

  2. Ranjbar M, Pusch G. Pyrolysis and combustion kinetics of crude oils, asphaltenes and resins in relation to thermal recovery processes. J Anal Appl Pyrolysis. 1991;20:185–91.

    Article  CAS  Google Scholar 

  3. Ranjbar M. Influence of reservoir rock composition in crude oil pyrolysis sand combustion. J Anal Appl Pyrolysis. 1993;27–1:87–95.

    Article  Google Scholar 

  4. Kok MV. Use of thermal equipment to evaluate crude oils. Thermochim Acta. 1993;214:315–24.

    Article  CAS  Google Scholar 

  5. Kok MV, Sztatisz J, Pokol G. High pressure DSC applications on crude oil combustion. Energy Fuels. 1997;11:1137–42.

    Article  Google Scholar 

  6. Kok MV, Karacan O. Pyrolysis analysis and kinetics of crude oils. J Therm Anal Calorim. 1998;52:781–8.

    Article  CAS  Google Scholar 

  7. Goncalves MLA, Teixeira MAG, Pereira RCL, Mercury RLP, Matos JR. Contribution of thermal analysis for characterization of asphaltenes from Brazilian crude oil. J Therm Anal Calorim. 2001;64–2:06–697.

    Google Scholar 

  8. Kok MV, Keskin C. Comparative combustion kinetics for in situ combustion process. Thermochim Acta. 2001;369–2:143–7.

    Article  Google Scholar 

  9. Kok MV. An investigation into the combustion curves of lignites. J Therm Anal Calorim. 2001;64–3:1319–23.

    Article  Google Scholar 

  10. Kok MV. Thermal investigation of Seyitömer oil shale. Thermochim Acta. 2001;369–371:149–55.

    Article  Google Scholar 

  11. Kok MV, Pamir R. Non-isothermal pyrolysis and kinetics of oil shales. J Therm Anal Calorim. 1999;56:953–8.

    Article  CAS  Google Scholar 

  12. Coats AW, Redfern JP. Kinetic parameters from thermogravimetric data. Nature. 1964;201–491:68–9.

    Article  Google Scholar 

  13. Ingraham TR, Marrier P. Activation energy calculation from a linearly increasing temperature experiments. Can J Chem Eng. 1965;43–6:354–6.

    Article  Google Scholar 

  14. Kok MV, Acar C. Kinetics of crude oil combustion. J Therm Anal Calorim. 2006;83–2:445–9.

    Article  Google Scholar 

  15. Kok MV. Influence of reservoir rock composition on the combustion kinetics of crude oils. J Therm Anal Calorim. 2009;97–2:397–402.

    Article  Google Scholar 

  16. Kok MV. Effect of pressure and particle size on the thermal cracking of light crude oils in sandstone matrix. J Therm Anal Calorim. 2009;97–2:403–7.

    Article  Google Scholar 

  17. Kok MV, Gundogar AS. Effect of different clay concentrations on crude oil combustion kinetics bythermogravimetry. J Therm Anal Calorim. 2010;99–3:779–83.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mustafa Versan Kok.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kok, M.V. Thermo-oxidative reactions of crude oils. J Therm Anal Calorim 105, 411–414 (2011). https://doi.org/10.1007/s10973-010-1117-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-010-1117-x

Keywords

Navigation