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Thermodynamic Properties and Thermal Expansion of Tm2O3 · 2ZrO2 Solid Solution

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Abstract

The isobaric heat capacity of Tm2O3 · 2ZrO2 solid solution was measured by adiabatic calorimetry and differential scanning calorimetry (DSC), and smoothed values of the enthalpy changes, entropy, and reduced Gibbs free energy in the temperature range 8–1200 K were calculated. Thermal expansion was studied by X-ray diffraction in the temperature range 298–1173 K.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    P. G. Gagarin, A. V. Tyurin, V. N. Gus’kov, A. V. Khoroshilov & K. S. Gavrichev

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  1. P. G. Gagarin
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  2. A. V. Tyurin
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  3. V. N. Gus’kov
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  4. A. V. Khoroshilov
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  5. K. S. Gavrichev
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Corresponding author

Correspondence to V. N. Gus’kov.

Additional information

Original Russian Text © P.G. Gagarin, A.V. Tyurin, V.N. Gus’kov, A.V. Khoroshilov, K.S. Gavrichev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 11, pp. 1458–1464.

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Gagarin, P.G., Tyurin, A.V., Gus’kov, V.N. et al. Thermodynamic Properties and Thermal Expansion of Tm2O3 · 2ZrO2 Solid Solution. Russ. J. Inorg. Chem. 63, 1478–1483 (2018). https://doi.org/10.1134/S0036023618110050

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