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Low-temperature heat capacity of diglycylglycine

Some summaries and forecasts for the heat capacity of amino acids and peptides

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Abstract

Heat capacity of tripeptide diglycylglycine was measured in a temperature range from 6.5 to 304 K. The results were compared with those for glycine and glycylglycine. Peptide bonding was found not to change C P(T) virtually above 70 K, where heat capacity does not obey the Debye model.

Comparison with literature data allows one to expect a significant difference in the heat capacity for enantiomorph and racemic species of valine and leucine, like it was found recently for D-and DL-serine.

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References

  1. V. G. Badelin, O. V. Kulikov, V. S. Vatagin, E. Udzig, A. Zielenkiewicz, W. Zielenkiewicz and G. A. Krestov, Thermochim. Acta, 169 (1990) 81.

    Article  CAS  Google Scholar 

  2. V. A. Drebushchak, Y. A. Kovalevskaya, I. E. Paukov and E. V. Boldyreva, J. Therm. Anal. Cal., 74 (2003) 109.

    Article  CAS  Google Scholar 

  3. V. A. Drebushchak, E. V. Boldyreva, Y. A. Kovalevskaya, I. E. Paukov and T. N. Drebushchak, J. Therm. Anal. Cal., 79 (2005) 65.

    Article  CAS  Google Scholar 

  4. V. A. Drebushchak, Yu. A. Kovalevskaya, I. E. Paukov and E. V. Boldyreva, J. Therm. Anal. Cal., 85 (2006) 485.

    Article  CAS  Google Scholar 

  5. T. Srikrishnan, N. Winiewicz and R. Parthasarathy, Int. J. Pept. Protein Res., 19 (1982) 103.

    CAS  Google Scholar 

  6. G. G. Gorboletova and L. A. Kochergina, J. Therm. Anal. Cal., 87 (2007) 561.

    Article  CAS  Google Scholar 

  7. B. Wunderlich, J. Therm. Anal. Cal., 89 (2007) 321.

    Article  CAS  Google Scholar 

  8. O. V. Kulikov, V. A. Kozlov, L. I. Malenkina and V. G. Badelin, Heat Capacities of Amino Acids and Peptides and Excess Characteristics to their Aqueous Solutions, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo, Inst. nevod. rast., Akad. Nauk SSSR, (1989) 36.

  9. H. M. Huffman, J. Am. Chem. Soc., 63 (1941) 688.

    Article  CAS  Google Scholar 

  10. J. O. Hutchens, A. G. Cole and J. W. Stout, J. Biol. Chem., 244 (1969) 33.

    CAS  Google Scholar 

  11. G. S. Parks, H. M. Huffman and M. Barmore, J. Am. Chem. Soc., 55 (1933) 2733.

    Article  CAS  Google Scholar 

  12. J. O. Hutchens, A. G. Cole and J. W. Stout, J. Am. Chem. Soc., 82 (1960) 4813.

    Article  CAS  Google Scholar 

  13. C. H. Spink and I. Wadsö, J. Chem. Thermodyn., 7 (1975) 561.

    Article  CAS  Google Scholar 

  14. S. Skouilika and R. Sabbah, Thermochim. Acta, 61 (1983) 203.

    Article  Google Scholar 

  15. H. M. Huffman and H. Borsook, J. Am. Chem. Soc., 54 (1932) 4297.

    Article  CAS  Google Scholar 

  16. H. M. Huffman and E. L. Ellis, J. Am. Chem. Soc., 59 (1937) 2150.

    Article  CAS  Google Scholar 

  17. A. G. Cole, J. O. Hutchens and J. W. Stout, J. Phys. Chem., 67 (1963) 1852.

    Article  CAS  Google Scholar 

  18. V. A. Drebushchak, Yu. A. Kovalevskaya, I. E. Paukov and E. V. Boldyreva, J. Therm. Anal. Cal., 89 (2007) 649.

    Article  CAS  Google Scholar 

  19. H. N. Bordallo, B. A. Kolesov, E. V. Boldyreva and F. Juranyi, J. Am. Chem. Soc., 129 (2007) 10984.

    Article  CAS  Google Scholar 

  20. B. A. Kolesov and E. V. Boldyreva, J. Phys. Chem. B, 111 (2007) 14387.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Novosibirsk State University, Ul. Pirogova 2, Novosibirsk, 630090, Russia

    V. A. Drebushchak & Elena V. Boldyreva

  2. Institute of Geology and Mineralogy SB RAS, Pr. Ac. Koptyuga 3, Novosibirsk, 630090, Russia

    V. A. Drebushchak

  3. Institute of Inorganic Chemistry SB RAS, Pr. Ac. Lavrentieva 3, Novosibirsk, 630090, Russia

    V. A. Drebushchak, Yulia A. Kovalevskaya & I. E. Paukov

  4. Institute of Solid State Chemistry and Mechanochemistry SB RAS, Ul. Kutateladze 3, Novosibirsk, 630128, Russia

    Elena V. Boldyreva

Authors
  1. V. A. Drebushchak
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  2. Yulia A. Kovalevskaya
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  3. I. E. Paukov
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  4. Elena V. Boldyreva
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Correspondence to V. A. Drebushchak.

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Drebushchak, V.A., Kovalevskaya, Y.A., Paukov, I.E. et al. Low-temperature heat capacity of diglycylglycine. J Therm Anal Calorim 93, 865–869 (2008). https://doi.org/10.1007/s10973-007-8891-0

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  • DOI: https://doi.org/10.1007/s10973-007-8891-0

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