Skip to main content
Log in

Halloysite nanotubes/polystyrene (HNTs/PS) nanocomposites via in situ bulk polymerization

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Serials of halloysite nanotubes/polystyrene (HNTs/PS) nanocomposites with different contents of organo-modified halloysite nanotubes (organo-HNTs) were successfully prepared by the in situ bulk polymerization of styrene with the organo-HNTs as macromonomers. The percentage of grafting (PG%) of more than 230% was achieved, calculated from the results of the thermogravimetric analysis (TG). The TG results also showed that the thermal stabilities of the HNTs/PS nanocomposites prepared via the bulk polymerization were better than the pure polystyrene. And the maximum thermal degradation temperature of the nanocomposites increased with the increasing of the amount of the HNTs fillers added.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Fischer, Mater. Sci. Eng. C, 23 (2003) 763.

    Article  Google Scholar 

  2. S. C. Tjong, Mater. Sci. Eng. R, 53 (2006) 73.

    Article  Google Scholar 

  3. D. L. Burris, B. Boesl, G. R. Bourne and W. G. Sawyer, Macromol. Mater. Eng., 292 (2007) 387.

    Article  CAS  Google Scholar 

  4. G. Rupali and D. Amitabha, Chem. Mater., 13 (2000) 608.

    Google Scholar 

  5. B. M. Alexander, Polym. Adv. Technol., 17 (2007) 206.

    Google Scholar 

  6. S. C. Mojumdar, L. Raki, N. Mathis, K. Schmidt and S. Lang, J. Therm. Anal. Cal., 85 (2006) 119.

    Article  CAS  Google Scholar 

  7. M. Alexandre and P. Dubois, Mater. Sci. Eng. R., 28 (2000) 1.

    Article  Google Scholar 

  8. C. E. Powell and G. W. Beall, Curr. Opin. Solid State Mater. Sci., 10 (2006) 73.

    Article  CAS  Google Scholar 

  9. Q. H. Zeng, A. B. Yu, G. Q. Lu and D. R. Paul, J. Nanosci. Nanotechnol., 5 (2005) 1574.

    Article  CAS  Google Scholar 

  10. S. Sinha Ray and M. Okamoto, Prog. Polym. Sci., 28 (2003) 1539.

    Article  Google Scholar 

  11. A. Bansal, H. Yang, C. Li, B. C. Benicewicz, S. K. Kumar and L. S. Schadler, J. Polym. Sci.: Polym. Phys., 44 (2006) 2944.

    Article  CAS  Google Scholar 

  12. J. Xu, F. Qiu, H. Zhang and Y. Yang, J. Polym. Sci.: Polym. Phys., 44 (2006) 2811.

    Article  CAS  Google Scholar 

  13. S. S. Lee and J. Kim, J. Polym. Sci.: Polym. Phys., 42 (2004) 2367.

    Article  CAS  Google Scholar 

  14. D. Ciprai, K. Jacob and R. Tannenbaum, Macromolecules, 39 (2006) 6565.

    Article  Google Scholar 

  15. L. Schadler, Mater Mater., 6 (2007) 257.

    CAS  Google Scholar 

  16. P. Rittiqstein and J. M. Torkelson, J. Polym. Sci.: Polym. Phys., 44 (2006) 2935.

    Article  Google Scholar 

  17. P. Liu, E-Polymers, (2006) No. 070.

  18. P. Liu, Polymeric Nanostructures and their Applications, Ed. by H. S. Nalwa, Volume 2, Chapter 13, American Scientific Publishers, CA, 2007.

    Google Scholar 

  19. S. R. Levis and P.B. Deasy, Int. J. Pharm., 243 (2002) 125.

    Article  CAS  Google Scholar 

  20. H. Noro, Miner., 21 (1986) 401.

    CAS  Google Scholar 

  21. S. J. Antill, Aust. J. Chem., 56 (2003) 723.

    Article  CAS  Google Scholar 

  22. D. G. Shchukin, G. B. Sukhorukov, R. R. Price and Y. M. Lvov, Small, 1 (2005) 510.

    Article  CAS  Google Scholar 

  23. M. L. Du, B. C. Guo and D. M. Jia, Eur. Polym. J., 42 (2006) 1362.

    Article  CAS  Google Scholar 

  24. P. Liu, J. Tian, W. M. Liu and Q. J. Xue, Polym. J., 35 (2003) 379.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Liu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhao, M., Liu, P. Halloysite nanotubes/polystyrene (HNTs/PS) nanocomposites via in situ bulk polymerization. J Therm Anal Calorim 94, 103–107 (2008). https://doi.org/10.1007/s10973-007-8677-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-007-8677-4

Keywords

Navigation