Skip to main content
SpringerLink
Log in

Kinetic parameters of unsaturated polyester resin modified with poly(ε -caprolactone)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The curing of the neat unsaturated polyester resin (UP) with benzoyl peroxide (initiator) as well as the curing of UP modified with two poly(ε-caprolactone) PCL samples (PCL2 and PCL50) of different molecular masses (M n=2⋅103 and M n=5⋅104, respectively), were investigated by non-isothermal differential scanning calorimetry (DSC), at different heating rates. The activation energy was determined from the variation of the peak exotherm temperature, T peak, upon heating rate. Besides, the degree of conversion (α) was obtained from isothermal DSC measurements at 80°C at different curing times for neat UP, UP+ PCL2 and UP+PCL50. Kinetic parameters were deduced assuming the n th order reaction kinetic model for neat UP, UP+PCL2 and UP+PCL50 systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. ASM International Handbook Engineering Plastics, Vol. 2 ASM International 1997.

  2. Q Guo (1995) Polymer 36 4753 Occurrence Handle10.1016/0032-3861(95)99290-B Occurrence Handle1:CAS:528:DyaK2MXpvVOjurg%3D

    Article  CAS  Google Scholar 

  3. Q Guo H Zheng (1999) Polymer 40 6377 Occurrence Handle10.1016/S0032-3861(98)00326-7

    Article  Google Scholar 

  4. D Nava C Salom MG Prolongo RM Masegosa (2003) J. Mater. Process. Technol. 1 6835

    Google Scholar 

  5. RM Masegosa D Nava MG Prolongo C Salom (2006) Thermochim. Acta 440 93 Occurrence Handle10.1016/j.tca.2005.10.019 Occurrence Handle1:CAS:528:DC%2BD2MXht12ls7fN

    Article  CAS  Google Scholar 

  6. M Avella E Martuscelli M Mazzola (1985) J. Thermal Anal. 30 1359 Occurrence Handle10.1007/BF01914307 Occurrence Handle1:CAS:528:DyaL28Xit1Gkt7Y%3D

    Article  CAS  Google Scholar 

  7. K de la Caba P Guerrero A Eceiza I Mondragón (1997) Eur. Polym. J. 33 19 Occurrence Handle10.1016/S0014-3057(96)00110-3 Occurrence Handle1:CAS:528:DyaK2sXot1Srug%3D%3D

    Article  CAS  Google Scholar 

  8. W Li J Lee (1998) Polymer 39 5677 Occurrence Handle10.1016/S0032-3861(98)00074-3 Occurrence Handle1:CAS:528:DyaK1cXls1Kiurg%3D

    Article  CAS  Google Scholar 

  9. K de la Caba P Guerrero I Mondragón JM Kenny (1998) Polym. Int. 45 333 Occurrence Handle10.1002/(SICI)1097-0126(199804)45:4<333::AID-PI932>3.0.CO;2-T

    Article  Google Scholar 

  10. N Delahaye S Marais JM Saiter M Metayer (1998) J. Appl. Polym. Sci. 67 695 Occurrence Handle10.1002/(SICI)1097-4628(19980124)67:4<695::AID-APP12>3.0.CO;2-3 Occurrence Handle1:CAS:528:DyaK1cXjtVCnuw%3D%3D

    Article  CAS  Google Scholar 

  11. Y M.Yun SJ Lee KJ Lee YK Lee JD Nam (1997) J. Polym. Sci. B. 35 2447 Occurrence Handle10.1002/(SICI)1099-0488(19971115)35:15<2447::AID-POLB7>3.0.CO;2-Q

    Article  Google Scholar 

  12. W Li LJ Lee KH Hsu (2000) Polymer 41 711 Occurrence Handle10.1016/S0032-3861(99)00179-2 Occurrence Handle1:CAS:528:DyaK1MXntlyhsr4%3D

    Article  CAS  Google Scholar 

  13. W Li LJ Lee (2000) Polymer 41 697 Occurrence Handle10.1016/S0032-3861(99)00178-0 Occurrence Handle1:CAS:528:DyaK1MXntlyiu7c%3D

    Article  CAS  Google Scholar 

  14. M Messori M Toselli F Pilati C Tonelli (2001) Polymer 42 9877 Occurrence Handle10.1016/S0032-3861(01)00521-3 Occurrence Handle1:CAS:528:DC%2BD3MXmslCksLo%3D

    Article  CAS  Google Scholar 

  15. V Kosar Z Gomzi (2004) Eur. Polym. J. 40 2793 Occurrence Handle10.1016/j.eurpolymj.2004.07.027 Occurrence Handle1:CAS:528:DC%2BD2cXpt1SrtL0%3D

    Article  CAS  Google Scholar 

  16. YJ Huang JS Leu (1993) Polymer 34 295 Occurrence Handle10.1016/0032-3861(93)90080-T Occurrence Handle1:CAS:528:DyaK3sXhtVegs7w%3D

    Article  CAS  Google Scholar 

  17. EMS Sanchez CAC Zavaglia MI Felisberti (2000) Polymer 41 765 Occurrence Handle10.1016/S0032-3861(99)00184-6 Occurrence Handle1:CAS:528:DyaK1MXntlyhsrk%3D

    Article  CAS  Google Scholar 

  18. E Bureau K Chebli C Cabot JM Saiter F Dreux S Marais M Metayer (2001) Eur. Polym. J. 37 2176 Occurrence Handle10.1016/S0014-3057(01)00114-8

    Article  Google Scholar 

  19. JC Lucas J Borrajo RJJ Williams (1993) Polymer 34 1886 Occurrence Handle10.1016/0032-3861(93)90430-I Occurrence Handle1:CAS:528:DyaK3sXkt12iurY%3D

    Article  CAS  Google Scholar 

  20. YJ Huang CC Su (1994) Polymer 35 2397 Occurrence Handle10.1016/0032-3861(94)90779-X Occurrence Handle1:CAS:528:DyaK2cXktlKrurg%3D

    Article  CAS  Google Scholar 

  21. JL Martin (1999) Polymer 40 3451 Occurrence Handle10.1016/S0032-3861(98)00556-4 Occurrence Handle1:CAS:528:DyaK1MXhvFegsr8%3D

    Article  CAS  Google Scholar 

  22. JM Salla A Cadenato X Ramis M Morancho (1999) J. Therm. Anal. Cal. 56 441 Occurrence Handle10.1023/A:1010158223347

    Article  Google Scholar 

  23. TR Cuadrado J Borrajo RJJ Williams FM Clara (1983) J. Appl. Polym. Sci. 28 485 Occurrence Handle10.1002/app.1983.070280205 Occurrence Handle1:CAS:528:DyaL3sXptVSmuw%3D%3D

    Article  CAS  Google Scholar 

  24. H Ng I Mana-Zloczower (1989) Polym. Eng. Sci. 29 1097 Occurrence Handle10.1002/pen.760291604 Occurrence Handle1:CAS:528:DyaK3cXnvVGktg%3D%3D

    Article  CAS  Google Scholar 

  25. T Ozawa (1970) J. Thermal Anal. 2 301 Occurrence Handle10.1007/BF01911411 Occurrence Handle1:CAS:528:DyaE3MXmvVaisw%3D%3D

    Article  CAS  Google Scholar 

  26. M Avella E Martuscelli MG Volpe (1988) J. Thermal Anal. 34 441 Occurrence Handle10.1007/BF01913183 Occurrence Handle1:CAS:528:DyaL1cXkvFektbY%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. E.T.S.I. Aeronáuticos, Universidad Politécnica de Madrid, Madrid, Spain

    Escribano J., Prolongo M. G. & Salom Catalina

  2. E.U.I.T. Aeronáutica, Universidad Politécnica de Madrid, Madrid, Spain

    Masegosa R. & Nava D.

Authors
  1. Escribano J.
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Masegosa R.
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nava D.
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Prolongo M. G.
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Salom Catalina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Salom Catalina.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Escribano, J., Masegosa, R., Nava, D. et al. Kinetic parameters of unsaturated polyester resin modified with poly(ε -caprolactone). J Therm Anal Calorim 86, 675–679 (2006). https://doi.org/10.1007/s10973-006-7892-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-006-7892-8

Keywords

Search

Navigation