Skip to main content
Log in

Synthesis, characterization and luminescence properties of SrLa2(MoO4)4:Eu phosphors

  • Original Category
  • Published:
Journal of Sol-Gel Science and Technology Aims and scope Submit manuscript

Abstract

SrLa2(MoO4)4 (SLM) phosphors doped with Eu3+ ions were prepared by a sol–gel combustion method using citric acid as a fuel/reductant and nitrates as oxidants. The crystallization processes were tracked by means of X-ray diffraction and thermo-gravimetric analysis and differential scanning calorimetry. The size and shape of the products were characterized using a scanning electron microscope, while the luminescent spectra of these resulting phosphors were recorded using a photoluminescence (PL) spectrophotometer. PL studies reveal that the emission intensity of SLM:Eu phosphors was strongly related to sintering temperature as well as the doping concentration of Eu3+ ions. The present phosphor has a strong excitation at 395 and 459 nm, indicating that it could serve as a promising red-emitting candidate for near-UV and GaN-based blue light-emitting diode chips.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Shao QY, Li HJ, Wu KW, Dong Y, Jiang JQ (2009) Photoluminescence studies of red-emitting NaEu(WO4)2 as a near-UV or blue convertible phosphor. J Lumin 129:879–883

    Article  CAS  Google Scholar 

  2. Guo CF, Chen T, Luan L, Zhang W, Huang DX (2008) Luminescent properties of R2(MoO4)3: Eu3+ (R = La, Y, Gd) phosphors prepared by sol-gel process. J Phys Chem Solids 69:1905–1911

    Article  CAS  Google Scholar 

  3. Thomas M, Rao PP, Deepa M, Chandran MR, Koshy P (2009) Novel powellite-based red-emitting phosphors: CaLa1−x NbMoO8:xEu3+ for white light emitting diodes. J Solid State Chem 182:203–207

    Article  CAS  Google Scholar 

  4. Nishiura S, Tanabe S, Fujioka K, Fujimoto Y (2011) Properties of transparent Ce:YAG ceramic phosphors for white LED. Optic Mater 33:688–691

    Article  CAS  Google Scholar 

  5. Ge XX, Sun YH, Liu C, Qi WK (2009) Influence of combustion reagent and microwave drying method on the characteristics of nano-sized Nd3+:YAG powders synthesized by the gel combustion method. J Sol-Gel Sci Techn 52:179–187

    Article  CAS  Google Scholar 

  6. Won CW, Nersisyan HH, Won HI, Youn JW (2011) Integrated chemical process for exothermic wave synthesis of high luminance YAG: Ce phosphors. J Lumin 131:2174–2180

    Article  CAS  Google Scholar 

  7. Nishida T, Ban T, Kobayashi N (2003) High-color-rendering light sources consisting of a 350-nm ultraviolet light-emitting diode and three-basal-color phosphors. Appl Phys Lett 22:3817–3819

    Article  Google Scholar 

  8. Wang ZL, Liang HB, Gong ML, Su Q (2007) Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure. J Alloys Compd 432:308–312

    Article  CAS  Google Scholar 

  9. Ci Z, Wang Y, Zhang J, Sun Y (2008) Ca1−xMo1−ySiyO4: Eu 3+x : a novel red phosphor for white light emitting diodes. Phys B 403:670–674

    Article  CAS  Google Scholar 

  10. Yi LH, He XP, Zhou LY, Gong FZ, Wang RF, Sun JH (2010) A potential red phosphor LiGd(MoO4)2:Eu3+ for light-emitting diode application. J Lumin 130:1113–1117

    Article  CAS  Google Scholar 

  11. Zhou LY, Wei JS, Wu JR, Gong FZ, Yi LH, Huang JL (2009) Potential red-emitting phosphor for white LED solid-state lighting. J Alloys Compd 476:390–392

    Article  CAS  Google Scholar 

  12. Wu HY, Hu YH, Zhang W, Kang FW, Li NN, Ju GF (2012) Sol–gel synthesis of Eu3+ incorporated CaMoO4: the enhanced luminescence performance. J Sol-Gel Sci Techn 62:227–233

    Article  CAS  Google Scholar 

  13. Li LL, Shen XQ, Li L, Meng XF (2010) Preparation and characterization of Li0.25Sr0.5(MoO4):Eu 3+0.25 red-emitting phosphors for white LEDs by organic gel-thermal decomposition process. J Sol-Gel Sci Techn 57:198–203

    Article  Google Scholar 

  14. Haque M, Kim DK (2009) Luminescent properties of Eu3+ activated MLa2(MoO4)4 based (M = Ba, Sr and Ca) novel red-emitting phosphors. Mater Lett 63:793–796

    Article  CAS  Google Scholar 

  15. Cao FB, Tian YW, Chen YJ, Xiao LJ, Wu Q (2008) Novel red phosphors for solid-state lighting: Ca0.54Sr0.34−1.5xEu0.08La x (MoO4) y (WO4)1−y . J Alloys Compd 475:387–390

    Article  Google Scholar 

  16. Han YC, Wang XY, Li SP, Ma XH (2008) Synthesis of terbium doped calcium phosphate nanocrystalline powders by citric acid sol–gel combustion method. J Sol-Gel Sci Techn 49:125–129

    Article  Google Scholar 

  17. Chen QJ, Qin LJ, Feng ZQ, Ge R, Zhao XJ, Xu HZ (2011) Upconversion luminescence of KGd(MoO4)2: Er3+, Yb3+ powder prepared by Pechini method. J Rare Earth 29:843–848

    Article  CAS  Google Scholar 

  18. Guo C, Yang HK, Jeong J-H (2010) Preparation and luminescent properties of phosphor MGd2(MoO4)4:Eu3+ (M = Ca, Sr and Ba). J Lumin 130:1390–1393

    Article  CAS  Google Scholar 

  19. Haque M, Kim D-K (2009) Luminescent properties of Eu3+ activated MLa2(MoO4)4 based (M = Ba, Sr and Ca) novel red-emitting phosphors. Mater Lett 63:793–796

    Article  CAS  Google Scholar 

  20. Li Z-M, Zhong Y-J, Gao S-K (2012) Luminescent properties of red phosphors K2Ba (MoO4)2:Eu3+ for white light emitting diodes. J Rare Earths 30:990–994

    Article  CAS  Google Scholar 

  21. Patterson AL (1939) The Scheerer formula for X-ray particle size determination. Phys Rew 56:978–982

    Article  CAS  Google Scholar 

  22. Xia G, Zhou S, Zhang J, Wang S, Liu Y, Xu J (2005) Sol-gel combustion synthesis and luminescent properties of nanocrystalline YAG:Eu3+ phosphors. J Cryst Growth 283:257–262

    Article  CAS  Google Scholar 

  23. Blasse G, Bril A (1970) Characteristic luminescence. Philips Tech Rev 31:304–334

    CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Nature Science Foundation of China (No. 31070517), the 973 Program (No. 2013CB932902) and NNSF of China (No. 21173042).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jiancheng Zhou.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, N., Zhou, B., Zhou, J. et al. Synthesis, characterization and luminescence properties of SrLa2(MoO4)4:Eu phosphors. J Sol-Gel Sci Technol 67, 196–202 (2013). https://doi.org/10.1007/s10971-013-3067-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10971-013-3067-9

Keywords

Navigation