Skip to main content
SpringerLink
Log in

Infrared, Raman, 1H NMR, TG, and SEM properties of the charge-transfer interactions between tris(hydroxymethyl)methane with the acceptors picric acid, chloranilic acid, and 1,3-dinitrobenzene

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Intermolecular charge-transfer complexes (CT) between the tris(hydroxymethyl)methane (THM) as a donor and picric acid (PA), chloranilic acid (CLA) and 1,3-dinitrobenzene (DNB) as a π-acceptor have been structurally, thermally and morphologically studied in methanol at room temperature. Based on elemental analyses (CHN), the stoichiometry of the obtained CT complexes (THM: acceptor molar ratios) was determined to be 1 : 1 for all three complexes. The CT complexes have been characterized via elemental analyses (CHN), IR, Raman and 1H NMR spectroscopy in order to predict the position of the CT interaction between the donating and accepting sites. Thermal decomposition behavior of these complexes was also investigated, and their kinetic thermodynamic parameters were calculated with Coats-Redfern and Horowitz-Metzger methods. Finally, the microstructure properties of these complexes were observed using scanning electron microscope (SEM).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mulliken, R.S., J. Am. Chem. Soc., 1950, vol. 72, p. 4493.

    Article  CAS  Google Scholar 

  2. Mulliken, R.S. and Pearson, W.B., Molecular Complexes, New York: Wiley Publishers, 1969.

    Google Scholar 

  3. Foster, R., Charge Transfer Complexes, London: Academic Press, 1969.

    Google Scholar 

  4. Mulliken, R.S., J. Am. Chem. Soc., 1952, vol. 74, p. 811.

    Article  CAS  Google Scholar 

  5. Mulliken, R.S., J. Phys. Chem., 1952, vol. 56, p. 801.

    CAS  Google Scholar 

  6. Roy, T., Dutta, K., Nayek, M.K., Mukherjee, A.K., Banerjee, M., and Seal, B.K., J. Chem. Soc., Perkin Trans. 2, 1999, p. 2219.

    Google Scholar 

  7. Roy, D.K., Saha, A., and Mukherjee, A.K., Spectrochim. Acta A, 2005, vol. 61, p. 2017.

    Article  Google Scholar 

  8. Slifkin, A.M., Charge-Transfer Interaction of Biomolecules, New York: Academic Press, 1971.

    Google Scholar 

  9. Dozal, A., Keyzer, H., Kim, H.K., and Wang, W.W., Int. J. Antimicrob. Agent, 2000, vol. 14, p. 261.

    Article  CAS  Google Scholar 

  10. Korolkovas, A., Essentials of Medical Chemistry, 2nd ed., New York: Wiley, 1998, ch. 3.

    Google Scholar 

  11. Pandeeswaran, M., El-Mossalamy, E.H., and Elango, E.H., Int. J. Chem. Kinet., 2009, vol. 41, p. 787.

    Article  CAS  Google Scholar 

  12. Pandeeswaran, M. and Elango, K.P., Spectrochim. Acta A, 2010, vol. 75, p. 1462.

    Article  CAS  Google Scholar 

  13. Yakuphanoglu, F. and Arslan, M., Solid State Commun., 2004, vol. 132, p. 229.

    Article  CAS  Google Scholar 

  14. Yakuphanoglu, F. and Arslan, M., Opt. Mater., 2004, vol. 27, p. 29.

    Article  CAS  Google Scholar 

  15. Yakuphanoglu, F., Arslan, M., Kucukislamoglu, M., and Zengin, M., Sol. Energy, 2005, vol. 79, p. 96.

    Article  CAS  Google Scholar 

  16. Andrade, S.M., Costa, S.M.B., and Pansu, R., J. Colloid Interface Sci., 2000, vol. 226, p. 260.

    Article  CAS  Google Scholar 

  17. Jakubiak, R., Bao, Z., and Rothberg, L., Synth. Met., 2000, vol. 114, p. 61.

    Article  CAS  Google Scholar 

  18. Eychmuller, A. and Rogach, A.L., Pure Appl. Chem., 2000, vol. 72, p. 179.

    Article  CAS  Google Scholar 

  19. Das, S.K., Krishnamoorthy, G., and Dofra, S.K., Can. J. Chem., 2000, vol. 78, p. 191.

    Article  CAS  Google Scholar 

  20. Smith, G., Bott, R.C., Rae, A.D., and Willis, A.C., Aust. J. Chem., 2000, vol. 53, p. 531.

    Article  CAS  Google Scholar 

  21. Adam, A.M.A., Refat, M.S., and Saad, H.A., J. Mol. Struct., 2013, no. 1051, p. 144.

    Google Scholar 

  22. Adam, A.M.A., Refat, M.S., and Saad, H.A., J. Mol. Struct., 2013, no. 1037, p. 376.

    Google Scholar 

  23. Adam, A.M.A., Spectrochim. Acta A, 2013, no. 104, p. 1.

    Google Scholar 

  24. Khan, I.M. and Ahmad, A., J. Mol. Struct., 2013, no. 1050, p. 122.

    Google Scholar 

  25. Refat, M.S., Adam, A.M.A., Sharshar, T., Saad, H.A., and Eldaroti, H.H., Spectrochim. Acta A, 2014, no. 122, p. 34.

    Google Scholar 

  26. Refat, M.S., El-Sayed, M.Y., Adam, A.M.A., Saad, H.A., and Eldaroti, H.H., Int. J. Electrochem. Sci., 2013, no. 8, p. 4234.

    Google Scholar 

  27. Adam, A.M.A., Refat, M.S., Saad, H.A., and Eldaroti, H.H., Eur. Chem. Bull., 2012, no. 1(7), p. 241.

    Google Scholar 

  28. Kross, R.D. and Fassel, V.A., J. Am. Chem. Soc., 1957, vol. 79, p. 38.

    Article  CAS  Google Scholar 

  29. Al-Attas, A.S., Habeeb, M.M., and Al-Raimi, D.S., J. Mol. Struct., 2000, no. 928, p. 158.

    Google Scholar 

  30. Coats, A.W. and Redfern, J.P., Nature (London), 1964, no. 201, p. 68.

    Google Scholar 

  31. Horowitz, H.H. and Metzger, G., Anal. Chem., 1963, no. 35, p. 1464.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Taif University, Al-Haweiah, P.O. Box 888, Zip Code 21974, Taif, Saudi Arabia

    Moamen S. Refat, Hosam A. Saad & Abdel Majid A. Adam

  2. Department of Chemistry, Faculty of Science, Port Said University, Port Said, Egypt

    Moamen S. Refat

  3. Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt

    Hosam A. Saad

Authors
  1. Moamen S. Refat
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hosam A. Saad
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Abdel Majid A. Adam
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Moamen S. Refat.

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Refat, M.S., Saad, H.A. & Adam, A.M.A. Infrared, Raman, 1H NMR, TG, and SEM properties of the charge-transfer interactions between tris(hydroxymethyl)methane with the acceptors picric acid, chloranilic acid, and 1,3-dinitrobenzene. Russ J Gen Chem 84, 1417–1428 (2014). https://doi.org/10.1134/S1070363214070305

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363214070305

Keywords

Search

Navigation