Abstract
We describe a new approach to the bench top production of surrogate nuclear explosion debris by employing high power continuous wave CO2 laser irradiation. High surface temperatures >2,500 K can be rapidly attained, allowing virtually any combination of materials to be fused into a glassy matrix that can display high levels of elemental fractionation. Examples of the laser fused glasses will be presented and compared to trinitite nuclear explosion glass along with the elemental fractionation effects that were induced in the NIST glass standard SRM-612 by this method.
Similar content being viewed by others
References
Carney KP, Finck MR, McGrath CA, Martin LR, Lewis RR (2014) The development of radioactive glass surrogates for fallout debris. J Radioanal Nucl Chem 299:363–372
Harvey SD, Liezers M, Antolick KC, Garcia BJ, Sweet LE, Carman AJ, Eiden GC (2013) Porous chromatographic materials as substrates for preparing synthetic nuclear explosion debris particles. J Radioanal Nucl Chem 298:1885–1898
Pravin PP, Semkow TM, Torres MA, Haines DK, Cooper JM, Rosenburg PM, Kitto ME (2006) Radioactivity in Trinitite six decades later. J Enviro Radioact 85:103–120
Nygren U, Ramebäck H, Nilsson C (2007) Age determination of plutonium using inductively coupled plasma mass spectrometry. J Radioanal Nucl Chem 272:45–51
Fahey AJ, Zeissler CJ, Newbury JD, Lindstrom RM (2010) Postdetonation nuclear debris for attribution. Proc Natl Acad Sci USA 107(47):20207–20212
Bellucci JJ, Simonetti A (2012) Nuclear Forensics: searching for nuclear device debris in Trinitite-hosted inclusions. J Radioanal Nucl Chem 293:313–319
Bellucci JJ, Wallace C, Koeman EC, Simonetti A, Burns PC, Kieser J, Port E, Walczak T (2012) Distribution and behavior of some radionuclides associated with the Trinity nuclear test. J Radioanal Nucl Chem 295:2049–2057
Wallace C, Bellucci JJ, Simonetti A, Hainley T, Koeman EC, Burns PC (2013) A multi-method approach for the determination of radionuclide distribution in Trinitite. J Radioanal Nucl Chem 298:993–1003
Bellucci JJ, Simonetti A, Wallace C, Koeman EC, Burns PC (2013) Isotopic fingerprinting of the world’s first nuclear device using post-detonation materials. Anal Chem 85(8):4195–4198
Bellucci JJ, Simonetti A, Wallace C, Koeman EC, Burns PC (2013) Lead isotopic composition of Trinitite melt glass: evidence for the presence of Canadian industrial lead in the first atomic bomb test. Anal Chem 85(15):7588–7593
IAEA (2005) Radiological conditions at the Former French Nuclear Test Sites in Algeria: preliminary assessment and recommendations. IAEA, Vienna, Radiological report series ISSN 1020-6566, STI/PUB/1215, ISBN 92-0-113304-9
Pittauerová D, Kolb WM, Rosenstiel JC, Fischer HW (2010) Radioactivity in Trinitite: a review and new measurements. Proceedings of the 3rd European IRPA Congress, Helsinki, Finland
Dai ZR, Crowhurst JC, Grant CD, Knight KB, Tang V, Chernov AA, Cook EG, Lotscher JP, Hutcheon ID (2013) Exploring high temperature phenomena related to post-detonation using an electric arc. J Appl Phys 114:204901. doi:10.1063/1.4829660
Liezers M, Harvey SD, Eiden GC, Carman AJ (2014) Poster presentation generation and analysis of Surrogate Nuclear Explosion Debris using the ICP. Winter Plasma Conference, Amelia Island, Florida, 11–16 Jan 2014
Jerome S, Leggitt J, Inn KGW (2012) Fresh, post-IND reference material based on glass. Presentation at the International Workshop on Certified Reference Materials for Nuclear Measurements, Saclay, France
Ramirez SM, Diaz L, Camacho JJ (2013) Cw CO2-laser-induced formation of Fulgurite on Lime-pozzolan mortar. J Am Ceram Soc 96(9):2824–2830
Koch J, Heiroth S, Lippert T, Günther D (2010) Femtosecond laser ablation: Visualization of the aerosol formation process by light scattering and shadow graphic imaging. Spectrochim Acta B 65(11):943–949
Liu HC, Mao XL, Yoo JH, Russo RE (1999) Early phase laser induced plasma diagnostics and mass removal during single-pulse laser ablation of silicon. Spectrochim Acta B 54(11):1607–1624
Russo RE, Mao X, Liu H, Gonzalez J, Mao SS (2002) Laser ablation in analytical chemistry-a review. Talanta 57(3):425–451
DeMaria AJ, Hennessey TV (2010) The CO2 laser: the workhorse of the laser material processing industry, SPIE Professional Magazine, http://spie.org/Documents/Membership/laser_co2_demaria_hennessey.pdf
Lioy PJ, Weisel CP, Millette JR, Eisenreich S, Vallero D, Offenberg J, Buckley B, Turpin B, Zhong M, Cohen MD, Prophete C, Yang I, Stiles R, Chee G, Johnson W, Porcja R, Alimokhtari S, Hale RC, Weschler C, Chen LC (2002) Characterization of the dust/smoke aerosol that settled east of the World Trade Center (WTC) in Lower Manhattan after the collapse of the WTC 11 September 2001. Environ Health Perspect 110(7):703–714
McGee JK, Chen LC, Cohen MD, Chee GR, Prophete CM, Haykal-Coates N, Wasson SJ, Conner TL, Costa DL, Gavett SH (2003) Chemical analysis of World Trade Center fine particulate matter for use in toxicologic assessment. Environ Health Perspect 111(7):972–980
Jochum KP, Weis U, Stoll B, Kuzmin D, Yang Q, Raczek I, Jacob DE, Stracke A, Birbaum K, Frick DA, Günther D, Enzweiler J (2011) Determination of reference values for NIST SRM 610-617 glasses following ISO guidelines. Geostand Geoanal Res 35(4):397–429
Lide DR (ed) (1997) CRC handbook of chemistry and physics. CRC Press, New York. ISBN 0-8493-0478-4
Lodders K (2003) Solar system abundances and condensation temperatures of the elements. Astrophys J 591:1220–1247
Freiling EC (1961) Radionuclide fractionation in bomb debris. Science 133:1991–1999
Gibson TA (1968) Observed fractionation in ground level fallout from three nuclear cratering detonations. University of California, Lawrence Radiation Laboratory report: TID-4500 UC-35, San Diego
Morely D, Izrael LA, Izrael YA (2002) Radioactive fallout after nuclear explosions and accidents. ISBN 0-080-43855-5, Elsevier Science Ltd
Cassata WS, Prussin SG, Knight KB, Hutcheon ID, Isselhardt BH, Renne PR (2014) When the dust settles: stable xenon isotope ratio constraints on the formation of nuclear fallout. J Environ Radioact 137:88–95
Acknowledgments
My thanks to Dr. John McCloy at Washington State University, Pullman for bringing to our attention the CO2 laser Fulgurite article [16] that sparked this line of research. This work was funded by the Office of Defense Nuclear Nonproliferation Research and Development with the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC05-75RLO1830. The views, opinions and findings contained within this paper are those of the authors and should not be construed as an official position, policy or decision of the DOE unless designated by other documentation.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Liezers, M., Fahey, A.J., Carman, A.J. et al. The formation of trinitite-like surrogate nuclear explosion debris (SNED) and extreme thermal fractionation of SRM-612 glass induced by high power CW CO2 laser irradiation. J Radioanal Nucl Chem 304, 705–715 (2015). https://doi.org/10.1007/s10967-014-3895-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-014-3895-2