Abstract
A kind of silica composite containing bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272) was prepared via a in situ sol–gel approach. 31P solid-state NMR and FT–IR spectra were employed to analyze the structure of the composite. The thermal stability and surface properties were characterized, and the adsorption ability towards trivalent neodymium (Nd(III)) was evaluated by batch experiments. The Cyanex 272 loaded silica composite showed the advantage of an effective adsorption of Nd(III) from low acidic or neutral solutions with a capacity of ~50 mg/g. The influence of contact time, acidity and initial metal concentration of the stock solutions on the adsorption were comprehensively investigated.
Similar content being viewed by others
References
Shin YJ, Kim IS, Lee WK, Shin HS, Ro SG (1996) J Radioanal Nucl Chem Art 209:217
Doyle FM (2003) Int J Miner Process 72:387
Sastre AM, Kumar A, Shukla JP, Singh RK (1998) Sep Purif Methods 27:213
Zhong X, Wu Y (2012) J Radioanal Nucl Chem 292:355
Hussein AEM (2011) J Radioanal Nucl Chem 289:321
Madane NS, Nikam GH, Mahanwar KR, Mohite BS (2011) J Radioanal Nucl Chem 288:285
Madane NS, Mohite BS (2011) J Radioanal Nucl Chem 290:649
Dogmane SD, Singh RK, Bajpai DD, Mathur JN (2002) J Radioanal Nucl Chem 253:477
Swain B, Otu EO (2011) Sep Purif Technol 83:82
Naik P, Dhami P, Misra S, Jambunathan U, Mathur J (2003) J Radioanal Nucl Chem 257:327
Bhattacharyya A, Mohapatra PK, Manchanda VK (2006) J Chromatogr A 1123:26
Bhattacharyya A, Mohapatra PK, Manchanda VK (2007) Solvent Extr Ion Exch 25:27
Sano Y, Surugaya N, Yamamoto M (2009) In: Actinides Conference, vol 9. IOP Publishing Ltd, San Francisco
Liu RQ, Wei YZ, Tozawa D, Xu YL, Usuda S, Yamazaki H, Ishii K, Sano Y, Koma Y (2011) Nucl Sci Technol 22:18
Zhang A, Wei Y, Kumagai M (2005) J Radioanal Nucl Chem 265:409
Wei Y, Kumagai M, Takashima Y, Modolo G, Odoj R (2000) Nucl Technol 132:413
Zhang A, Wei Y, Kumagai M, Koma Y (2005) J Alloys Compd 390:275
Cortina JL, Miralles N, Sastre A, Aguilar M, Profumo A, Pesavento M (1992) React Polym 18:67
Zhu YJ, Chen JF, Choppin GR (1996) Solvent Extr Ion Exch 14:543
Chen J, Zhu YJ, Jiao RZ (1996) Sep Sci Technol 31:2723
Zhu YJ, Chen J, Jiao RZ (1996) Solvent Extr Ion Exch 14:61
Chen J, Zhu YJ, Jiao RZ (1998) Nucl Technol 122:64
Chen J, Jiao RZ, Zhu YJ (1999) Radiochim Acta 86:151
Chen J, Wang F, He XH, Pan DF (2011) Prog Chem 23:1338 (in Chinese)
Yonghui Y, Jinglan S, Sixiu S (1989) Huaxue Shiji 11:381 (in Chinese)
Wang J, Zou B, El-Sayed MA (1999) J Mol Struct 508:87
Bari MF, Saad B, Rahman IA, Saleh MI (2007) J Alloys Compd 436:187
Acknowledgments
The financial support from the NSFC under Project 51103079 is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, W., Ye, G. & Chen, J. Preparation of Cyanex 272-containing silica composite by sol–gel method for neodymium adsorption. J Radioanal Nucl Chem 295, 1667–1672 (2013). https://doi.org/10.1007/s10967-012-2197-9
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-012-2197-9