Abstract
In this work, Cs+ ion sorption on some clays and zeolite were investigated. 137Cs was used as a tracer. Activities were measured with a NaI crystal gamma counter. The particle size distribution was determined by a laser sizer. Surface area of the particles were determined by BET (Brunauer, Emmett and Teller method). Structure analysis was made by using X-ray diffraction. The chemical compositions of the solid samples were determined using a ICAP-OE spectrometer. Kinetic and thermodynamic parameters were determined. Due to very high uptake results; clay and zeolite can be proposed as a good sorbents in waste management considerations.
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Shahwan T, Sayan S, Erten HN, Black L, Hallam KR, Allen GC (2000) Surface spectroscopic studies of Cs+, Ba2+ sorption on chlorite-illite mixed clay. Radiochim Acta 88:681–686
Missana T, Adell A (2000) On the applicability of DLVO theory to the prediction of clay colloids stability. J Colloid Interface Sci 230:150–156
Xu YF, Sun D, Yao Y (2004) Surface fractal dimension of bentonite and its application to determination of swelling properties. Chaos Solitons Fractals 19(2):347–356
Jeong CH (2001) Mineralogical and hydrochemical effects on adsorption removal of cesium-137 and strontium-90 by kaolinite. J Environ Sci Heal A 36(6):1089–1099
Ebina T, Iwasaki T, Onodera Y, Chatterjee A (1999) A comparative study of DFT and XPS with reference to the adsorption of caesium ions in smectites. Comp Mater Sci 14(1–4):254–260
Plecas I, Pavlovic R, Pavlovic S (2004) Leaching behaviour of 60Co and 137Cs from spent ion exchange resins in cement-bentonite clay matrix. J Nucl Mater 327:171–174
Sakr K, Sayed MS, Hafez MB (2003) Immobilization of radioactive waste in mixture of cement, clay and polymer. J Radioanal Nucl Chem 256(2):179–184
Singh R, Dutta PK (1999) Use of surface-modified zeolite Y for extraction of metal ions from aqueous to organic phase. Micropor Mesopor Mater 32:29–35
Kaya A, Durukan S (2004) Utilization of bentonite-embedded zeolite as clay liner. Appl Clay Sci 25:83–91
Chmielewská-Horvátová E (1998) The interaction mechanisms between aqueous solutions of 137Cs and 134Ba radionuclides and local natural zeolites for an dectivation scenario. J Radioanal Nucl Chem 227(1–2):151–155
Elizondo NV, Ballesteros E, Kharisov BI (2000) Cleaning of liquid radioactive wastes using natural zeolites. Appl Radiat Isot 52:27–30
Tsai S-C, Ouyang S, Hsu C-N (2001) Sortion and diffusion behaviour of Cs and Sr on Jih-Hising bentonite. Appl Radiat Isot 54:209–215
Pavel CC, Popa K, Bilba N, Cecal A, Cozma D, Pui A (2003) The sorption of some radiocations on microporous titanosilicate ETS-10. J Radioanal Nucl Chem 258(2):243–248
Karamanis DT, Aslanoglou XA, Assimakopoulos PA, Gangas NH (1999) Characterization of an aluminum pillared montmorillonite with cation exchange properties. J Radioanal Nucl Chem 242(1):3–9
Lujaniene G, Meleshevych S, Kanibolotskyy V, Sapolaite J, Strelko V, Remeikis V, Oleksienko O, Ribokaite K, Sciglo T (2009) Application of inorganic sorbents for removal of Cs, Sr, Pu and Am from contaminated solutions. J Radioanal Nucl Chem 282:787–791
Ioannides KG, Mertzimekis TJ, Karamanis DT, Stamoulis KC, Kırıkopoulos I (1996) Radiocesium sorption-desorption processse in lake sediments. J Radioanal Nucl Chem 208(2):549–557
Man CK, Chu PY (2004) Experimental and modelling studies of radiocesium retention in soils. J Radioanal Nucl Chem 262(2):339–344
Orechovska J, Rajec P (1999) Sorption of cesium on composite sorbents based on nickel ferrocyanide. J Radioanal Nucl Chem 242(2):387–390
Pathak PN, Chopin GR (2006) Kinetic and thermodynamic studies of cesium(I) sorption of hdrous silica. J Radioanal Nucl Chem 270(2):299–305
Tsai S-C, Wang T-H, Wei Y-Y, Yeh W-C, Jan Y-L, Teng S-P (2008) Kinetics of Cs adsorption/desorption on granite by a pseudo first order reaction model. J Radioanal Nucl Chem 275(3):555–562
Konan KL, Peyratout C, Bonnet J-P, Smith A, Jacquet A, Magnoux P, Ayrault P (2007) Surface properties of kaolin and illite suspensions in concentrated calcium hydroxide medium. J Colloid Interface Sci 307(1):101–108
Salles F, Henry M, Douillard J-M (2006) Determination of the surface energy of kaolinite and serpentine using PACHA formalism—comparison with immersion experiments. J Colloid Interface Sci 303:617–626
Galambos M, Paucova V, Kufcakova J, Rosskopfova O, Rajec P, Adamcova R (2010) Cesium sorption on bentonites and montmorillonite K10. J Radioanal Nucl Chem 284:55–64
Galambos M, Kufcakova J, Rosskopfova O, Rajec P (2010) Adsorption of cesium and strontium on natrified bentonites. J Radioanal Nucl Chem 283:803–813
Galambos M, Kufcakova J, Rajec P (2009) Adsorption of cesium on domestic bentonites. J Radioanal Nucl Chem 281:485–492
Lujaniene G, Motiejunas S, Šapolaite J (2007) Sorption of Cs, Pu and Am on clay minerals. J Radioanal Nucl Chem 274(2):345–353
Rajec P, Domianova K (2008) Cesium exchange reaction on natural and modified clinoptilolite zeolites. J Radioanal Nucl Chem 275(3):503–508
Vokal A, Vopalka D, Vecernık P (2010) An approach for acquiring data for description of diffusion in safety assessment of radioactive waste repositories. J Radioanal Nucl Chem 286(3):751–757
El-Kamash AM, Zaki AA, El Geleel MA (2005) Modelling batch kinetics and thermodynamics of zinc and cadmium ions removal from waste solutions using synthetic zeolite A. J Hazard Mater B127:211–220
El-Kamash AM, El-Gammal B, El-Sayed AA (2007) Preparation and evaluation of cerium(IV) tungstate powder as inorganic exchanger in sorption of cobalt and europium ions from aqueous solutions. J Hazard Mater 141:719–728
Ho YS, Ng JCY, McKay G (2000) Kinetics of pollutant sorption by biosorbents: review. Sep Purif Method 29:189–232
Lin S-H, Juang R-S (2002) Heavy metal removal from water by sorption using surfactant-modified montmorillonite. J Hazard Mater B92:315–326
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Yıldız, B., Erten, H.N. & Kış, M. The sorption behavior of Cs + ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics. J Radioanal Nucl Chem 288, 475–483 (2011). https://doi.org/10.1007/s10967-011-0990-5
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DOI: https://doi.org/10.1007/s10967-011-0990-5