Skip to main content
SpringerLink
Log in

Adsorptivity of silica-supported adsorbents impregnated with polyphosphine polyoxides to U(VI) and some other metal ions in nitric acid media

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

For the selective extraction of radionuclides from nitrate media, the extraction properties of organopolyphosphine polyoxides were examined in the form of impregnated adsorbents. It was found that the extraction property of 1,1,3,5,5-pentaphenyl-1,3,5-triphosphapentane trioxide (PPTPT) for U(VI) is quite unusual with very high values of the distribution ratio in nitric acid solutions of both low and high concentration ranges, which is not observed for other types of extractants. From the extraction properties for other metal ions, this type of extracant may be promising for the selective extraction of U(VI) from HNO3 of very low and high concentrations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Gasparini GM, Grossi G (1986) Solvent Extr Ion Exch 4:1233–1271

    Article  CAS  Google Scholar 

  2. Schulz WW, Horwitz EP (1988) Sep Sci Technol 23:1191–1210

    Article  CAS  Google Scholar 

  3. Turanov AN, Karandashev VK, Baulin VE (1999) Solvent Extr Ion Exch 17:1423–1444

    Article  CAS  Google Scholar 

  4. Madic C et al (2000) New partitioning techniques for minor actinides. Nucl Sci Technol, final report, EUR19149, European Commission, p 44

  5. Tachimori S, Suzuki S, Sasaki Y, Apichaibukol A (2003) Solvent Extr Ion Exch 21:707–715

    Article  CAS  Google Scholar 

  6. Nash KL, Lavallette C, Borkowski M, Paine RT, Gan X (2001) Inorg Chem 41:5849–5858

    Article  Google Scholar 

  7. Turanov AN, Karandashev VK, Baulin VE (2002) Radiochemistry 44:26–34

    Article  CAS  Google Scholar 

  8. Drew MGB, Hill C, Hudson MJ, Iveson PB, Madic C, Youngs TGA (2004) Dalton Trans 244–251

  9. Horton CA, White JC (1958) Anal Chem 30:1779–1784

    Article  CAS  Google Scholar 

  10. Heyn AHA, Soman YDJ (1964) Inorg Nucl Chem 26:287–295

    Article  CAS  Google Scholar 

  11. Burcik I, Mikulaj VJ (1991) J Radioanal Nucl Chem 150:247–253

    Article  CAS  Google Scholar 

  12. Kulkarni PS (2003) Chem Eng J 92:209–214

    Article  CAS  Google Scholar 

  13. Smirnov IV (2007) Radiochemistry 49:44–54

    Article  CAS  Google Scholar 

  14. Turanov AN, Karandashev VK, Bondarenko NA (2007) Radiochemistry 49:55–63

    Article  CAS  Google Scholar 

  15. Turanov AN, Karandashev VK, Yatkevich AN, Safronova ZV, Rodygina NI, Fedoseev AM (2007) Radiochemistry 49:618–623

    Article  CAS  Google Scholar 

  16. Cristau HJ, Virieux D, Dozol JF, Rouquette H (1999) J Radioanal Nucl Chem 241:543–547

    Article  CAS  Google Scholar 

  17. Nogami M, Ishihara T, Suzuki K, Ikeda Y (2007) J Radioanal Nucl Chem 273:37–41

    Article  CAS  Google Scholar 

  18. Egawa H, Nonaka T, Ikari M (1984) J Appl Polym Sci 29:2045–2055

    Article  CAS  Google Scholar 

  19. Chiarizia R, Horwitz EP, D’Arcy KA, Alexandratos SD, Trochimczuk AW (1996) R Soc Chem 182:321–328

    CAS  Google Scholar 

Download references

Acknowledgment

The authors would like to thank Mr. K. Maruyama for his technical advice and support.

Author information

Authors and Affiliations

  1. Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1-N1-34 O-okayama, Meguro-ku, Tokyo, 152-8550, Japan

    Masanobu Nogami, Yuichi Sugiyama & Yasuhisa Ikeda

Authors
  1. Masanobu Nogami
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuichi Sugiyama
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yasuhisa Ikeda
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masanobu Nogami.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nogami, M., Sugiyama, Y. & Ikeda, Y. Adsorptivity of silica-supported adsorbents impregnated with polyphosphine polyoxides to U(VI) and some other metal ions in nitric acid media. J Radioanal Nucl Chem 284, 195–199 (2010). https://doi.org/10.1007/s10967-010-0465-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-010-0465-0

Keywords

Search

Navigation