Skip to main content
SpringerLink
Log in

Preconcentration and determination of osmium(VIII) using silicas chemically modified with sulfur-containing groups

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

The adsorption of osmium(VIII) from sulfuric and hydrochloric acid solutions and gas phase on silicas chemically modified by dithiocarbamate, thiodiazolthiol, mercaptophenylpropylurea, and aminobenzothiazolpropyl groups is studied. A procedure is developed for the adsorption-photometric determination of osmium, including the adsorption of osmium(VIII) from the gas phase on silicas chemically modified by sulfur-containing groups and the determination of osmium in the adsorbent phase by diffuse reflection spectroscopy. The procedure was used to determine osmium in a certified reference material of the composition of a matte ore thermal melting and process waters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chmilenko, F.A. and Khudyakova, S.N., J. Anal. Chem., 2008, vol. 63, no. 5, p. 439.

    Article  CAS  Google Scholar 

  2. Balcerzak, M., Analyst, 1988, vol. 113, no. 1, p. 129.

    Article  CAS  Google Scholar 

  3. Akhond, M., Safavi, A., and Massoumi, A., Anal. Lett., 1987, vol. 20, no. 1, p. 29.

    Article  CAS  Google Scholar 

  4. Božkov, O., Čermakova, L., and Malat, M., Anal. Lett., 1979, vol. 12, no. 12, p. 1259.

    Article  Google Scholar 

  5. Zolotov, Yu.A., Bodnya, V.A., Zagruzina, A.N., and Freiser, H., CRC Crit. Rev. Anal. Chem., 1982, vol. 14, no. 2, p. 93.

    Article  CAS  Google Scholar 

  6. Bukhbinder, G.L., Korda, T.M., Demidova, M.G., Gus’kova, E.A., and Torgov, V.G., J. Anal. Chem., 2009, vol. 64, no. 6, p. 593.

    Article  CAS  Google Scholar 

  7. Mokhodoeva, O.B., Myasoedova, G.V., and Kubrakova, I.V., J. Anal. Chem., 2007, vol. 62, no. 7, p. 607.

    Article  CAS  Google Scholar 

  8. Analiticheskaya khimiya metallov platinovoi gruppy (Analytical Chemistry of Platinum Group Metals), Zolotov, Yu.A., Varshal, G.M., and Ivanov, V.M., Eds., Moscow: Editorial URSS, 2003.

    Google Scholar 

  9. Beamish, F.E., The Analytical Chemistry of the Noble Metals, New York: Pergamon, 1966.

    Google Scholar 

  10. Švorc, L., Tomčik, P., Durdiak, J., Rievaj, M., and Bustin, D., Pol. J. Environ. Stud., 2012, vol. 21, no. 1, p. 7.

    Google Scholar 

  11. Losev, V.N., Bakhtina, M.P., Bakhvalova, I.P., Trofimchuk, A.K., and Runov, V.K., J. Anal. Chem., 1998, vol. 53, no. 11, p. 1014.

    CAS  Google Scholar 

  12. Losev, V.N., Bakhvalova, I.P., Kudrina, Yu.V., and Trofimchuk, A.K., J. Anal. Chem., 2004, vol. 59, no. 8, p. 708.

    Article  CAS  Google Scholar 

  13. McGarvey, B.R., Coord. Chem. Rev., 1998, vol. 170, no. 1, p. 75.

    Article  CAS  Google Scholar 

  14. Komozin, P.N., Berngard, E.A., Belyaeva, V.K., and Marov, I.N., Zh. Neorg. Khim., 1995, vol. 40, no. 3, p. 496.

    Google Scholar 

  15. Losev, V.N., Bakhtina, M.P., Bakhvalova, I.P., Trofimchuk, A.K., and Runov, V.K., J. Anal. Chem., 2001, vol. 56, no. 4, p. 341.

    Article  CAS  Google Scholar 

  16. Losev, V.N., Kudrina, Yu.V., Trofimchuk, A.K., and Komozin, P.N., J. Anal. Chem., 2004, vol. 59, no. 6, p. 546

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kristall Research and Engineering Center, Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk, 660041, Russia

    V. N. Losev, V. V. Parfenova & E. V. Elsuf’ev

  2. Faculty of Chemistry, Taras Shevchenko National University, Kyiv, Vladimirskaya ul. 64, Kyiv, 01033, Ukraine

    A. K. Trofimchuk

Authors
  1. V. N. Losev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Parfenova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Elsuf’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. K. Trofimchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Losev.

Additional information

Original Russian Text © V.N. Losev, V.V. Parfenova, E.V. Elsuf’ev, A.K. Trofimchuk, 2015, published in Zhurnal Analiticheskoi Khimii, 2015, Vol. 70, No. 7, pp. 686–692.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Losev, V.N., Parfenova, V.V., Elsuf’ev, E.V. et al. Preconcentration and determination of osmium(VIII) using silicas chemically modified with sulfur-containing groups. J Anal Chem 70, 781–787 (2015). https://doi.org/10.1134/S1061934815070072

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934815070072

Keywords

Search

Navigation