Skip to main content
Log in

Features of forming the structure and properties of polyamide-6 via in situ polymerization with oxidized graphite

  • ORIGINAL PAPER
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

The paper presents the results of the study on the application of the method of polymerization combination of components. The possibility of the addition of oxidized graphite obtained by various oxidation methods into polyamide-6 at the stage of cationic polymerization of caprolactam has been studied. Its thermal expansion has been confirmed under the conditions of polymer synthesis. The effect of oxidized graphite on the formation of the structure of the modified polyamide has been shown. The improvement of the functional properties of polyamide-6 containing oxidized graphite has been proven: the volumetric electrical resistance decreases by more than 3 times, the coefficient of friction decreases by 40%, the coefficient of thermal conductivity increases by 35%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Chen XT, Liu HJ, Zxeng XY (2016) Crystallization and mechanical properties of multi-walled carbon nanotubes modified polyamide 6. Mater Sci Environ Eng 651:321–324

    Article  Google Scholar 

  2. Mahmood N, Islam M, Hameed A, Saeed S (2013) Polyamide 6/multiwalled carbon nanotubes Nanocomposites with modified morphology and thermal properties. Polymers 5:1380–1391

    Article  Google Scholar 

  3. Jogia BF, Sawanta M, Brahmankara PK, Ratnab D, Tarhekar MC (2014) Study of mechanical and crystalline behavior of polyamide 6 / Hytrel / carbon nanotubes (CNT) based polymer composites. Procedia Mater Sci 6:805–811

    Article  Google Scholar 

  4. Dencheva N, Gaspar H, Filonovich S, Lavrova O, Busani T, Bernardo G, Denchev Z (2014) Fullerene-modified polyamide 6 by in situ anionic polymerization in the presence of PCBM. J Mater Sci 49:4751–4764

    Article  CAS  Google Scholar 

  5. Gao Y, Müller-Plathe F (2016) Increasing the thermal conductivity of Graphene-Polyamide-6,6 Nanocomposites by surface-grafted polymer chains: calculation with molecular dynamics and effective-medium approximation. J Phys Chem B 120(7):1336–1346

    Article  CAS  Google Scholar 

  6. Ding P, Shengfu S, Yimin T, Shi L (2014) Highly thermal conductive composites with polyamide-6 covalently-grafted graphene by an in situ polymerization and thermal reduction process. Carbon 66:576–584

    Article  CAS  Google Scholar 

  7. Wu X-F, Zhao Y-K, Li H, Zhao Z-H, Yang S, Zhang H, Yu M-T, Jia F-F (2015) Polyamide 6/modified carbon black Nanocomposites prepared via in situ polymerization. J Macromol Sci Phys 54:469–480

  8. Meng F, Huang F, Guo Y, Chen J, Chen X, Hui D, He P, Zhou X, Zhou Z (2017) In situ intercalation polymerization approach to polyamide-6/graphite nanoflakes for enhanced thermal conductivity. Compos Part B 117:165–173

    Article  CAS  Google Scholar 

  9. Zhou S, Yang C, Zou H, Liang M (2013) Thermally conductive composites obtained by flake graphite filling immiscible polyamide 6 / polycarbonate blends. Thermochim Acta 566:84–91

    Article  CAS  Google Scholar 

  10. Markov VA, Saki TA, Markov AV (2016) Effect of relaxation processes during deformation on electrical resistivity of polyethylene composites filled with carbon black. J Polym Res 23:191

    Article  Google Scholar 

  11. Shornikova ON, Kogan EV, Sorokina NE, Avdeev VV (2009) The specific surface area and porous structure of graphite materials. Russ J Phys Chem 83(6):1022–1025

    Article  CAS  Google Scholar 

  12. Leonov DV, Levkina NL, Ustinova TP (2015) Choice of the composition and complex evaluation of the properties of polycaprolactam modified with oxidized graphite. Russ J Appl Chem 88(6):1052–1056

    Article  CAS  Google Scholar 

  13. Leonov DV, Ustinova TP, Levkina NL (2018) A complex assessment of the properties of Polyamide-6 modified with industrial grades of oxidised graphite. Int Polym Sci Technol 45(45):217–220

    Article  Google Scholar 

  14. Dixon D, Lemonine P, Hamilton J, Lubarsky G, Archer E (2015) Graphene oxide–polyamide 6 nanocomposites produced via in situ polymerization. J Thermoplast Compos Mater 28(3):372–389

    Article  CAS  Google Scholar 

  15. Yang X, Yang W, Fan J, Wu J, Zhang K (2019) Effects of molding on property of thermally conductive and electrically insulating polyamide 6–based composite. J Thermoplast Compos Mater 32(9):1190–1203

    Article  CAS  Google Scholar 

  16. Kaynak C, Sankal S (2015) Effects of oxidative functionalization and aminosilanization of carbon nanotubes on the mechanical and thermal properties of polyamide 6 nanocomposites. J Thermoplast Compos Mater 28(9):1321–1333

    Article  CAS  Google Scholar 

  17. Mostovoy AS, Yakovlev AV (2019) Reinforcement of epoxy composites with graphite-Graphene structures. Sci Rep 9:16246

    Article  CAS  Google Scholar 

  18. Tseluikin VN, Vasilenko EA (2011) Electrodeposition and properties of composite coatings based on nickel. Russ J Appl Chem 84(11):2005–2007

    Article  CAS  Google Scholar 

  19. Mostovoy AS, Yakovlev AV, Lopukhova MI (2020) Directional control of physico-chemical and mechanical properties of epoxide composites by the addition of graphite-graphene structures. Polym-Plast Technol Mater 59(8):874–883

    Article  CAS  Google Scholar 

Download references

Funding

The reported study was funded by RFBR according to the research project № 20-33-70002.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anton Mostovoy.

Ethics declarations

Conflict of interest

The authors declare no conflict of financial and non-financial interest requiring disclosure in this article.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Leonov, D., Ustinova, T., Levkina, N. et al. Features of forming the structure and properties of polyamide-6 via in situ polymerization with oxidized graphite. J Polym Res 27, 273 (2020). https://doi.org/10.1007/s10965-020-02248-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-020-02248-5

Keywords

Navigation