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Effect of single-walled carbon nanotubes with imide cycles on the synthesis and properties of polycaproamide

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Abstract

The anionic polymerization of ε-caprolactam in the presence of single-walled carbon nanotubes with grafted acyllactam groups or polyimide macromolecules is performed. It is shown that the polymerization of ε-caprolactam slows down with an increase in the filler concentration. The introduction of 0.01 wt % nanotubes with polyimide fragments into polycaproamide leads to a 25% increase in the compressive modulus. In this case, the Izod impact strength is 10 kJ/m2, that is, 150% higher than that for an unfilled polycaproamide or polycaproamide containing other types of nanotubes.

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Authors and Affiliations

  1. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    O. N. Zabegaeva, D. A. Sapozhnikov, V. A. Kotel’nikov, B. A. Baiminov & Ya. S. Vygodskii

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    A. V. Krestinin

Authors
  1. O. N. Zabegaeva
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  2. D. A. Sapozhnikov
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  3. A. V. Krestinin
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  4. V. A. Kotel’nikov
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  5. B. A. Baiminov
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  6. Ya. S. Vygodskii
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Correspondence to O. N. Zabegaeva.

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Original Russian Text © O.N. Zabegaeva, D.A. Sapozhnikov, A.V. Krestinin, V.A. Kotel’nikov, B.A. Baiminov, Ya.S. Vygodskii, 2016, published in Vysokomolekulyarnye Soedineniya. Ser. B, 2016, Vol. 58, No. 1, pp. 53–60.

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Zabegaeva, O.N., Sapozhnikov, D.A., Krestinin, A.V. et al. Effect of single-walled carbon nanotubes with imide cycles on the synthesis and properties of polycaproamide. Polym. Sci. Ser. B 58, 54–60 (2016). https://doi.org/10.1134/S1560090416010085

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  • DOI: https://doi.org/10.1134/S1560090416010085

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