Abstract
Polymer based energy storage devices have luminous advantages in comparison with currently employed supercapacitors due to the environmental friendliness, cost and versatility. In general conjugated polymers are more conductive than the inorganic battery materials and have greater power capability. In this report the electron-rich conjugated polymers, containing thiophene as the core named polyazomethines ware synthesized. It contains thiophene electron-donating unit and electron withdrawing unit in which quinoxaline integrated in benzene ring. The influence of the π-linkers of the polyazomethines materials on thermal properties, and electrochemical energy storage performance was investigated. Their outstanding electrochemical performance can be attributed to their conductive frameworks, plentiful redox-active units, and homogeneous porous structure. The electrochemical properties of the polyazomethines electrode are examined with cyclic voltammetry and electrochemical impedance spectroscopy. In addition, various electrolyte solutions are studied to investigate the capacitive behavior of polyazomethines. According to the differing electrolyte types, the maximum specific capacitance of PAM-3 electrode is obtained in 1 M NaOH as 253.40 F/g.
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Biswas S, Drzal L (2010). Chem Mater 22:5667–5671
David A, Dorian G, Gérard B, Pascal G, Maxime B, Deepak D, Pedro G, Jan W, Schubert TJ, Said S (2015). J Mater Chem A 3:13978–13985
Urewicz K, Elpeux S, Bertagna V, Béguin F, Frackowiak E (2001). Chem Phys Lett 347:36–40
Hughes M, Chen GZ, Shaffer MS, Fray DJ, Windle AH (2002). Chem Mater 14:1610–1613
Kima B, Kwon J, Ko J, Park J, Too C, Wallace G (2010). Synth Met 160:94–98
Xu Y, Jin S, Xu H, Nagai A, Jiang D (2013). Chem Soc Rev 42:8012–8031
Jianchang W, Liu C, Deng X, Zhang L, Manman H, Tang J, Tan W, Tian Y, Xu B (2017). RSC Adv 7:45478–45483
Kaneto K, Maxfield MR, Nairns DP, MacDiarmid AG, Heeger AJ (1982). J Chem Soc Faraday Trans 78:3417–3429
Trinidad F, Alonso-Lopez J, Nebot M (1987). J Appl Electrochem 17:215–218
Elizabeth WP, Antonio JR, Mark SW (1985). J Phys Chem 89:1441–1447
Conway BE (1999) Electrochemical Supercapacitors: scientific fundamentals and technological applications. KluwerAcademia/Plenum Publishers, New York
Pacheco-Catalan DE, Smit MA, Morales E (2011). Int J Electrochem Sci 6:78–90
Kotz K, Carlen M (2000). Electrochim Acta 45:2483–2486
Ingole SM, Navale ST, Navale YH, Dhole IA, Mane RS, Stadler FJ, Patil VB (2017). J Solid State Electrochem 21:1817–1826
Pandolfo AG, Hollenkamp AF (2006). J Power Sources 157:11–27
Wang Y, Shi Z, Yi H, Ma Y, Wang C, Chen MCY (2009). J Phys Chem C 113:13103–13107
Lu X, Zhang W, Wang C, Wen TC, Wei Y (2011). Prog Polym Sci 36:671–712
Naoi K, Morita M (2008). Electrochem Soc Interface 17:44–48
Arbizzani CM, Mastragostino et al (2001). J Power Sources 100:164–170
Arbizzani CM, Mastragostino et al (1996). Electrochim Acta 41:21–26
Mastragostino M, Arbizzani C et al (2001). J Power Sources 97-98:812–815
Frackowiak, E., V. Khomenko, et al., (2005) J Power Sources In Press. Corrected Proof
Kou Y, Xu Y, Guo Z, Jiang D (2000). Angew Chem Int Ed Engl 50:8753–8757
Xu F, Chen X, Tang Z, Wu D, Fu R, Jiang D (2014). Chem Commun 50:4788–4790
Sakaushi K, Hosono E, Nickerl G, Zhou H, Kaskel S, Eckert J (2014). J Power Sources 245:553–556
Sakaushi K, Hosono E, Nickerl G, Gemming T, Zhou H, Kaskel S, Eckert J (2013). Nat Commun 4:1485
Imai Y, Maldar NN, Kakimoto M (1985). J Polym Sci Polym Chem 23:1797–1803
Lai C-T, Chien R-H, Liu C-W, Hong J-L (2011). J Polym Sci Part A: Polym Chem 49:2059–2069
Hergenrother PM (1969). J Polym Sci Part A: Polym Chem 7:945–957
Ghaemy M, Porazizollahy R, Bazzar M (2011). Macromol Res 19:528–536
Chauhan ACP (2014). J Anal Bioanal Tech https://doi.org/10.4172/2155-9872.1000212
Petrus ML, Bouwer RKM, Lafont U, Murthy DHK, Kist RJP, Bohm ML, Olivier Y, Savenije TJ, Siebbeles LDA, Greenhamd NC, Dingmans TJ (2013). Polym Chem 4:4182–4191
Mastrorilli P, Dell’Anna MM, Rizzuti A, Mali M, Zapparoli M, Leonelli C (2015). Molecules 20:18661–18684
Navale YH, Navale ST, Chougule MA, Ingole SM, Stadler FJ, Mane RS, Naushad M, Patil VB (2017). J Colloid Interface Sci 487:458–464
Navale ST, Mali VV, Pawar SA, Mane RS, Naushad M, Stadler FJ, Patil VB (2015). RSC Adv 5:51961–51965
Sing KSW, Evertt DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985). Pure & Appl Chem 57:603–619
Yu H, Tian M, Shen C, Wang Z (2013). Polym Chem 4:961
Kotz R, Carlen M (1999). Electrochim Acta 45:2483–2498
Dhole IA, Navale ST, Navale YH, Jadhav YM, Pawar CS, Suryavanshi SS, Patil VB (2017). J Mater Sci Mater Electron 28:10819–10829
Aleksic MM, Pantic J, Kapetanovic VP (2014). Facta Universitatis, Series Physics, Chemistry and Technology 12:55–63
Aleksic MM, Radulovic V, Lijeskic N, Kapetanovic V (2012). Curr Anal Chem 8:133–142
Aleksic MM, Radulovic V, Kapetanovic V, Agbaba D (2013). Electrochim Acta 106:75–81
Wang P, Qiong W, Han L, Wang S, Fang S, Zhang Z, Sun S (2015). RSC Adv 5:27290
Perepichka IF, Perepichka DF, Meng H, Wudl F (2005). Adv Mater 17:2281–2305
Andy R, John D, Ian R, Shimshon G, John PF (1994). J Power Sources 47:89–107
Dubal DP, Patil SV, Jagadale AD, Lokhande CD (2011). J Alloys Compd 509:8183–8188
Sezai Sarac A, Ates M, Kilic B (2008). Int J Electrochem Sci 3:777–786
Ates M, Sezai Sarac A (2009). Prog Org Coat 65:281–287
Sarac AS, Sezgin S, Ates M, Turhan CM, Parlak EA, Irfanoglu B (2008). Prog Org Coat 62:331
Lang G, Bacskai J, Inzelt G (1991). Electrochim Acta 38:773
Bonazzola C, Calvo EJ (1996). J Electroanal Chem 405:59
Acknowledgements
The author AAG thanks to University Grant Commission, New Delhi for financial assistance in the form of major research project: UGC-MAJOR-MRP-CHEM-2013-39804.
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Salunkhe, P.H., Patil, Y.S., Patil, V.B. et al. Synthesis and characterization of conjugated porous polyazomethines with excellent electrochemical energy storage performance. J Polym Res 25, 147 (2018). https://doi.org/10.1007/s10965-018-1545-z
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DOI: https://doi.org/10.1007/s10965-018-1545-z