Abstract
High density polyethylene (HDPE)/clay nanocomposites containing nanoclay concentrations of 1, 2.5, and 5 wt% were prepared by a melt blending process. The effects of various types of nanoclays and their concentrations on permeability, solubility, and diffusivity of natural gas in the nanocomposites were investigated. The results were compared with HDPE typically used in the production of liners for the petroleum industry. Four different nanoclays—Cloisite 10A, 15A, 30B and Nanomer 1.44P—were studied in the presence of CH4 and a CO2/CH4 mixture in the temperature range 30–70 °C and pressure range 50–100 bar. The permeability and diffusivity of the gases were considerably reduced by the incorporation of nanoclay into the polymer matrix. Addition of 5 wt% loading of Nanomer 1.44P reduced the permeability by 46% and the diffusion coefficient by 43%. Increasing the pressure from 50 to 100 bar at constant temperature had little influence on the permeability, whereas increasing the temperature from 30 to 70 °C significantly increased the permeability of the gas. Additionally, the effect of crystallinity on permeability, solubility, and diffusivity was investigated. Thus, the permeability of the CO2/CH4 mixture in Nanomer 1.44P nanocomposite was reduced by 47% and diffusion coefficient by 35% at 5 wt% loading, 50 °C, and 100 bar, compared with pure HDPE.
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References
Paul DR, Robeson LM (2008) Polymer 49:3187–3204
Xiao J, Hu Y, Kong Q, Song L, Wang Z, Chen Z, Fan W (2005) Polym Bull 54:271–278
Ahmadi SJ, Hunang YD, Li W (2004) J Mater Sci 39:1919–1925
Nwabunma D (2008) In: Nwabunma D, Kyu T (eds) Polyolefin composite. Wiley-Interscience, New Jersey
Hu Y, Lu H, Song L (2008) In: Nwabunma D, Kyu T (eds) Polyolefin composite. Wiley-Interscience, New Jersey
Deka BK, Maji TK, Mandal M (2011) Study on properties of nanocomposites based on HDPE, LDPE, PP, PVC and clay. Polym Bull. doi:10.1007/s00289-011-0529-5
Scharlach K, Walter K (2007) J Zhejiang Univ Sci A 8:987–990
Lomakin SM, Dubnikova IL, Shchegolikhin AN, Zaikov GE, Kozlowski R, Kim GM, Michler GH (2008) J Therm Anal Calorim 94:719–726
Adewole JK, Al-Mubaiyedh UA, Ul-Hamid A, Al-Juhani AA, Hussein IA (2011) Can J Chem Eng 9999:1–13
Deepthi MV, Sharma M, Sailaja R, Anantha P, Sampathkumaran P, Seetharamu S (2010) Mater Des 31:2051–2060
Gopakumar T, Lee J, Kontopoulou M, Parent J (2002) Polym 43:5483–5491
Zhai H, Xu W, Guo H, Zhou Z, Shen S, Song Q (2004) Eur Polym J 40:2539–2545
Zhang J, Wilkie CA (2003) Polym Degrad Stab 80:163–169
Zhao C, Qin H, Gong F, Feng M, Zhang S, Yang M (2005) Polym Degrad Stab 87:183–189
Chuang TH, Guo W, Cheng KC, Chen SW, Wang HT, Yen YY (2004) J Polym Res 11:169–174
Flaconnèche B, Martin J, Klopffer MH (2001) Oil Gas Sci Technol 56:261–278
Picard E, Vermogen A, Gerard J, Espuche E (2008) J Polym Sci B Polym Phys 46:2593–2604
Jacquelot E, Espuche E, Gerard JF, Duchet J, Mazabraud P (2006) J Polym Sci B Polym Phys 44:431–440
Naito Y, Mizoguchi K, Terada K, Kamiya Y (1991) J Polym Sci B Polym Phys 29:457–462
Hotta S, Paul DR (2004) Polymer 45:7639–7654
Raharjo RD, Freeman BD, Paul DR, Sarti GC, Sanders ES (2007) J Membr Sci 306:75–92
Klopffer M, Flaconnèche B (2001) Oil Gas Sci Technol Rev IFP 56:223–244
Lin H, Freeman B (2004) J Membr Sci 239:105–117
Safari M, Ghanizadeh A, Montazer-Rahmati MM (2009) Int J Greenh Gas Control 3:3–10
Stern SA, Krishnakumar B, Nadakatti SM (1996) In: Mark JE (ed) Physical properties of polymers handbook. AIP, Woodbury
Alamo RG, Mandelkern L (2009) In: Mark JE (ed) Polymer data handbook. Oxford University Press, Oxford
Flaconnèche B, Martin J, Klopffer M (2001) Oil Gas Sci Technol Rev IFP 56:245–259
Koros WJ, Madden CW (2003) Transport Properties. In: Mark HF (ed) Encyclopedia of polymer science and technology. Wiley-Interscience, New Jersey
Ghadimi A, Sadrzadeh M, Shahidi K, Mohammadi T (2009) J Membr Sci 344:225–236
Merkel CT, He Z, Pinnau I, Freeman BD, Meakin P, Hill JA (2003) Macromol 36:6844–6855
Matteucci S, Raharjo RD, Kusuma VA, Swinnea S, Freeman BD (2008) Macromol 41:2144–2156
Lee H, Jung D, Hong C, Rhee KY, Advani SG (2005) Compos Sci Technol 65:1996–2002
Jordan SM, Koros WJ (1990) J Polym Sci B Polym Phys 28:795–809
Zeng Q, Yu A (2010) In: Vittal M (ed) Optimization of polymer nanocomposite properties. Wiley-VCH, Weinheim
Hussein IA (1999) Molecular order, miscibility and rheology of molten polyethylenes. PhD Thesis, University of Alberta
Welty JR, Wicks CE, Wilson RE, Rorrer G (2008) Fundamentals of momentum, heat and mass transfer, 5th edn. Wiley, New Jersey
Mogri Z, Paul DR (2004) Polym 42:7781–7789
Dhingra SS, Marand E (1998) J Membr Sci 141:45–63
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Adewole, J.K., Jensen, L., Al-Mubaiyedh, U.A. et al. Transport properties of natural gas through polyethylene nanocomposites at high temperature and pressure. J Polym Res 19, 9814 (2012). https://doi.org/10.1007/s10965-011-9814-0
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DOI: https://doi.org/10.1007/s10965-011-9814-0