Skip to main content
Log in

Novel epoxidized natural rubber toughened polyamide 6/halloysite nanotubes nanocomposites

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

A novel ternary epoxidized natural rubber (ENR-50) toughened polyamide 6/halloysite nanotubes (PA6/HNTs) nanocomposites were successfully prepared by extrusion followed by injection molding. The HNTs revealed a favourable interaction with the PA6 matrix as seen by the improvement in mechanical properties and presence of a new FTIR vibrational peak. The ENR-50 showed an improvement of the impact strength up to 300% with a super tough characteristic at only 15 wt% ENR-50. The naturally occurring nanotubes proved to be a suitable candidate to replace other synthetic nanotubes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17

Similar content being viewed by others

References

  1. Carothers WH, Hill JW (1932) J Am Chem Soc 54:1579–1587

    Article  CAS  Google Scholar 

  2. Wu SH, Wang FY, Ma CCM, Chang WC, Kuo CT, Kuan HC, Chen WJ (2001) Mat Lett 49:327–333

    Article  CAS  Google Scholar 

  3. Ramkumar A, Gnanamoorthy R (2008) Comp Sci Technol 68:3401–3405

    Article  CAS  Google Scholar 

  4. Guo BC, Zou Q, Lei Y, Du ML, Liu MX, Jia D (2009) Thermochimica Acta 484:48–56

    Article  CAS  Google Scholar 

  5. Sirong Y, Zhen YZ, Wing MY (2007) Trib Inter 40:855–862

    Article  Google Scholar 

  6. San J, Wang Z, Li S, Liu J (2006) Surf Coat Technol 200:5245–5252

    Article  CAS  Google Scholar 

  7. Gowariker VR, Viswanathan NV, Sreedhar J (1999) Polym science. New Age, India

    Google Scholar 

  8. Joussein E, Petit S, Churchman GJ, Theng BKG, Righi D, Delvaux B (2005) Clay Min 40:383–426

    Article  CAS  Google Scholar 

  9. Du ML, Guo BC, Wan JJ, Zou QL, Jia DM (2010) J Polym Res 17:109–118

    Article  CAS  Google Scholar 

  10. Ye YP, Chen HB, Wu JS, Ye L (2007) Polym 48:6426–6433

    Article  CAS  Google Scholar 

  11. Guo BC, Lei Y, Chen F, Liu XL, Du ML, Jia D (2008) App Surf Sci 255:2715–2722

    Article  CAS  Google Scholar 

  12. Du ML, Guo BC, Lei Y, Liu XL, Jia D (2008) Polym 49:4871–4876

    Article  CAS  Google Scholar 

  13. Fornes TD, Yoon PJ, Hunter DL, Keskkula H (2002) Polym 43:5915–5933

    Article  CAS  Google Scholar 

  14. Deng S, Zhang J, Ye L (2009) Comp Sci Technol 69:2497–2505

    Article  CAS  Google Scholar 

  15. Rao Y, Pochan JM (2007) Macromol 40:290–296

    Article  CAS  Google Scholar 

  16. Ishak ZAM, Bakar AA (1995) Euro Polym J 31:259–269

    Article  CAS  Google Scholar 

  17. Hong SG, Chan CK, Chuang CC, Keong CW, Hsueh YP (2005) J Polym Res 12:295–303

    Article  CAS  Google Scholar 

  18. Mohamad Z, Ismail H, Thevy RC (2006) J App Polym Sci 99:1504–1515

    Article  CAS  Google Scholar 

  19. Huang JJ, Keskkula H, Paul DR (2004) Polym 45:4203–4215

    Article  CAS  Google Scholar 

  20. Wang XH, Zhang HX, Jiang ZG, Liu CH, Liang HJ, Jiang BZ (1998) Polym 39:2697–2701

    Article  CAS  Google Scholar 

  21. Jha A, Bhowmick AK (1998) Polym Degrad Stab 62:575–586

    Article  CAS  Google Scholar 

  22. Ahn YC, Paul DR (2006) Polym 47:2830–2838

    Article  CAS  Google Scholar 

  23. Guo BC, Lei Y, Chen F, Liu XL, Du ML, Jia D (2008) App Surf Sci 255:2715–2722

    Article  CAS  Google Scholar 

  24. Bao SP, Tjong SC (2007) Comp: Part A 38:378–338

    Article  Google Scholar 

  25. Chiu FC, Lai SM, Chen YL, Lee TH (2005) Polym 46:11600–11609

    Article  CAS  Google Scholar 

  26. Chow WS, Bakar AA, Ishak ZAM, Karger-Kocsis J, Ishiaku US (2005) Euro Polym J 41:687–696

    Article  CAS  Google Scholar 

  27. Dasari A, Yu ZZ, Mai YW (2005) Polym 46:5986–5991

    Article  CAS  Google Scholar 

  28. Dong WF, Zhang XH, Liu YQ, Gui H, Wang QG, Gao JM, Song ZH, Lai JM, Huang F, Qiao JL (2006) Euro Polym J 42:2515–2522

    Article  CAS  Google Scholar 

  29. González I, Eguiazábal JI, Nazábal J (2006) Comp Sci Technol 66:1833–1843

    Article  Google Scholar 

  30. Kelnar I, Khunová V, Kotek J, Kaprálková L (2007) Polym 48:5332–5339

    Article  CAS  Google Scholar 

  31. Kelnar I, Rotrekl J, Kotek J, Kaprálková L, Hromádková J (2009) Euro Polym J 45:2760–2766

    Article  CAS  Google Scholar 

  32. Lai SM, Li HC, Liao YC (2007) Euro Polym J 43:1660–1671

    Article  CAS  Google Scholar 

  33. Shelley JS, Mather PT, DeVries KL, Mauger M (2001) Polym 42:5849–5858

    Article  CAS  Google Scholar 

  34. Kusmono, Ishak ZAM, Chow WS, Takeichi T, Rochmadi N (2008) Euro Polym J 44:1023–1039

    Article  CAS  Google Scholar 

  35. Tanrattakul V, Sungthong N, Raksa P (2008) Polym Test 27:794–800

    Article  Google Scholar 

Download references

Acknowledgement

Research E-Science Grant, (No. 03-01-06-SF0671), by Ministry of Science, Technology and Innovation (MOSTI), Malaysia is gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zurina Mohamad.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharif, N.F.A., Mohamad, Z., Hassan, A. et al. Novel epoxidized natural rubber toughened polyamide 6/halloysite nanotubes nanocomposites. J Polym Res 19, 9749 (2012). https://doi.org/10.1007/s10965-011-9749-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-011-9749-5

Keywords

Navigation