Abstract
A novel ternary epoxidized natural rubber (ENR-50) toughened polyamide 6/halloysite nanotubes (PA6/HNTs) nanocomposites were successfully prepared by extrusion followed by injection molding. The HNTs revealed a favourable interaction with the PA6 matrix as seen by the improvement in mechanical properties and presence of a new FTIR vibrational peak. The ENR-50 showed an improvement of the impact strength up to 300% with a super tough characteristic at only 15 wt% ENR-50. The naturally occurring nanotubes proved to be a suitable candidate to replace other synthetic nanotubes.
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Carothers WH, Hill JW (1932) J Am Chem Soc 54:1579–1587
Wu SH, Wang FY, Ma CCM, Chang WC, Kuo CT, Kuan HC, Chen WJ (2001) Mat Lett 49:327–333
Ramkumar A, Gnanamoorthy R (2008) Comp Sci Technol 68:3401–3405
Guo BC, Zou Q, Lei Y, Du ML, Liu MX, Jia D (2009) Thermochimica Acta 484:48–56
Sirong Y, Zhen YZ, Wing MY (2007) Trib Inter 40:855–862
San J, Wang Z, Li S, Liu J (2006) Surf Coat Technol 200:5245–5252
Gowariker VR, Viswanathan NV, Sreedhar J (1999) Polym science. New Age, India
Joussein E, Petit S, Churchman GJ, Theng BKG, Righi D, Delvaux B (2005) Clay Min 40:383–426
Du ML, Guo BC, Wan JJ, Zou QL, Jia DM (2010) J Polym Res 17:109–118
Ye YP, Chen HB, Wu JS, Ye L (2007) Polym 48:6426–6433
Guo BC, Lei Y, Chen F, Liu XL, Du ML, Jia D (2008) App Surf Sci 255:2715–2722
Du ML, Guo BC, Lei Y, Liu XL, Jia D (2008) Polym 49:4871–4876
Fornes TD, Yoon PJ, Hunter DL, Keskkula H (2002) Polym 43:5915–5933
Deng S, Zhang J, Ye L (2009) Comp Sci Technol 69:2497–2505
Rao Y, Pochan JM (2007) Macromol 40:290–296
Ishak ZAM, Bakar AA (1995) Euro Polym J 31:259–269
Hong SG, Chan CK, Chuang CC, Keong CW, Hsueh YP (2005) J Polym Res 12:295–303
Mohamad Z, Ismail H, Thevy RC (2006) J App Polym Sci 99:1504–1515
Huang JJ, Keskkula H, Paul DR (2004) Polym 45:4203–4215
Wang XH, Zhang HX, Jiang ZG, Liu CH, Liang HJ, Jiang BZ (1998) Polym 39:2697–2701
Jha A, Bhowmick AK (1998) Polym Degrad Stab 62:575–586
Ahn YC, Paul DR (2006) Polym 47:2830–2838
Guo BC, Lei Y, Chen F, Liu XL, Du ML, Jia D (2008) App Surf Sci 255:2715–2722
Bao SP, Tjong SC (2007) Comp: Part A 38:378–338
Chiu FC, Lai SM, Chen YL, Lee TH (2005) Polym 46:11600–11609
Chow WS, Bakar AA, Ishak ZAM, Karger-Kocsis J, Ishiaku US (2005) Euro Polym J 41:687–696
Dasari A, Yu ZZ, Mai YW (2005) Polym 46:5986–5991
Dong WF, Zhang XH, Liu YQ, Gui H, Wang QG, Gao JM, Song ZH, Lai JM, Huang F, Qiao JL (2006) Euro Polym J 42:2515–2522
González I, Eguiazábal JI, Nazábal J (2006) Comp Sci Technol 66:1833–1843
Kelnar I, Khunová V, Kotek J, Kaprálková L (2007) Polym 48:5332–5339
Kelnar I, Rotrekl J, Kotek J, Kaprálková L, Hromádková J (2009) Euro Polym J 45:2760–2766
Lai SM, Li HC, Liao YC (2007) Euro Polym J 43:1660–1671
Shelley JS, Mather PT, DeVries KL, Mauger M (2001) Polym 42:5849–5858
Kusmono, Ishak ZAM, Chow WS, Takeichi T, Rochmadi N (2008) Euro Polym J 44:1023–1039
Tanrattakul V, Sungthong N, Raksa P (2008) Polym Test 27:794–800
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Research E-Science Grant, (No. 03-01-06-SF0671), by Ministry of Science, Technology and Innovation (MOSTI), Malaysia is gratefully acknowledged.
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Sharif, N.F.A., Mohamad, Z., Hassan, A. et al. Novel epoxidized natural rubber toughened polyamide 6/halloysite nanotubes nanocomposites. J Polym Res 19, 9749 (2012). https://doi.org/10.1007/s10965-011-9749-5
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DOI: https://doi.org/10.1007/s10965-011-9749-5