Skip to main content
Log in

Dielectric Constants of Water, Methanol, Ethanol, Butanol and Acetone: Measurement and Computational Study

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The dielectric constants (relative permittivities) of water, methanol, ethanol, butanol and acetone were measured at 91.3 kPa and (283.15 and 293.15) K and are reported here. The dielectric constants were determined by using a new setup based on a low-pass filter. The obtained dielectric constant values are compared with those reported in the literature, and are consistent with those reported in the literature. The obtained dielectric constant data were also compared with those calculated by the Kirkwood model. The comparisons indicated that Kirkwood model can be successfully used for calculation of dielectric constants of the pure fluids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Jennings, S.G.: A method of measurement of the dielectric constant of some liquids. Phys. Educ. 12, 40–42 (1977)

    Article  Google Scholar 

  2. Fernandez, D.P., Goodwin, A.R.H., Levelt Sengers, J.M.H.: Measurements of the relative permittivity of liquid water at frequencies in the range of 0.1 to 10 kHz and at temperatures between 273.1 and 373.2 K at ambient. Int. J. Thermophys. 16, 929–955 (1995)

    Article  CAS  Google Scholar 

  3. Goodwin, R.H., Mehl, J.B., Moldover, M.R.: Reentrant radio-frequency resonator for automated phase-equilibria and dielectric measurements in fluids. Rev. Sci. Instrum. 67, 4294–4298 (1996)

    Article  CAS  Google Scholar 

  4. Kaatze, U.: The dielectric properties of water in its different states of interaction. J. Solution Chem. 26, 1049–1112 (1997)

    Article  CAS  Google Scholar 

  5. Anderson, G.S., Miler, R.C., Goodwin, R.H.: Static dielectric constants for liquid water from 300 K to 350 K at pressure to MPa using a new radio-frequency resonator. J. Chem. Eng. Data 45, 549–554 (2000)

    Article  CAS  Google Scholar 

  6. Buckley, F., Maryott, A.A.: Tables of dielectric dispersion data for pure liquids and dilute solutions. NBS Circular No. 589, National Bureau of Standards, Washington, DC (1958)

  7. Dunn, L.A., Stokes, R.H.: Pressure and temperature dependence of the electrical permittivities of formamide and water. Trans. Faraday Soc. 65, 2906–2912 (1996)

    Article  Google Scholar 

  8. Åkerlöf, G.: Dielectric constants of some organic solvent-water mixtures at various temperatures. J. Am. Chem. Soc. 54, 4125–4139 (1932)

    Article  Google Scholar 

  9. Archer, D.G., Wang, P.: The dielectric constant of water and Debye–Hückel limiting law slopes. J. Phys. Chem. Ref. Data 19, 371–411 (1990)

    Article  CAS  Google Scholar 

  10. Owen, B.B., Miller, R.C., Milner, C.E., Cogan, H.L.: The dielectric constant of water as a function of temperature and pressure. J. Phys. Chem. 65, 2065–2070 (1961)

    Article  CAS  Google Scholar 

  11. Dannhauser, W., Bahe, L.W.: Dielectric constant of hydrogen bonded liquids. III. Superheated alcohols. J. Chem. Phys. 40, 3058–3066 (1964)

    Article  CAS  Google Scholar 

  12. Floriano, W.B., Nascimento, M.A.C.: Dielectric constant and density of water as a function of pressure at constant temperature. Braz. J. Phys. 34, 38–41 (2004)

    Article  CAS  Google Scholar 

  13. Hamelin, J., Mehl, J.B., Moldover, M.R.: The static dielectric constant of liquid water between 274 and 418 K near the saturated vapor pressure. Int. J. Thermophys. 19, 1359–1380 (1998)

    Article  CAS  Google Scholar 

  14. Hamelin, J., Mehl, J.B., Moldover, M.R.: Resonators for accurate dielectric measurements in conducting liquids. Rev. Sci. Instrum. 69, 255–260 (1998)

    Article  CAS  Google Scholar 

  15. Marcus, Y., Hefter, G.: On the pressure and electric field dependencies of the relative permittivity of liquids. J. Solution Chem. 28, 575–592 (1999)

    Article  CAS  Google Scholar 

  16. Sivasubramanian, S., Widom, A., Srivastava, Y.N.: The Clausius–Mossotti phase transition in polar liquids. Physica A 345, 356–366 (2005)

    Article  Google Scholar 

  17. Wang, P., Anderko, A.: Computation of dielectric constants of solvent mixtures and electrolyte solutions. Fluid Phase Equil. 186, 103–122 (2001)

    Article  CAS  Google Scholar 

  18. Hasted, J.B., Ritson, D.M., Collie, C.H.: Dielectric properties of aqueous ionic solutions. Parts I and II. J. Chem. Phys. 16, 1–21 (1948)

    Article  CAS  Google Scholar 

  19. Akhadov, Y.Y.: Dielectric Properties of Binary Solutions. Pergamon, New York (1980)

    Google Scholar 

  20. Lowery, T.H., Richardson, K.S.: Mechanism and Theory in Organic Chemistry, 3d edn. Harper Collins Publishers, New York (1987)

    Google Scholar 

  21. Tanford, C.: The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd edn. Wiley, New York (1973)

    Google Scholar 

  22. Taylor, J.T., Huang, Q. (eds.): CRC Handbook of Electrical Filters. CRC Press, Boca Raton (1997)

    Google Scholar 

  23. Garland, C.W., Niber, J.W., Shomaker, D.: Experiment in Physical Chemistry, 7th edn. McGraw-Hill, Boston (2003)

    Google Scholar 

  24. Gregory, A.P., Clarke, R.N.: Traceable measurements of the static permittivity of dielectric reference liquids over the temperature range 5–50°C. Meas. Sci. Technol. 16, 1506–1516 (2005)

    Article  CAS  Google Scholar 

  25. Lide, D.R.: Handbook of Chemistry and Physics, 85th edn. CRC Press, Boca Raton (2004)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Mohsen-Nia.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mohsen-Nia, M., Amiri, H. & Jazi, B. Dielectric Constants of Water, Methanol, Ethanol, Butanol and Acetone: Measurement and Computational Study. J Solution Chem 39, 701–708 (2010). https://doi.org/10.1007/s10953-010-9538-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-010-9538-5

Keywords

Navigation