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The dielectric properties of water in its different states of interaction

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Abstract

A tutorial on dielectric (relaxation) spectrometry of liquids is given in this article. Some methods of measuring complex (electric) permittivity spectra are briefly described. Results for water are presented and related to characteristic properties of the liquid structure and to models of the molecular dynamics, particularly as resulting from computer simulation studies. Dielectric spectra for aqueous solutions of low weight electrolytes, polyelectrolytes, small molecules, and polymers are discussed to illustrate effects of kinetic depolarization, structure saturation, as well as positive, negative, and hydrophobic hydration. Reference is also made to fluctuations in the hydrogen bond network of mixtures of water with liquids that are completely miscible with this unique solvent.

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References

  1. R. A. Robinson and R. H. Stokes,Electrolyte Solutions, (Butterworths, London, 1959).

    Google Scholar 

  2. O. J. Samoilow,Die Struktur wäßriger Elektrolytlösungen und die Hydratation von Ionen, (B. G. Teubner, Leipzig, 1961).

    Google Scholar 

  3. Water, a Comprehensive Treatise, Vol. 1:The Physics and Physical Chemistry of Water, F. Franks, ed., (Plenum, New York, 1972).

    Google Scholar 

  4. Water, a Comprehensive Treatise, Vol. 2:Water in Crystalline Hydrates, Aqueous Solutions of Simple Nonelectrolytes, F. Franks, ed., (Plenum, New York, 1973).

    Google Scholar 

  5. Water, a Comprehensive Treatise, Vol. 3:Aqueous Solutions of Simple Electrolytes, F. Franks, ed., (Plenum, New York, 1973).

    Google Scholar 

  6. Water, a Comprehensive Treatise, Vol. 4:Aqueous Solutions of Amphiphiles and Macromolecules, F. Franks, ed., (Plenum, New York, 1975).

    Google Scholar 

  7. Water, a Comprehensive Treatise, Vol. 5:Water in Disperse Systems, F. Franks, ed., (Plenum, New York, 1975).

    Google Scholar 

  8. Water, a Comprehensive Treatise, Vol. 6:Recent Adavances, F. Franks, ed., (Plenum, New York, 1979).

    Google Scholar 

  9. Water, a Comprehensive Treatise, Vol. 7:Water and Aqueous Solutions at Subzero Temperatures, F. Franks, ed., (Plenum, New York, 1982).

    Google Scholar 

  10. Structure of Water and Aqueous Solutions, W. A. P. Luck, ed., (Verlag Chemie and Physik Verlag, Weinheim, 1974).

    Google Scholar 

  11. L’eau et les systemes biologiques, A. Alfsen and A. J. Berteaud, eds., (Éditions du CNRS, Paris, 1976).

    Google Scholar 

  12. Water Science Reviews I, F. Franks, ed., (Cambridge University Press, Cambridge, 1985).

    Google Scholar 

  13. Water Science Reviews 2: Crystalline Hydrates, F. Franks, ed., (Cambridge University Press, Cambridge, 1986).

    Google Scholar 

  14. Water Science Reviews 3: Water Dynamics, F. Franks, ed., (Cambridge University Press, Cambridge, 1988).

    Google Scholar 

  15. Water Science Reviews 4: Hydration Phenomena in Colloidal Systems, F. Franks, ed., (Cambridge University Press, Cambridge, 1989).

    Google Scholar 

  16. C. Tanford,The Hydrophobic Effect: Formation of Micelles and Biological Membranes, (Wiley, New York, 1973).

    Google Scholar 

  17. R. Pottel, inChemical Physics of Ionic Solutions, B. E. Conway and R. G. Barradas, eds., (Wiley, New York, 1966), Chap. 25.

    Google Scholar 

  18. V. V. Daniel,Dielectric Relaxation, (Academic Press, London, 1967).

    Google Scholar 

  19. N. E. Hill, W. E. Vaughan, A. H. Price, and M. Davies,Dielectric Properties and Molecular Behaviour, (Van Nostrand Reinhold, London, 1969).

    Google Scholar 

  20. J. Crossley,Adv. Mol. Relaxation Processes 2, 69 (1970).

    Article  CAS  Google Scholar 

  21. M. Davies,Dielectric and Related Molecular Processes, Vol. 1:A Review of Selected Developments in the Period 1966–1971, (The Chemical Society, London, 1972).

    Google Scholar 

  22. J. B. Hasted,Aqueous Dielectrics, (Chapman and Hall, London, 1973).

    Google Scholar 

  23. S. S. Dukhin and V. N. Shilov,Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes, (Keter, Jerusalem, 1974).

    Google Scholar 

  24. M. Davies,Dielectric and Related Molecular Processes, Vol. 2:Reviews of Recent Developments up to December 1973, (The Chemical Society, London, 1975).

    Google Scholar 

  25. M. Davies,Dielectric and Related Molecular Processes, Vol. 3:Reviews of Recent Developments up to December 1976, (The Chemical Society, London, 1977).

    Google Scholar 

  26. R. Cooke and J. D. Kuntz,Ann. Rev. Biophys. Bioeng. 3, 95 (1974).

    Article  CAS  Google Scholar 

  27. E. H. Grant, R. J. Sheppard, and G. P. South,Dielectric Behaviour of Biological Molecules in Solution, (Clarendon, Oxford, 1978).

    Google Scholar 

  28. R. Pethig,Dielectric and Electronic Properties of Biological Material, (Wiley, Chichester, 1979).

    Google Scholar 

  29. Biophysics of Water, F. Franks and S. Mathias, eds., (Wiley, New York, 1982).

    Google Scholar 

  30. J. S. Clegg,Ann. J. Physiol. 246, R133 (1984).

    CAS  Google Scholar 

  31. Interactions between Electromagnetic Fields and Cells, A. Chiabrera, C. Nicolini, and H. P. Schwan, eds., (Plenum, New York, 1985).

    Google Scholar 

  32. R. Pethig and D. B. Kell,Phys. Med. Biol. 32, 933 (1987).

    Article  CAS  Google Scholar 

  33. W. Gundler, F. Keilmann, and H. Fröhlich,Phys. Lett. 62A, 463 (1977):

    Google Scholar 

  34. S. M. Michaelson,Proc. IEEE 68, 40 (1980).

    CAS  Google Scholar 

  35. K. R. Foster and A. W. Guy,Sci.Am. 255, 28 (1986).

    Article  Google Scholar 

  36. K. Sheikh,Arch. Environ. Health 41, 56 (1986).

    Article  CAS  Google Scholar 

  37. P. Leuthold,Beeinflussung der Umwelt durch elektromagnetische Felder, (Eidg. Drucksachen und Materialzentrale, Bern, 1986).

    Google Scholar 

  38. F. Keilmann,Z. Naturf. 41c, 795 (1986).

    Google Scholar 

  39. D. A. Savitz and E. E. Calle,J. Occup. Med. 29, 47 (1987).

    CAS  Google Scholar 

  40. Biological Coherence and Response to External Stimuli, H. Fröhlich, ed., (Springer, Berlin, 1988).

    Google Scholar 

  41. H. D. Brown and S. K. Chattopadhyay,Cancer Biochem. Biophys. 9, 295 (1988).

    CAS  Google Scholar 

  42. M. Coleman and V. Beral,Int. J. Epidemiol. 17, 1 (1988).

    Article  CAS  Google Scholar 

  43. E. Saalman,Extremely Low and Microwave Frequency Electromagnetic Fields-Influence on Biological Systems?, Dissertation, (Chalmers University of Technology, Göteborg, 1991).

    Google Scholar 

  44. S.-T. Chen, S.-H. Chion, and K.-T. Wang,J. Chin. Chem. Soc. 38, 85 (1991).

    CAS  Google Scholar 

  45. R. Laurent, A. Laporterie, J. Dubac, J. Berlan, S. Lefeuvre, and M. Audhuy,J. Org. Chem. 57, 7099 (1992).

    Article  CAS  Google Scholar 

  46. U. Kaatze,J. Chem. Eng. Data 34, 371 (1989).

    Article  CAS  Google Scholar 

  47. J. G. Powles,J. Mol. Liquids 56, 35 (1993).

    Article  CAS  Google Scholar 

  48. P. Debye,Polar Molecules, (Chemical Catalog, New York, 1929).

    Google Scholar 

  49. J. P. Grant, B. N. Clarke, G. T. Symm, and N. M. SpyrouJ. Phys. E: Sci. Instrum. 22, 757 (1989).

    Article  CAS  Google Scholar 

  50. D. Misra, M. Chahbra, B. R. Epstein, M. Mirotznik, and K. R. Foster,IEEE Trans. MTT 38, 8 (1990).

    Article  CAS  Google Scholar 

  51. R. Pottel and A. Protte,Biomed. Technik 35, 158 (1990).

    Article  CAS  Google Scholar 

  52. H. Cachet, J.-C. Lestrade, and I. Epelboin,J. Chim. Phys. 62, 802 (1965).

    Google Scholar 

  53. R. Nozaki and T. K. Bose,IEEE Trans. IM 39, 945 (1990).

    Google Scholar 

  54. U. Kaatze and K. Giese,J. Mol. Liquids 36, 15 (1987).

    Article  CAS  Google Scholar 

  55. O. Göttmann and A. Dittrich,J. Phys. E: Sci. Instrum. 17, 772 (1984).

    Article  Google Scholar 

  56. O. Göttmann, U. Kaatze, and P. Petong,Meas. Sci. Technol. 7, 525 (1996).

    Article  Google Scholar 

  57. R. H. Cole,Ann. Rev. Phys. Chem. 28, 283 (1977).

    Article  CAS  Google Scholar 

  58. B. Gestblom, E. Noreland, and J. Sjöblom,J. Phys. Chem. 91, 6329 (1987).

    Article  CAS  Google Scholar 

  59. R. H. Cole, J. G. Berberian, S. Mashimo, G. Chryssikos, and A. Bums,J. Appl. Phys. 66, 793 (1989).

    Article  Google Scholar 

  60. R. Nozaki and T. K. Bose,IEEE Trans. IM 39, 945 (1990).

    Google Scholar 

  61. Y. Husimi and A. Wada,Rev. Sci. Instrum. 47, 213 (1978).

    Article  Google Scholar 

  62. J. R. MacDonald,Phys. Rev. 92, 4 (1953).

    Article  CAS  Google Scholar 

  63. H. P. Schwan, inBiological Research, Vol. 6, W. L. Nastuk, ed., (Academic, New York, 1963), p. 323.

    Google Scholar 

  64. H. P. Schwan,Biophysik 3, 181 (1966).

    Article  CAS  Google Scholar 

  65. F. van der Touw, M. Mandel, D. D. Honijk, and G. F. Verhoog,Trans. Faraday Soc. 67, 1343 (1971).

    Article  Google Scholar 

  66. F. van der Touw, G. Selier, and M. Mandel,J. Phys. E: Sci. Instrum. 8, 844 (1975).

    Article  Google Scholar 

  67. S. B. Sachs, A. Katchalsky, and K. S. Spiegler,Electrochim Ada,15, 693 (1970).

    Article  CAS  Google Scholar 

  68. F. van der Touw and M. Mandel,Trans. Faraday Soc. 67, 1336 (1971).

    Article  Google Scholar 

  69. V. Uhlendorf,Beeinflussung wäßriger Lecithin-Vesikel-Suspensionen durch weniger als 1 Molprozent Fettsäureanionen und Alkalichlorid nachgewiesen mittels dielektrischer Relaxationsspektroskopie im Bereich 5 kHz-100 MHz, Dissertation, (Georg-August-University, Göttingen, 1982).

    Google Scholar 

  70. H. P. Schwan and C. D. Ferris,Rev. Sci. Instrum. 39, 481 (1968).

    Article  Google Scholar 

  71. R. Hayakawa, H. Kanda, M. Sacramento, and Y. Wada,Jpn. J. Appl. Phys. 14, 2039 (1975).

    Article  CAS  Google Scholar 

  72. I. Yu,Meas. Sci. Technol. 4, 344 (1993).

    Article  Google Scholar 

  73. T. J. Buchanan,Proc. IEEE, part HI,99, 61 (1952).

    Google Scholar 

  74. E. H. Grant and R. J. Sheppard,J. Phys. D: Appl. Phys. 3, 84 (1970).

    Article  CAS  Google Scholar 

  75. R. J. Sheppard,J. Phys. D: Appl. Phys. 5, 1576 (1972).

    Article  CAS  Google Scholar 

  76. J. Krülger, E. Schollmeyer, and J. Barthel,Z. Naturforsch. 30a, 1476 (1975).

    Google Scholar 

  77. A. Price and G. H. Wegdam,J. Phys. E: Sci. Instrum. 10, 478 (1977).

    Article  CAS  Google Scholar 

  78. S. Szwarnowski,J. Phys. E: Sci. Instrum. 15, 1068 (1982).

    Article  CAS  Google Scholar 

  79. S. Roberts and A. von Hippel,J. Appl. Phys. 17, 610 (1946).

    Article  CAS  Google Scholar 

  80. T. J. Buchanan and E. H. Grant,Br. J. Appl. Phys. 6, 64 (1955).

    Article  Google Scholar 

  81. E. Fatuzzo and P. R. Mason,J. Appl. Phys. 36, 427 (1965).

    Article  CAS  Google Scholar 

  82. E. H. Grant and S. E. Keefe,Rev. Sci. Instum. 39, 1800 (1968).

    Article  Google Scholar 

  83. B. P. Jordan and E. H. Grant,J. Phys. D: Appl. Phys. 3, 1068 (1970).

    Article  CAS  Google Scholar 

  84. R. van Loon and R. Finsy,Rev. Sci. Instrum. 44, 1204 (1973).

    Article  Google Scholar 

  85. N. R. V. Nightingale, S. Szwarnowski, R. J. Sheppard, and E. H. GrantJ. Phys. E: Sci. Instrum. 14, 156 (1981).

    Article  CAS  Google Scholar 

  86. T. J. Natarajan, U. M. S. Murthy, and J. Sobhanadri,IEEE Trans. IM 34, 643 (1985).

    Google Scholar 

  87. H. A. Buckmaster, T. H. T. Kalleveen, H. Zaghloul, and C. H. Hansen,IEEE Trans. MTT 35, 909 (1987).

    Article  Google Scholar 

  88. M. G. M. Richards and R. J. Sheppard,Meas. Sci. Technol. 2, 663 (1991).

    Article  CAS  Google Scholar 

  89. U. Kaatze, R. Pottel, and A. Wallusch,Meas. Sci. Technol. 6, 1201 (1995).

    Article  CAS  Google Scholar 

  90. C. H. Collie, J. B. Hasted, and D. M. Ritson,Proc. Phys. Soc. (London) 60, 71 (1948).

    Article  CAS  Google Scholar 

  91. G. Roussy and M. Felden,IEEE Trans. MTT,14, 171 (1966).

    Article  Google Scholar 

  92. U. Kaatze,Appl. Phys. 2, 241 (1973).

    Article  Google Scholar 

  93. C. D. Gupta,IEEE Trans. MTT 22, 365 (1974).

    Article  Google Scholar 

  94. K. Hallenga,Rev. Sci. Instrum. 46, 1691 (1975).

    Article  CAS  Google Scholar 

  95. A. Bonnincontro and C. Cametti,J. Phys. E: Sci. Instrum. 10, 1232 (1977).

    Article  Google Scholar 

  96. K. Lamkaouchi,L’eau: étalon diélectrique. Etude de lois diélectriques appliquées à I’eau et à des émulsions depétrole mesurées en microondes, (Dissertation, University of Bordaux I, Bordeaux, 1992).

    Google Scholar 

  97. U. Kaatze and V. Uhlendorf,Z Phys. Chem. Neue Folge 126, 151 (1981).

    CAS  Google Scholar 

  98. U. Kaatze,Chem. Phys. Lett. 203, 1 (1993).

    Article  CAS  Google Scholar 

  99. A. A. Jarkih, A. K. Lyashchenko, V. S. Kharkin, V. V. Goncharov, and A. S. Lileev, data quoted in Ref. 100.

  100. L. M. Svishchev and P. G. Kusalik,J. Phys. Chem. 98, 728 (1994).

    Article  CAS  Google Scholar 

  101. H. Weing→tner and C. A. Chatzidimitriou-DreismannNature 246, 548 (1990).

    Article  Google Scholar 

  102. R. Pottel, E. Asselborn, R. Eck, and V. Tresp,Ber. Bunsenges. Phys. Chem. 93, 676(1989).

    CAS  Google Scholar 

  103. T. Manabe, H. J. Liebe, and G. A. Hufford,IEEE Con. Dig. 12th Conf. on IR Millimetre Waves (1987) p. 220.

  104. M. S. Zafar, J. B. Hasted, and J. Chamberlain,Nature, Phys. Sci. 243, 106 (1973).

    CAS  Google Scholar 

  105. J. Barthel, K. Bachhuber, R. Buchner, and H. Hetzenauer,Chem. Phys. Lett. 165, 369 (1990).

    Article  CAS  Google Scholar 

  106. O. Conde and J. Teixera,J. Phys. (Paris)44, 525 (1983).

    CAS  Google Scholar 

  107. S. K. Garg and C. P. Smyth,J. Phys. Chem. 69, 1294 (1965).

    Article  CAS  Google Scholar 

  108. E. Jakusck and L. Sobczyk, Ref. 25, p. 108.

  109. I. Ohmine,J. Phys. Chem. 99, 6767 (1995).

    Article  CAS  Google Scholar 

  110. R. H. Cole,J. Chem. Phys. 23, 493 (1955).

    Article  CAS  Google Scholar 

  111. D. W. Davidson and R. H. Cole,J. Chem. Phys. 18, 1417 (1950).

    Article  CAS  Google Scholar 

  112. S. Mashimo, S. Kuwabara, S. Yagihara, and K. Higasi,J. Chem. Phys. 90, 3292 (1989).

    Article  CAS  Google Scholar 

  113. D. Bertolini, M. Cassettari, and G. Salvetti,J. Chem. Phys. 78, 365 (1983).

    Article  CAS  Google Scholar 

  114. U. Kaatze, A. Schumacher, and R. Pottel,Ber. Bunsenges. Phys. Chem. 95, 585 (1991).

    CAS  Google Scholar 

  115. W. F. Brown, inEncyclopedia of Physics, Vol. 17, S. Flügge, ed., (Springer, Berlin, 1956) Chap. 1.

    Google Scholar 

  116. H. Fröhlich,Theory of Dielectrics, (Clarendon, Oxford, 1958).

    Google Scholar 

  117. N. E. Hill, Ref. 19, Chap. 1.

  118. C. J. F. Böttcher,Theory of Electric Polarization, Vol. 1, (Elsevier, Amsterdam, 1973).

    Google Scholar 

  119. J. B. Hasted and M. Shahidi,Nature 263, 777 (1976).

    Article  Google Scholar 

  120. I. M. Hodge and C. A. Angell,J. Chem. Phys. 68, 1363 (1978).

    Article  CAS  Google Scholar 

  121. C. G. Malmberg and A. A. Maryott,J. Res. Nat. Bur. Stand. 56, 1 (1956).

    CAS  Google Scholar 

  122. G. A. Vidulich, D. F. Evans, and R. L. Kay,J. Phys. Chem. 17, 656 (1967).

    Article  Google Scholar 

  123. J. G. Kirkwood,J. Chem. Phys. 7, 911 (1939).

    Article  CAS  Google Scholar 

  124. A. H. Price, Ref. 19, Chap. 3.

  125. N. E. Hill,J. Phys. C: Solid State Phys. 3, 238 (1970).

    Article  CAS  Google Scholar 

  126. R. Pottel and U. Kaatze,Ber. Bunsenges. Phys. Chem. 73, 437 (1969).

    CAS  Google Scholar 

  127. U. Kaatze and W.-Y. Wen,J. Phys. Chem. 82, 109 (1978).

    Article  CAS  Google Scholar 

  128. U. Kaatze, R. Pottel, and P. Schmidt,J. Phys. Chem. 92, 3669 (1988).

    Article  CAS  Google Scholar 

  129. U. Kaatze,Adv. Mol. Relax. Processes 7, 71 (1975).

    Article  CAS  Google Scholar 

  130. U. Kaatze, O. Göttmann, R. Podbielski, R. Pottel, and U. Terveer,J. Phys. Chem. 82, 112(1978).

    Article  CAS  Google Scholar 

  131. U. Kaatze,Ber. Bunsenges. Phys. Chem. 84, 1195 (1980).

    CAS  Google Scholar 

  132. C. J. F. Böttcher and D. Bordewijk,Theory of Electric Polarization, Vol. 2, (Elsevier, Amsterdam, 1978).

    Google Scholar 

  133. M. Lavergne and W. Drost-Hansen,Naturwissenschaften 43, 511 (1956).

    Article  Google Scholar 

  134. W. Drost-Hansen,Ann. N.Y. Acad. Sci. 125, 471 (1965).

    Article  CAS  Google Scholar 

  135. E. H. Grant and R. J. Sheppard,J. Chem. Phys. 60, 1792 (1974).

    Article  CAS  Google Scholar 

  136. R. Pottel, inSommerschule Physik desflüssigen Zustands, Vol. 3, F. Kohler, P. Weinzierl, eds., (Ruhr-Universität, Bochum, 1977), p. 180.

    Google Scholar 

  137. U. Kaatze and R. Pottel,J. Mol. Liquids. 52, 181 (1992).

    Article  CAS  Google Scholar 

  138. H. Tanaka and I. Ohmine,J. Chem. Phys. 87, 6128 (1987).

    Article  CAS  Google Scholar 

  139. I. Ohmine, H. Tanaka, and P. G. Wolynes,J. Chem. Phys. 89, 5852 (1988).

    Article  Google Scholar 

  140. J. Schnitker and A. Geiger,Z Phys. Chem. Neue Folge 155, 29 (1987).

    CAS  Google Scholar 

  141. M. Neumann,J. Chem. Phys. 82, 5663 (1982).

    Article  Google Scholar 

  142. M. Neumann,J. Chem. Phys. 85, 1567 (1986).

    Article  CAS  Google Scholar 

  143. O. A. Nabokov and Y. A. Lyubimov,J. Struct. Chem. 27, 731 (1986).

    Article  Google Scholar 

  144. A. Geiger, P. Mausbach, and J. Schnitker, inWater and Aqueous Solutions, G. W. Neilson, J. E. Enderby, ed. (Hilger, Bristol, 1986), p. 15.

    Google Scholar 

  145. D. Bertolini, M. Cassettari, M. Ferrario, P. Grigolini, G. Salvetti, and A. Tari,J. Chem. Phys. 91, 1179(1989).

    Article  CAS  Google Scholar 

  146. F. Sciortino and S. L. Fornili,J. Chem. Phys. 90, 2786 (1989).

    Article  CAS  Google Scholar 

  147. F. Sciortino, A. Geiger, and H. E. Stanley,Phys. Rev. Lett. 65, 3452 (1990).

    Article  CAS  Google Scholar 

  148. F. Sciortino, A. Geiger, and H. E. Stanley,Nature 354, 218 (1991).

    Article  CAS  Google Scholar 

  149. F. Sciortino, A. Geiger, and H. E. Stanley,J. Chem. Phys. 96, 3857 (1992).

    Article  CAS  Google Scholar 

  150. B. Gestblom and J. Sjöblom,Acta Chem. Scand. A 38, 47 (1984).

    Google Scholar 

  151. B. Gestblom and J. Sjöblom,Acta Chem. Scand. A 38, 575 (1984).

    Google Scholar 

  152. U. Kaatze, M. Schäfer, and R. Pottel,Z Phys. Chem. Neue Folge 165, 103 (1989).

    CAS  Google Scholar 

  153. U. Kaatze, R. Pottel, and A. Schumacher,J. Phys. Chem. 96, 6017 (1992).

    Article  CAS  Google Scholar 

  154. K. S. Cole and R. H. Cole,J. Chem. Phys. 9, 341 (1941).

    Article  CAS  Google Scholar 

  155. S. Havriliak and S. Negami,J. Polymer Sci. C14, 99 (1966).

    Google Scholar 

  156. R. M. Hill,Nature 275, 96 (1978).

    Article  CAS  Google Scholar 

  157. R. M. Hill,Phys. Stat. Sol. B 103, 319 (1981).

    Article  CAS  Google Scholar 

  158. U. Kaatze and R. Pottel,J. Mol. Liquids 30, 115 (1985).

    Article  CAS  Google Scholar 

  159. U. Kaatze, P. Schmidt, and R. Pottel,Ber. Bunsenges. Phys. Chem. 92, 609 (1988).

    CAS  Google Scholar 

  160. U. Kaatze,Z Phys. Chem. Neue Folge 13, 141 (1987).

    Google Scholar 

  161. U. Kaatze, C. Neumann, and R. Pottel,J. Solution Chem. 16, 191 (1987).

    Article  CAS  Google Scholar 

  162. U. Kaatze, K. Menzel, and R. Pottel,J. Phys. Chem. 95, 324 (1991).

    Article  CAS  Google Scholar 

  163. U. Kaatze,J. Phys. Chem. 91, 3111 (1987).

    Article  CAS  Google Scholar 

  164. J. O’M Bockris and A. K. N. Reddy,Modern Electrochemistry, Vol. 1, (Plenum, New York, 1970), ch. 5.

    Google Scholar 

  165. C. Grosse,J. Phys. Chem 92, 3905 (1988).

    Article  CAS  Google Scholar 

  166. L. K. H. van Beek, inProgress in Dielectrics, Vol. 7, J. B. Birks, ed., (Heywood, London, 1967), p. 69.

    Google Scholar 

  167. J. C. Maxwell,Electricity and Magnetism, (Clarendon, Oxford, 1892).

    Google Scholar 

  168. K. W. Wagner,Arch. Elektrotechn. 2, 371 (1914).

    Article  Google Scholar 

  169. D. A. G. Bruggeman,Ann. Phys. Lpz 5, 636 (1935).

    Article  Google Scholar 

  170. D. Polder and N. J. van Santen,Physica, Amsterdam 12, 257 (1946).

    Article  Google Scholar 

  171. U. Kaatze,Z Phys. Chem. Neue Folge 135, 51 (1983).

    CAS  Google Scholar 

  172. U. Kaatze, A. Dittrich, K.-D. Göpel, and R. Pottel,Chem. Phys. Lipids 35, 279 (1984).

    Article  CAS  Google Scholar 

  173. R. Pottel, K.-D. Göpel, R. Henze, U. Kaatze, and V. Uhlendorf,Biophys. Chem. 19, 233 (1984).

    Article  CAS  Google Scholar 

  174. U. Kaatze, K.-D. Göpel, and R. Pottel,J. Phys. Chem. 89, 2565 (1985).

    Article  CAS  Google Scholar 

  175. R. Pottel, U. Kaatze, and S. C. Müller,Ber. Bunsenges. Phys. Chem. 82, 1086 (1978).

    CAS  Google Scholar 

  176. J. Sjöblom, R. Skurtveit, J. O. Saeten, and B. Gestblom,J. Colloid Interface Sci. 141, 329 (1991).

    Article  Google Scholar 

  177. J. B. Hubbard, L. Onsager, W. M. van Beek, and M. Mandel,Proc. Natl. Acad. Sci. USA 74, 401 (1977).

    Article  CAS  Google Scholar 

  178. J. B. Hubbard and L. Onsager,J. Chem. Phys. 67, 4850 (1977).

    Article  CAS  Google Scholar 

  179. J. B. Hubbard,J. Chem. Phys. 68, 1649 (1978).

    Article  CAS  Google Scholar 

  180. J. B. Hubbard, P. Colonomos, and P. G. Wolynes,J. Chem. Phys. 71, 2652 (1979).

    Article  CAS  Google Scholar 

  181. J. B. Hubbard and R. F. Kayser,J. Chem. Phys. 74, 3535 (1981).

    Article  CAS  Google Scholar 

  182. P. G. Wolynes,Ann. Rev. Phys. Chem. 31, 345 (1980).

    Article  CAS  Google Scholar 

  183. P. G. Kusalik and G. N. Patey,J. Chem. Phys. 79, 4468 (1983).

    Article  CAS  Google Scholar 

  184. B. J. Alder and T. E. Wainwright,Phys. Rev. A 1, 18 (1970).

    Article  Google Scholar 

  185. B. J. Alder and W. E. Alley,Phys. Today 37, 56 (1984).

    Article  CAS  Google Scholar 

  186. R. Pottel, Ref. 5, Chap. 8.

  187. U. Kaatze and R. Pottel,Z Phys. Chem. Neue Folge 141, 1 (1984).

    CAS  Google Scholar 

  188. H. G. Hertz, R. Tutsch, and H. Versmold,Ber. Bunsenges. Phys. Chem. 75, 1177 (1971).

    Google Scholar 

  189. H. G. Hertz and M. D. Zeidler,Ber. Bunsenges. Phys. Chem. 67, 774 (1963).

    CAS  Google Scholar 

  190. J. E. Enderby and G. W. Neilson,Adv. Phys. 29, 323 (1980).

    Article  CAS  Google Scholar 

  191. V. Uhlendorf,Messung der dielektrischen Relaxation wßiriger Polyelektrolyt-Lösungen zwischen 5 MHz und 40 GHz, Diploma-Thesis, (Georg-August-University, Göttingen, 1978).

    Google Scholar 

  192. U. Kaatze, H. Gerke, and R. Pottel,J. Phys. Chem. 90, 5464 (1986).

    Article  CAS  Google Scholar 

  193. U. Kaatze, C. H. Limberg, and R. Pottel,Ber. Bunsenges. Phys. Chem. 78, 555 (1974).

    CAS  Google Scholar 

  194. W.-Y. Wen and U. Kaatze,J. Phys. Chem. 81, 177 (1977).

    Article  CAS  Google Scholar 

  195. K. Giese, U. Kaatze, and R. Pottel,J. Phys. Chem. 74, 3718 (1970).

    Article  CAS  Google Scholar 

  196. G. Bödecker,Messungen von Schalldämpfung und Schallgeschwindigkeit an wäßrigen Harnstofflösungen im Frequenzbereich von 330 bis 830 MHz, Diploma-Thesis, (Georg-August-University, Göttingen, 1974).

    Google Scholar 

  197. U. Kaatze, C. H. Limberg, and R. Pottel,Ber. Bunsenges. Phys. Chem. 78, 561 (1974).

    CAS  Google Scholar 

  198. U. Kaatze,Ber. Bunsenges. Phys. Chem. 82, 690 (1978).

    CAS  Google Scholar 

  199. H. G. Hertz, Ref. 5, Chap. 7.

  200. B. E. Conway,Ionic Hydration in Chemistry and Biophysics, (Elsevier, Amsterdam, 1981).

    Google Scholar 

  201. K. Giese,Ber. Bunsenges. Phys. Chem. 76, 495 (1972).

    CAS  Google Scholar 

  202. R. Pottel, K. Giese, and U. Kaatze, Ref. 10, Chap. 6.2.

  203. L. Endom, H. G. Hertz, B. Thai, and M. Zeidler,Ber. Bunsenges. Phys. Chem. 71, 1008 (1967).

    CAS  Google Scholar 

  204. G. Engel and H. G. Hertz,Ber. Bunsenges. Phys. Chem. 72, 808 (1968).

    CAS  Google Scholar 

  205. R. Pottel,Ber. Bunsenges. Phys. Chem. 69, 363 (1965).

    CAS  Google Scholar 

  206. J. Barthel, R. Buchner, and H.-J. Wittmann,Z Phys. Chem. Neue Folge 139, 23 (1984).

    CAS  Google Scholar 

  207. U. Kaatze, V. Lönnecke, and R. Pottel,J. Mol. Liquids 34, 241 (1987).

    Article  CAS  Google Scholar 

  208. P. S. Belton, K. J. Parker, and T. C. Sellwood,Biochim. Biophys. Acta 304, 56 (1973).

    CAS  Google Scholar 

  209. F. Franks, Ref. 9, Chap. 3.

  210. W. Derbyshire, Ref. 9, Chap. 4.

  211. V. Lönnecke-Gabel,Dielektrische Spektroskopie an wasserarmen Mischungen zur Frage der dielektrischen Relaxation “gebundenen” Wassers, Dissertation, (Georg-August-University, Gottingen, 1990).

    Google Scholar 

  212. U. Kaatze, V. Lonnecke-Gabel, and R. Pottel,Z Phys. Chem. Neue Folge 175, 165 (1992).

    CAS  Google Scholar 

  213. U. Kaatze, R. Pottel, and M. Schäfer,J. Phys. Chem. 93, 5623 (1989).

    Article  CAS  Google Scholar 

  214. A. Chandra, D. Wei, and G. N. Patey,J. Chem. Phys. 98, 4959 (1994).

    Article  Google Scholar 

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  1. Drittes Physikalisches Institut, Georg-August-Universität, Bürgerstraße 42–44, D-37073, Göttingen, Germany

    Udo Kaatze

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Kaatze, U. The dielectric properties of water in its different states of interaction. J Solution Chem 26, 1049–1112 (1997). https://doi.org/10.1007/BF02768829

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