Abstract
Pure aluminum oxide (Al2O3) and iron-doped alumina Fe-doped Al2O3 with different percentages of Fe dopant nanoparticles (NPs) were synthesized by co-precipitation method. The XRD analysis indicated that the samples have γ, δ, θ, and α phases and the crystal structure became more stable with increasing Fe dopant. The results of the TEM analysis indicated that the particle size of the 4%-doped sample is about 45 nm. The results of FTIR analysis indicated an increase in the intensity of the Al-OH absorption with increasing of the Fe dopant. The UV-DRS optical analysis demonstrated that the band gap energy of the pure Al2O3 sample decreased from 4.1 to 3.51 eV for the sample with a 6% impurity. Finally, the VSM magnetic analysis showed the paramagnetic behavior of the Fe-doped alumina.
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Dastpak, M., Farahmandjou, M., Firoozabadi, T.P.: Synthesis and preparation of magnetic Fe-doped CeO2 nanoparticles prepared by simple sol-gel method. J. Supercond. Nov. Magn. 29, 2925–2929 (2016). https://doi.org/10.1007/s10948-016-3639-3
Farahmandjou, M., Soflaee, F.: Polymer-mediated synthesis of iron oxide (Fe2O3) Nanorods. Chin. J. Phys. 53, 080801–080809 (2015). https://doi.org/10.6122/CJP.20150413
Jurablu, S., Farahmandjou, M., Firoozabadi, T.P.: Multiple-layered structure of obelisk-shaped crystalline nano-ZnO prepared by sol–gel route. J. Theoretical. Appl. Phys. 9, 261–266 (2015). https://doi.org/10.1007/s40094-015-0184-6
Farahmandjou, M.; Soflaee, F., Synthesis and characterization of α-Fe2O3 nanoparticles by simple co-precipitation method. Phys. Chem. Res. 2015, 3, 193–198, https://doi.org/10.22036/pcr.2015.9193
Zarinkamar, M., Farahmandjou, M., Firoozabadi, T.P.: Diethylene glycol-mediated synthesis of nano-sized ceria (CeO2) catalyst. J. Nanostruct. 6, 116–120 (2016). https://doi.org/10.7508/jns.2016.02.002
Farahmandjou, M.: Magnetocrystalline properties of Iron-Platinum (L10-FePt) nanoparticles through phase transition. Iran. J. Phys. Res. 16, 1–5 (2016). https://doi.org/10.18869/acadpub.ijpr.16.1.1
Farahmandjou, M., Ramazani, M.: Fabrication and characterization of rutile TiO2 nanocrystals by water soluble precursor. Phys. Chem. Res. 3, 293–298 (2015). https://doi.org/10.22036/pcr.2015.10641
Shadrokh, S., Farahmandjou, M., Firozabadi, T.P.: Fabrication and characterization of nanoporous Co oxide (Co3O4) prepared by simple sol-gel synthesis. Phys. Chem. Res. 4, 153–160 (2016). https://doi.org/10.22036/pcr.2016.12909
Farahmandjou, M., Honarbakhsha, S., Behrouziniab, S.: PVP-assisted synthesis of cobalt ferrite (CoFe2O4) nanorods. Phys. Chem. Res. 4, 655–662 (2016). https://doi.org/10.22036/pcr.2016.16702
Aranzabal, A., Ayastuy, J.L., Gonza’lez, J.A.: Kinetics of the catalytic oxidation of lean trichloroethylene in air over Pd/alumina. Ind. Eng. Chem. Res. 42, 6007–6011 (2003)
Miranda, B., Díaz, E., Ordoñez, S., Díez, F.V.: Catalytic combustion of trichloroethene over Ru/Al2O3: reaction mechanism and kinetic study. Catal. Commun. 7, 945–949 (2006)
Bejenaru, N., Lancelot, C., Blanchard, P., Lamonier, C., Rouleau, L., Payen, E., Dumeignil, F., Royer, S.: Synthesis, characterization, and catalytic performances of novel CoMo hydrodesulfurization catalysts supported on mesoporous aluminas. Chem. Mater. 21, 522–533 (2009)
Farahmandjou, M.: Synthesis and structural study of L10- FePt nanoparticles. Turk. J. Eng. Environ. Sci. 34, 265–270 (2010). https://doi.org/10.3906/muh-1010-20
Akhtari, F., Zorriasatein, S., Farahmandjou, M., Elahi, S.M.: Structural, optical, thermoelectrical, and magnetic study of Zn1-xCoxO (0 ≤ x ≤ 0.10) nanocrystals. Int. J. Appl. Ceram. Technol. 15, 723–733 (2018). https://doi.org/10.1111/ijac.12848
Akhtari, F., Zorriasatein, S., Farahmandjou, M., Elahi, S.M.: Synthesis and optical properties of Co2+-doped ZnO network prepared by new precursors. Mater. Res. Express. 5, 065015 (2018). https://doi.org/10.1088/2053-1591/aac6f1
Khoshnevisan, B., Marami, M.B., Farahmandjou, M.: Fe3+-doped anatase TiO2 study prepared by new sol-gel precursors. Chin. Phys. Lett. 35, 027501–027505 (2018). https://doi.org/10.1088/0256-307X/35/2/027501
Marami, M.B., Farahmandjou, M., Khoshnevisan, B.: Solgel synthesis of Fe-doped TiO2 nanocrystals. J. Electron. Mater. 47, 3741–3749 (2018). https://doi.org/10.1007/s11664-018-6234-5
Wang, J.A., Bokhimi, X., Morales, A., Novaro, O., López, T., Gómez, R.: Aluminum local environment and defects in the crystalline structure of sol-gel alumina catalyst. J. Phys. Chem. B. 103, 299–303 (1999)
Farahmandjou, M., Honarbakhsh, S., Behrouzinia, S.: FeCo nanorods preparation using new chemical synthesis. J. Supercond. Nov. Magn. 31, 4147–4152 (2018). https://doi.org/10.1007/s10948-018-4659-y
Farahmandjou, M., Khalili, P.: Study of nano SiO2/TiO2 superhydrophobic self-cleaning surface produced by sol-gel. Aust. J. Basic Appl. Sci. 7, 462–465 (2013)
Jurablu, S., Farahmandjou, M., Firoozabadi, T.P.: Sol-gel synthesis of zinc oxide (ZnO) nanoparticles: study of structural and optical properties. J. Sci. Islamic Republic Iran. 26, 281–285 (2015)
Farahmandjou, M., Dastpak, M.: Fe-loaded CeO2 nanosized prepared by simple co-precipitation route. Phys. Chem. Res. 6, 713–720 (2018)
Farahmandjou, M., Motaghi, S.: Sol-gel synthesis of Ce-doped α-Al2O3: study of crystal and optoelectronic properties. Opt. Commun. 441, 1–7 (2019). https://doi.org/10.1016/j.optcom.2019.02.029
Motaghi, S., Farahmandjou, M.: Structural and optoelectronic properties of Ce-Al2O3 nanoparticles prepared by sol-gel precursors. Mater. Res. Express. 6, 045008 (2019). https://doi.org/10.1088/2053-1591/aaf927
Farahmandjou, M., Khalili, P.: Morphology study of anatase nano-TiO2 for self-cleaning coating. Int. J. Fund. Phys. Sci. 3, 54–56 (2013). https://doi.org/10.14331/ijfps.2013.330055
Farahmandjou, M.: Synthesis of ITO nanoparticles prepared by degradation of sulfide method. Chin. Phys. Lett. 29, 077306–077309 (2012). https://doi.org/10.1088/0256-307X/29/7/077306
Farahmandjou, M., Golabiyan, N.: Synthesis and characterization of alumina (Al2O3) nanoparticles prepared by simple sol-gel method. Int. J. Bio-Inorg. Hybr. Nanomater. 5(1), 73–77 (2016)
Jafari, A., Khademi, S., Farahmandjou, M.: Nano-crystalline Ce-doped TiO2 powders: sol-gel synthesis and optoelectronic properties. Mater. Res. Express. 5(9), 095008 (2018). https://doi.org/10.1088/2053-1591/aad5b5
Sohlberg, K., Pennycook, S.J., Pantelides, S.T.: Explanation of the observed dearth of three-coordinated Al on γ-alumina surfaces. J. Am. Chem. Soc. 121, 10999–11001 (1999). https://doi.org/10.1021/ja9926358
Yu-LingWei, H.-C.W., Yao-WenYang, J.-F.L.: XAS study of Zn-doped Al2O3 after thermal treatment. J. Electron Spectrosc. Relat. Phenom. 144–147, 817–819 (2005). https://doi.org/10.1016/j.elspec.2005.01.264
Chen, S., Cui, X.-M., Ding, S.-J.: Novel Zn-doped Al2O3 charge storage medium for light-erasable In–Ga–Zn–O TFT memory. IEEE Electron. Device Lett. 34(8), 1008–1010 (2013). https://doi.org/10.1109/LED.2013.2266371
Ivanova, T., Harizanova, A., Koutzarova, T., Vertruyen, B.: Study of sol-gel Cu-doped Al2O3 thin films: structural and optical properties. J. Phys. Conf. Ser. 514, 012008 (2014)
Heiba, Z.K., Mohamed, M.B., Wahba, A.M., Imam, N.G.: Structural, optical, and electronic characterization of Fe-doped alumina nanoparticles. J. Electron. Mater. 47, 711–720 (2018)
Farahmandjou, M., Golabiyan, N.: Solution combustion preparation of nano-Al2O3: synthesis and characterization. Transp. Phenom. Nano Micro Scales. 3, 100–105 (2015). https://doi.org/10.7508/tpnms.2015.02.004
Farahmandjou, M., Golabiyan, N.: New pore structure of nano-alumina (Al2O3) prepared by sol gel method. J. Ceramic Proc. Res. 16, 237–240 (2015)
Huang, J., Liao, Q., Wang, F., Huang, X., Zhu, H.: Synthesis of Fe-doped alumina transparent ceramics by co-precipitation and vacuum sintering. Ceram. Int. 44(2018), 799–804 (2017)
Scherrer, P.: Bestimmung der Grosse und der Inneren Struktur von Kolloidteilchen Mittels Rontgenstrahlen, Nachrichten von der Gesellschaft der Wissenschaften. Gottingen. Mathematisch-Physikalische Klasse. 2, 98–100 (1918). https://doi.org/10.4236/health.2011.37070 2, 486
Khodadadi, A., Farahmandjou, M., Yaghoubi, M., Amani, A.R.: Structural and optical study of Fe3+-doped Al2O3 nanocrystals prepared by new sol gel precursors. Int. J. Appl. Ceram. Technol. 16, 718–726 (2018). https://doi.org/10.1111/ijac.13065
Divband, L., et al.: Synthesis and characterization of Al2O3 nanoparticles by flame spray pyrolysis (FSP) — role of Fe ions in the precursor. Powder Technol. 298, 42–49 (2016). https://doi.org/10.1016/j.powtec.2016.05.003
Kaur, N., Kaur, S., Singh, V.: Anomalous behavior of visible light active TiO2 for photocatalytic degradation of different reactive dyes. Photochem. Photobiol. Sci. 14, 2024–2034 (2015). https://doi.org/10.1039/c5pp00165j
Jafari, A., Khademi, S., Farahmandjou, M., Darudi, A., Rasuli, R.: Structural and optical properties of Ce3+-doped TiO2 nanocrystals prepared by sol-gel precursors. J. Electron. Mater. 47, 6901–6908 (2018). https://doi.org/10.1007/s11664-018-6590-1
Farahamndjou, M.: The study of electro-optical properties of nanocomposite ITO thin films prepared by e-beam evaporation. Rev. Mex. Fís. 59, 205–207 (2013)
Zarinkamar, M., Farahmandjou, M., Firoozabadi, T.P.: One-step synthesis of ceria (CeO2) nano-spheres by a simple wet chemical method. J. Ceram. Process. Res. 17, 166–169 (2016)
Marami, M.B., Farahmandjou, M.: Water-based sol–gel synthesis of Ce-doped TiO2 nanoparticles. J. Electron. Mater. 48, 4740–4747 (2019). https://doi.org/10.1007/s11664-019-07265-9
Khodadadi, A., Farahmandjou, M., Yaghoubi, M.: Investigation on synthesis and characterization of Fe-doped Al2O3 nanocrystals by new sol–gel precursors. Mater. Res. Express. 6, 025029 (2019). https://doi.org/10.1088/2053-1591/aaef70
Ramazani, M., Farahmandjou, M., Firoozabadi, T.P.: Effect of nitric acid on particle morphology of the nano-TiO2. Int. J. Nanosci. Nanotech. 11, 115–122 (2015)
Farahmandjou, M., Zarinkamar, M.: Synthesis of nano-sized ceria (CeO2) particles via a cerium hydroxy carbonate precursor and the effect of reaction temperature on particle morphology. J. Ultrafine Grained Nanostruct. Mater. 48, 5–10 (2015). https://doi.org/10.7508/jufgnsm.2015.01.002
Farahmandjou, M., Zarinkamar, M., Firoozabadi, T.P.: Synthesis of cerium oxide (CeO2) nanoparticles using simple CO-precipitation method. Rev. Mex. Fís. 62, 496–499 (2016)
Farahmandjou, M., Salehizadeh, S.A.: The optical band gap and the tailing states determination in glasses of TeO2-V2O5-K2O system. Glas. Phys. Chem. 39, 473–479 (2013). https://doi.org/10.1134/S1087659613050052
Behrouzinia, S., Salehinia, D., Khorasani, K., Farahmandjou, M.: The continuous control of output power of a CuBr laser by a pulsed external magnetic field. Opt. Commun. 436, 143–145 (2019). https://doi.org/10.1016/j.optcom.2018.12.016
Farahmandjou, M.: Effect of oleic acid and oleylamine surfactants on the size of FePt nanoparticles. J. Supercond. Nov. Magn. 25, 2075–2079 (2012)
Khatoon, S., Wani, I.A., Ahmed, J., Magdaleno, T., Al-Hartomy, O.A., Ahmad, T.: Effect of high manganese substitution at ZnO host lattice using solvothermal method: structural characterization and properties. Mater. Chem. Phys. 138, 519–528 (2013)
Kumar, S., Kumar, R., Singh, D.P.: Swift heavy ion induced modifications in cobalt doped ZnO thin films: structural and optical studies. Appl. Surf. Sci. 255, 8014–8018 (2009)
Nomura, K., Kinoshita, R., Sakamoto, I., Okabayashi, J., Yamada, Y.: Dilute magnetic properties of Fe doped Al2O3 powders prepared by sol-gel method. Hyperfine Interact. 208, 65–69 (2012). https://doi.org/10.1007/s10751-011-0503-5
Farahmandjou, M., Soflaee, F.: Synthesis of iron oxide nanoparticles using borohydride reduction. Int. J. Bio-Inorg. Hybr. Nanomater. 3, 203–206 (2014)
Honarbakhsh, S., Farahmandjou, M., Behroozinia, S.: Synthesis and characterization of iron cobalt (FeCo) nanorods prepared by simple Co-precipitation method. J. Fund. Appl. Sci. 8, 892–900 (2016). https://doi.org/10.4314/jfas.8vi2s.142
Sebt, S.A., Parhizgar, S.S., Farahmandjou, M., Aberomand, P., Akhavan, M.: The role of ligands in the synthesis of FePt nanoparticles. J. Supercond. Nov. Magn. 22, 849–854 (2009). https://doi.org/10.1007/s10948-009-0509-2
Farahmandjou, M., Sebt, S.A., Parhizgar, S.S., Aberomand, P., Akhavan, M.: Stability investigation of colloidal FePt nanoparticle systems by spectrophotometer analysis. Chin. Phys. Lett. 26, 027501–027503 (2009). https://doi.org/10.1088/0256-307X/26/2/027501
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Farahmandjou, M., Khodadadi, A. & Yaghoubi, M. Low Concentration Iron-Doped Alumina (Fe/Al2O3) Nanoparticles Using Co-Precipitation Method. J Supercond Nov Magn 33, 3425–3432 (2020). https://doi.org/10.1007/s10948-020-05569-0
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DOI: https://doi.org/10.1007/s10948-020-05569-0